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Transient Circular Dichroism Approach to Chirality Detection in Dark Photo-Excited States

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Circularly Polarized Luminescence of Isolated Small Organic Molecules

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Abstract

A transient circular dichroism (CD)-based approach, called time-resolved circular dichroism (TRCD) spectroscopy, serves as an alternative to circularly polarized luminescence (CPL) spectroscopy for the investigation of excited-state chirality. The experimental apparatus for TRCD measurements was designed and is presented here. The Jones calculus approach to assessing experimental observables is also reported. Finally, to demonstrate the feasibility of TRCD, the CD spectrum of the photo-excited state of [6]carbohelicene is obtained.

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Authors and Affiliations

  1. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Japan

    Yasuyuki Araki

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  1. Yasuyuki Araki
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Correspondence to Yasuyuki Araki .

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Editors and Affiliations

  1. Osaka University, Suita, Japan

    Tadashi Mori

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Araki, Y. (2020). Transient Circular Dichroism Approach to Chirality Detection in Dark Photo-Excited States. In: Mori, T. (eds) Circularly Polarized Luminescence of Isolated Small Organic Molecules. Springer, Singapore. https://doi.org/10.1007/978-981-15-2309-0_15

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