Abstract
Wastewater adversely affects humans and another animal including metal like Pb, As, Zn, Hg, and Cd in wastewater (domestic or industrial). These toxic metals affect human health and are a serious threat to the environment by the precipitation, adsorption, accumulation in the food chain and non-biodegradable nature, respectively. In the present study, treatment of industrial wastewater in terms of toxic Pb(II) removal was investigated by the using of copper oxide alginate (CuO/Alg) nanocomposite. The CuO/Alg nanocomposite was prepared by chemical reduction method in solution phase, and synthesized particles size were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The wastewater sample collected from WWTP of the local electroplating industry is located in Okhla Industrial Area, New Delhi. A series of experimental approaches have been used to remove Pb2+ from industrial wastewater with CuO/Alg nanocomposite, which includes sorbent mass, competitive ion, contact time, and SEM. The SEM image of CuO/Alg nanocomposite showed that particles had a sheet-like shape and mean diameter of about 18.09 nm. The test was performed under the batch condition to determine the adsorption rate and uptake at equilibrium from single component solution. The maximum uptake value of Pb2+ in single component solution was 118.40 mg/g from wastewater. The CuO/Alg nanocomposite identified as the most promising sorbent with an effective potential of removal of Pb2+ from wastewater is due to their high metal uptake.
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References
Farghali AA, Bahgat M, Enaiet Allah A, Khedr MH (2013) Adsorption of Pb(II) ions from aqueous solutions using copper oxide nanostructures. Beni-Suef Univ J Basic Appl Sci 2:61–71. https://doi.org/10.1016/j.bjbas.2013.01.001
Heidari A, Younesi H, Mehraban Z (2009) Removal of Ni(II), Cd(II), and Pb(II) from a ternary aqueous solution by amino functionalized mesoporous and nano mesoporous silica. Chem Eng J 153:70–79. https://doi.org/10.1016/j.cej.2009.06.016
Liu X, Hu Q, Fang Z, Zhang X, Zhang B (2009) Magnetic chitosan nanocomposites: a useful recyclable tool for heavy metal ion removal. Langmuir 25:3–8. https://doi.org/10.1021/la802754t
Hussain M (2014) Synthesis, characterization and applications of metal oxide nanostructures. Linköping University Electronic Press, Department of Science and Technology, Linköping University
Yin P, Xu Q, Qu R, Zhao G, Sun Y (2010) Adsorption of transition metal ions from aqueous solutions onto a novel silica gel matrix inorganic–organic composite material. J Hazard Mater 173:710–716. https://doi.org/10.1016/j.jhazmat.2009.08.143
Jiang M, Wang Q, Jin X, Chen Z (2009) Removal of Pb(II) from aqueous solution using modified and unmodified kaolinite clay. J Hazard Mater 170:332–339. https://doi.org/10.1016/j.jhazmat.2009.04.092
Munagapati VS, Yarramuthi V, Nadavala SK, Alla SR, Abburi K (2010) Biosorption of Cu(II), Cd(II) and Pb(II) by Acacia leucocephala bark powder: kinetics, equilibrium and thermodynamics. Chem Eng J 157:357–365. https://doi.org/10.1016/j.cej.2009.11.015
Uheida A, Iglesias M, Fontàs C, Hidalgo M, Salvadó V, Zhang Y, Muhammed M (2006) Sorption of palladium(II), rhodium(III), and platinum(IV) on Fe3O4 nanoparticles. J Colloid Interface Sci 301:402–408. https://doi.org/10.1016/j.jcis.2006.05.015
Ruparelia JP, Duttagupta SP, Chatterjee AK, Mukherji S (2008) Potential of carbon nanomaterials for removal of heavy metals from water. Desalination 232:145–156. https://doi.org/10.1016/j.desal.2007.08.023
Mohapatra M, Anand S (2007) Studies on sorption of Cd(II) on Tata chromite mine overburden. J Hazard Mater 148:553–559. https://doi.org/10.1016/j.jhazmat.2007.03.008
Gupta VK, Agarwal S, Saleh TA (2011) Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. J Hazard Mater 185:17–23. https://doi.org/10.1016/j.jhazmat.2010.08.053
Gebru KA, Das C (2017) Removal of Pb (II) and Cu (II) ions from wastewater using composite electrospun cellulose acetate/titanium oxide (TiO 2) adsorbent. J Water Process Eng 16:1–13. https://doi.org/10.1016/j.jwpe.2016.11.008
Hassan KH, Mahdi ER (2016) Synthesis and characterization of copper, iron oxide nanoparticles used to remove lead from aquous solution. 04: 730–738
Moezzi A, Soltanali S, Torabian A, Hassani A (2017) Removal of lead from aquatic solution using synthesized iron nanoparticles. Int J Nanosci Nanotechnol 13:83–90
Hu J, Chen G, Lo IMC (2006) Selective removal of heavy metals from industrial wastewater using maghemite nanoparticle: performance and mechanisms. J Environ Eng 132:709–715. https://doi.org/10.1061/(ASCE)0733-9372(2006)132:7(709)
Afkhami A, Conway BE (2002) Investigation of Removal of Cr(VI), Mo(VI), W(VI), V(IV), and V(V) Oxy-ions from industrial waste-waters by adsorption and electrosorption at high-area carbon cloth. J Colloid Interface Sci 251:248–255. https://doi.org/10.1006/jcis.2001.8157
Yang M, He J, Hu X, Yan C, Cheng Z (2011) CuO nanostructures as quartz crystal microbalance sensing layers for detection of trace hydrogen cyanide gas. Environ Sci Technol 45:6088–6094. https://doi.org/10.1021/es201121w
Türker AR (2007) New sorbents for solid-phase extraction for metal enrichment. Clean–Soil, Air, Water 35: 548–557. https://doi.org/10.1002/clen.200700130
Ghorpade A, Ahammed MM (2017) Water treatment sludge for removal of heavy metals from electroplating wastewater. Environ Eng Res 23:92–98. https://doi.org/10.4491/eer.2017.065
Engates KE, Shipley HJ (2011) Adsorption of Pb, Cd, Cu, Zn, and Ni to titanium dioxide nanoparticles: effect of particle size, solid concentration, and exhaustion. Environ Sci Pollut Res 18:386–395. https://doi.org/10.1007/s11356-010-0382-3
Al-Saad KA, Amr MA, Hadi DT, Arar RS, Al-Sulaiti MM, Abdulmalik TA, Alsahamary NM, Kwak JC (2012) Iron oxide nanoparticles: applicability for heavy metal removal from contaminated water. Arab J Nucl Sci Appl 45:335–346
Siddiqui VU, Khan I, Ansari A, Siddiqui WA, Akram K (2018) Advances in polymer sciences and technology. Springer Singapore, Singapore
De Gisi S, Lofrano G, Grassi M, Notarnicola M (2016) Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: a review. Sustain Mater Technol 9:10–40. https://doi.org/10.1016/j.susmat.2016.06.002
Acknowledgements
The author, Afzal Ansari gratefully acknowledges for the financial assistance in terms of “Non-NET fellowship” by University Grant Commission (UGC), New Delhi. Further, the authors are also grateful to the Department of Applied Sciences, Faculty of Engineering and Technology, Jamia Millia Islamia, New Delhi, for providing the experimental facility.
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Ansari, A., Siddiqui, V.U., Akram, M.K., Siddiqi, W.A., Sajid, S. (2020). Removal of Pb(II) from Industrial Wastewater Using of CuO/Alg Nanocomposite. In: Ahmed, S., Abbas, S., Zia, H. (eds) Smart Cities—Opportunities and Challenges. Lecture Notes in Civil Engineering, vol 58. Springer, Singapore. https://doi.org/10.1007/978-981-15-2545-2_16
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