Abstract
Eu3+ doped polymer nanofibers were fabricated by electrospinning technique using various polymers such as poly(vinylidene fluoride) (PVDF), polyethylene oxide (PEO), poly(vinyl pyrrolidone) (PVP) to study the influence of polymer in their photoluminescence properties. As-fabricated nanofibers were characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDX) and photoluminescence (PL). Spectral analysis of Polymer/Eu3+ nanofibers was based on their emission spectra. The photoluminescence property shows superior bright red emission spectra from the Eu3+ and relatively stronger hypersensitive behavior of the 5D0 → 7F2 transition. Eu3+ doped polymeric nanofibers are very much suitable for photoluminescent fabric designing in smart textiles. The enhanced properties of this photoluminescence indicated a more polarized chemical environment for the Eu3+ ions and greater hypersensitivity for the 5D0 → 7F2 transition, which showed the potential for application in various polymer optoelectronic devices.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
H. Timothy, G. Froerer, Photoluminescence in analysis of surfaces and interfaces, in Encyclopedia of Analytical Chemistry (2006), pp. 9209–9239
V. Prajzler, V. Lyutakov, I. Hutte, J. Oswald, V. Jerabek, Optical and spectroscopic properties of polymer layers doped with rare earth ions source, in Advances in Lasers and Electro Optics, ed. by N. Costa, A. Cartaxo (2010). ISBN 978-953-307-088-9, p. 838
S. Itankar, M. Dandekar, S. Kondawar, B. Bahirwar, Eu3+ doped polystyrene and polyvinylidene fluoride nanofibers fabricated by electrospinning for photoluminescent fabric design. J. Luminescence 32 (2017)
S. Tang, C. Shao, M.R. Yichun, Electrospun nanofibers of poly(acrylonitrile)Eu3+ and their photoluminescent properties. J. Phys. Chem. Solids 71, 273–278 (2010)
S. Tang, C. Shao, Y.C. Li, Electrospun nanofibers of poly (vinyl pyrrolidone)/Eu3+ and its photoluminescence properties. Chin. Chem. Lett. 18, 465–468 (2007)
J. Liang, F. Xie, X. Ren, Y. Chen, B. Chen, F. Guo, Temperature dependent luminescence of a europium complex incorporated in poly(methyl methacrylate). Mol. Biomol. Spectrosc. 116, 317–320 (2013)
M. Dandekar, S. Kondawar, S. Itankar, D. Nandanwar, Luminescence properties of electrospun nanofibers of europium complex Eu(TTA)3phen/polymers. Procedia Mater. Sci. 10, 580–587 (2015)
X. Li, G. Shen, X. Jin, M. Liu, L. Shi, J. Lu, Novel polyimide containing 1,10-phenanthroline and its europium (III) complex: synthesis, characterization and luminescence properties. J. Mater. Sci. 51, 2072–2078 (2016)
S. Tang, S. Shao, S. Li, Electrospun nanofibers of poly (vinyl pyrrolidone)/Eu3+ and its photoluminescence properties. Chin. Chem. Lett. 18, 465–468 (2007)
S. Tang, C. Shao, Y. Liu, R. Mu, Electrospun nanofibers of poly(acrylonitrile)/Eu3+ and their photoluminescence properties. J. Phys. Chem. Solids 71, 273–278 (2010)
Z. Zhang, Y. Long, H. Yin, B. Sun, J. Zheng, H. Zhang, X. Ji, C. Gu, Electrospun fluorescein/polymer composite nanofibers and their photoluminescent properties. Chin. Phys. B. 21, 097805-1-6 (2012)
S. Itankar, M. Dandekar, S. Kondawar, B. Bahirwar, Comparative photoluminescent study of PVDF/Eu3+ and PEO/Eu3+ electrospun nanofibers in photonic fabric. AIP Conf. Proc. 2104, 1 (2019)
S. Itankar, M. Dandekar, S. Kondawar, B. Bahirwar, Synthesis and characterization of electrospun Eu3+ doped poly(methylmethacrylate) nanofibers. Int. J. Res. Biosci. Agric. Technol. 1, 419–425 (2014)
M. Mondragon, G. Trujillo, I. Moggio, E. Arias, Luminescent polylactic acid and polysulfone electrospun fibers containing europium (III) complexes. Eur. Polymer J. 80, 126–133 (2016)
J. Zhao, W. Zang, E. Xie, Z. Ma, A. Zhao, Z. Liu, Structure and photoluminescence of Ga2O3:Eu3+ nanofibers prepared by electrospinning. Appl. Surf. Sci. 275, 4968–4972 (2011)
R. Argauer, C. White, Fluorescent compounds for calibration of excitation and emission unit of spectroflurometer. Anal. Chem. 36, 368–371 (1964)
K. Sivaiah, S. Buddhudu, Light emission in Tb3+ and Eu3+ polymer films. Indian J. Pure Appl. Phys. 49, 377–381 (2011)
L. Saravanan, S. Diwakar, R. Mohankumar, A. Pandurangan, R. Jayavel, Synthesis, structural and optical properties of PVP encapsulated CdS nanoparticles. Nanomater. Nanotechnol. 1, 42–48 (2011)
Y. Tao, P. Yan, C. Wang, G. Li, Luminescent electrospun composite nanofibers of [Eu(TFI)3(Phen)].CHCl3/polyvinylpyrrolidone. J. Mater. Sci. 48, 6682–6688 (2013)
X. Zhang, S. Wen, L. Zhang, L. Liu, Electrospinning preparation and luminescence properties of Eu(TTA)3phen/polystyrene composite nanofibers. J. Rare Earths 28, 333–338 (2010)
Acknowledgements
This work was supported by the Department of Science and Technology (DST, New Delhi, India) Support under DST-FIST Program, Grant No. SR/FST/PSI-178/2012(C).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Itankar, S.G., Dandekar, M.P., Koinkar, P.M., Kondawar, S.B. (2020). Influence of Polymer in Photoluminescence Properties of Electrospun Eu3+ Doped Polymer Nanofibers. In: Murakami, RI., Koinkar, P., Fujii, T., Kim, TG., Abdullah, H. (eds) NAC 2019. Springer Proceedings in Physics, vol 242. Springer, Singapore. https://doi.org/10.1007/978-981-15-2294-9_10
Download citation
DOI: https://doi.org/10.1007/978-981-15-2294-9_10
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-15-2293-2
Online ISBN: 978-981-15-2294-9
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)