Abstract
One-dimensional nanofibers fabricated by the process of electrospinning have found engaging applications in the field of dye sensitized solar cells (DSSC) due to semi-directed electron transport. Current research accounts for the development of conductive mats made from nanofibers, which is achieved through the electrospinning of TiO2–ZnO composites and by using polyvinylpyrrolidine as a carrier solution. This fiber was annealed at 450 °C to attain a continuous network of conducting nanofibers. ZnO from the composite was selectively etched to fabricate high surface area anisotropic TiO2 hierarchical fiber. Morphological and phase analysis conducted by scanning electron microscopy and X-ray diffraction studies confirmed the formation of anatase phase and 1-D hierarchical morphology of TiO2. These structures were employed as photoanodes in DSSC, which had shown superior photoconversion efficiency.
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R. Jose, V. Thavasi, S. Ramakrishna, Metal oxides for dye-sensitized solar cells. J. Am. Ceram. Soc. 92, 289 (2009)
L. Schmidt-Mende, S.M. Zakeeruddin, M. Grätzel, Efficiency improvement in solid state-dye-sensitized photovoltaics with an amphiliphilic Ruthenium -dye. Appl. Phys. Lett. 86, 013504 (2005)
M.L. Schmidt, U. Bach, B.R. Humphry, T. Horiuchi, H. Miura, S. Ito, S. Uchida, M. Grätzel, Organic dye for highly efficient solid state DSSC. Adv. Mater. 17, 813 (2005)
S. Kim, J.K. Lee, S.O. Kang, J. Ko, J.-H. Yum, S. Fantacci, F. De Angelis, D. Di Censo, M.K. Nazeeruddin, M. Grätzel, Molecular engineering of organic sensitizers for solar cell applications. J. Am. Chem. Soc. 128, 16701 (2006)
M. Zukalová, A. Zukal, L. Kavan, M.K. Nazeeruddin, P. Liska, M. Grätzel, Organized mesoporous TiO2 films exhibiting greatly enhanced performance in dye-sensitized solar cells. Nano Lett. 5(9), 1789 (2005). https://doi.org/10.1021/nl051401l
H. Yu, S. Zhang, H. Zhao, G. Will, P. Liu, An efficient and low-cost TiO2 compact layer for performance improvement of dye-sensitized solar cells. Electrochim. Acta 54(4), 1319 (2009)
R.Y. Ogura, S. Nakane, M. Morooka, M. Orihashi, Y. Suzuki, K. Noda, High-performance dye-sensitized solar cell with a multiple dye system Appl. Phys. Lett. 94, 073308 (2009)
L. Hu, S. Dai, J. Weng, S. Xiao, Y. Sui, Y. Huang, S. Chen, F. Kong, X. Pan, L. Liang, K. Wang, Microstructure design of Nanoporous TiO2 Photoelectrodes for Dye-Sensitized solar cell modules. J. Phys. Chem. B 111, 358 (2007)
T. Berger, T. Lana-Villarreal, D. Monllor-Satoca, R. Gomez, In situ infrared study of the adsorption and surface acid − base properties of the Anions of Dicarboxylic acids at Gold Single Crystal and thin-film electrodes. J. Phys. Chem. C 111, 9936 (2007)
D.D. Vuong, D.T.N. Tram, P.Q. Pho, N.D. Chienin, Phys. Eng. New Mater. 95–102
Z. Miao, D. Xu, J. Ouyang, G. Guo, X. Zhao, Y. Tang, Electrochemically induced Sol − Gel preparation of single-crystalline TiO2 nanowires. Nano Lett. 2, 717 (2002)
J.J. Wu, C.J. Yu, J. Phys. Chem. B 108, 3377 (2004)
Y.W. Jun, M.F. Casula, J.H. Sim, S.Y. Kim, J. Cheon, A.P. Alivisatos, Surfactant-assisted elimination of a high energy facet as a means of controlling the shapes of TiO2 nanocrystals. J. Am. Chem. Soc. 125, 15981 (2003)
D. Li, Y. Xia, One-dimensional nanostructures: synthesis, characterization, and applications. Nano Lett. 3, 555 (2003)
J.B. Baxter, E.S. Aydil, Dye-sensitized solar cells based on semiconductor morphologies with ZnO nanowires Sol. Energy Mater. Sol. Cells 90, 607 (2006)
V.V. Kislyuk, O.P. Dimitriev, Nanorods and nanotubes for solar cells. J. Nanosci. Nanotechnol. 8, 131 (2008)
A. Kumar, R. Jose, K. Fujihara, J. Wang, S. Ramakrishna, Structural and optical properties of electrospun TiO2 nanofibers. Chem. Mater. 19, 6536 (2007)
A. Hagfeldt, G. Boschloo, L. Sun, L. Kloo, H. Pettersson, Chem. Rev. 110, 6595 (2010)
G.S. Anjusree, A. Sreekumaran Nair, S.V. Nair, S. Vadukumpully, One-pot hydrothermal synthesis of TiO2/graphene nanocomposites for enhanced visible photocatalysis and photovoltaics. RSC Adv. (2013)
K. Sujith, A.M. Asha, P. Anjali, N. Sivakumar, K.R.V. Subramanian, S.V. Nair, A. Balakrishnan, Fabrication of highly porous conducting PANI-C composite fiber mats via electrospinning. Mater. Lett. 67, 376 (2012)
A.A. Madhavan, A. Mohandas, A. Licciulli, K.P. Sanosh, P. Praveen, R. Jayakumar, S.V. Nair, A.S. Nair, A. Balakrishnan, Electrospun continuous nanofibers based on a TiO2–ZnO-graphene composite, RSC Adv. 3, 25312 (2013)
M. Asha, K. Sujith, P. Anjali, N. Sivakumar, K.R.V. Subramanian, S.V. Nair, A. Balakrishnan, Effect of surface nanomorphology and interfacial galvanic coupling of PEDOT-Titanium counter electrodes on the stability of dye-sensitized solar cell. J. Nanosci. Nanotechnol. 12, 1 (2012)
M. Chen, H. Qu, J. Zhu, Z. Luo, A. Khasanov, A.S. Kucknoor, N. Haldolaarachchige, D.P. Young, S. Wei, Z. Guo, Polymer, 53, 4501 (2012)
S.Y. Huang, G. Schlichthorl, A.J. Nozik, M. Grätzel, A.J. Frank, Charge recombination in dye-sensitized nanocrystalline TiO2 solar cells, J. Phys. Chem. B, 101, 2576 (1997)
H.B. Choi, S.O.J.J. Ko, G.H. Gao, H.S. Kang, M.S. Kang, M.K. Nazeeruddin, M. Grätzel, Angew. Chem, 121, 6052 (2009)
Acknowledgements
The author is grateful to Dr. Shanti Nair, Dean and Management of Amrita Center for Nano sciences, Kochi, for providing infrastructure and characterization facilities for conducting the research. Author would also like to thank Dr. A Sreekumaran Nair, MRF Limited, Chennai, for his guidance and other support for conducting the research.
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Madhavan, A.A. (2020). Facile Fabrication of 1-D Hierarchical TiO2 Nanomorphology and Its Application in Dye Sensitized Solar Cell. In: Jain, V., Kumar, V., Verma, A. (eds) Advances in Solar Power Generation and Energy Harvesting. Springer Proceedings in Energy. Springer, Singapore. https://doi.org/10.1007/978-981-15-3635-9_8
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