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Surface Phosphorylated Activated Carbons: Preparation and Acidity Studies

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Microstructure and Properties of Micro- and Nanoscale Materials, Films, and Coatings (NAP 2019)

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 240))

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Abstract

Here we report on the phosphorylation of activated carbon (AC) at 500–800 °C. From thermal, titrimetric, and catalytic data, high surface acidity of the prepared solids is attributed to the total concentration of the protogenic groups. Transmission electron microscopy and nitrogen physisorption measurements showed a chemisorption-induced contraction of microporosity. The most active catalysts prepared at 700 °C contain 1.04 mmol g−1 of the phosphonic groups and supports dehydration of isopropanol with about 100% conversion and 100% selectivity to propylene at 170–180 °C.

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References

  1. V.E. Diyuk, V.V. Lisnyak, R. Mariychuk, in Renewable Energy Sources: Engineering, Technology, Innovation, Springer Proceedings in Energy, ed. by M. Wróbel, A. Szlęk, M. Jewiarz et al. (Springer Nature, Cham, 2020), pp. 59–67

    Google Scholar 

  2. L.M. Grishchenko, V.E. Diyuk, R.T. Mariychuk, A.V. Vakaliuk, V.Z. Radkevich, S.G. Khaminets, O.V. Mischanchuk, V.V. Lisnyak, Appl. Nanosci. 1–17 (2019). https://doi.org/10.1007/s13204-019-01069-3

  3. L.M. Grishchenko, A.V. Vakaliuk, V.E. Diyuk, O.V. Mischanchuk, O.Yu. Boldyrieva, T.M. Bezugla, V.V. Lisnyak, Mol. Cryst. Liq. Cryst. 673, 1 (2018)

    Article  Google Scholar 

  4. A. Singh, P.S. Nigam, in Microbial Biotechnology: Progress and Trends, ed. by F.D. Harzevili, H. Chen (CRC Press, Boca-Raton, 2017), pp. 155–169

    Google Scholar 

  5. K. Bulkowska, Z. Gusiatin, E. Klimiuk, A. Pawlowski, T. Pokoj, Biomass for Biofuels, 1st edn. (CRC Press, London, 2016), p. 188

    Book  Google Scholar 

  6. M. Balat, H. Balat, C. Öz, Prog. Energy. Comb. Sci. 38, 551–573 (2008)

    Article  Google Scholar 

  7. M. Toda, A. Takagaki, M. Okamura, J.N. Kondo, S. Hayashi, K. Domen, M. Hara, Nature 438, 178 (2005)

    Article  ADS  Google Scholar 

  8. V.E. Diyuk, A.N. Zaderko, L.M. Grishchenko, A.V. Yatsymyrskiy, V.V. Lisnyak, Catal. Commun. 27, 33 (2012)

    Article  Google Scholar 

  9. T.M. Bezugla, L.M. Grishchenko, A.V. Vakaliuk, V.E. Diyuk, O.V. Mischanchuk, V.V. Lisnyak, Mol. Cryst. Liq. Cryst. 661, 58 (2018)

    Article  Google Scholar 

  10. J. Bedia, J.M. Rosas, D. Vera, J. Rodríguez-Mirasol, T. Cordero, Catal. Today 158, 89 (2010)

    Article  Google Scholar 

  11. J. Bedia, R. Barrionuev, J. Rodríguez-Mirasol, T. Cordero, Appl. Catal. B Environ. 103, 302 (2011)

    Article  Google Scholar 

  12. A. Villa, M. Schiavoni, P.F. Fulvio, S.M. Mahurin, S. Dai, R.T. Mayes, G.M. Veith, L. Prati, J. Energy Chem. 22, 305 (2013)

    Article  Google Scholar 

  13. L. Wang, X. Dong, H. Jiang, G. Li, M. Zhang, Catal. Commun. 56, 164 (2014)

    Article  Google Scholar 

  14. J. Bedia, R. Ruiz-Rosas, J. Rodriguez-Mirasol, T. Cordero, AIChE J. 56, 1557 (2010)

    Article  Google Scholar 

  15. A.M. Puziy, O.I. Poddubnaya, A. Martinez-Alonso, T. Cordero, Carbon 40, 1493 (2002)

    Article  Google Scholar 

  16. J.M. Rosas, R. Ruiz-Rosas, J. Rodriguez-Mirasol, T. Cordero, Kinetic study of the oxidation resistance of phosphorus-containing activated carbons. Carbon 50, 1523 (2012)

    Article  Google Scholar 

  17. M.M. Rahman, S.H. Samsuddin, M.F. Miskon, K. Yunus, A.M. Yusof, Green Chem. Lett. Rev. 8, 9 (2015)

    Article  Google Scholar 

  18. J. Bedia, M. Peñas-Garzón, A. Gómez-Avilés, J.J. Rodriguez, C. Belver, Carbon 4, 63 (2018)

    Article  Google Scholar 

  19. R.G. Pereira, C.M. Veloso, N.M. da Silva, L.F. Sousa, R.C.F. Bonomo, A.O. Souza, M.O. da Guarda Souza, R. da Costa Ilhéu Fontan, Fuel Proc. Technol. 126, 476 (2014)

    Article  Google Scholar 

  20. N. Suganthi, K. Srinivasan, J. Environ. Sci. Eng. 53, 163 (2011)

    Google Scholar 

  21. R.H. Hesas, A. Arami-Niya, W.M.A.W. Daud, J.N. Sahu, BioResources 8, 2950 (2013)

    Google Scholar 

  22. C.-X. Chen, B. Huang, T. Li, G.-F. Wu, BioResources 75, 5109 (2012)

    Google Scholar 

  23. J. Xu, L. Chen, H. Qu, Y. Jiao, J. Xie, G. Xing, Appl. Surf. Sci. 320, 674 (2014)

    Article  ADS  Google Scholar 

  24. M.A. Nahil, P. Williams, Biomass Bioenerg. 37, 142 (2012)

    Article  Google Scholar 

  25. C.L. Lee, P.S. H’ng, M.T. Paridah, K.L. Chin, U. Rashid, M. Maminski, W.Z. Go, R.A.R. Nazrin, S.N.A. Rosli, P.S. Khoo, R. Soc. Open Sci. 5, 180775 (2018)

    Article  Google Scholar 

  26. S. Zuo, Chem. Indus. Forest. Prod. 37, 1 (2017)

    Google Scholar 

  27. V.E. Diyuk, A.N. Zaderko, K. Veselovska, V.V. Lisnyak, J. Thermal. Anal. Calorim. 120, 1665 (2016)

    Article  Google Scholar 

  28. V.E. Diyuk, R.T. Mariychuk, V.V. Lisnyak, J. Thermal. Anal. Calorim. 124, 1119 (2016)

    Article  Google Scholar 

  29. L.M. Grishchenko, V.E. Diyuk, O.P. Konoplitska, V.V. Lisnyak, R.T. Maryichuk, Adsorption Sci. Technol. 35, 884 (2017)

    Article  Google Scholar 

  30. J.L. Figueiredo, M.F.R. Pereira, M.M.A. Freitas, J.J.M. Órfão, Carbon 38, 1379 (1999)

    Article  Google Scholar 

  31. X. Wu, L.R. Radovic, Carbon 44, 141 (2006)

    Article  Google Scholar 

  32. J.M. Rosas, J. Bedia, J. Rodríguez-Mirasol, T. Cordero, Fuel 88, 19 (2009)

    Article  Google Scholar 

  33. J.M. Rosas, R. Ruiz-Rosas, J. Rodríguez-Mirasol, T. Cordero, Carbon 50, 1523 (2012)

    Article  Google Scholar 

  34. J.M. Rosas, R. Berenguer, M.J. Valero-Romero, J. Rodríguez-Mirasol, T. Cordero, Front. Mater. 1, 29 (2014)

    Article  Google Scholar 

  35. V. Ye Diyuk, R.T. Mariychuk, V.V. Lisnyak, Mater. Chem. Phys. 184, 138 (2016)

    Article  Google Scholar 

  36. T.J. Mays, Stud. Surf. Sci. Catal. 160, 57 (2007)

    Article  Google Scholar 

  37. M. Thommes, K. Kaneko, A.V. Neimark, J.P. Olivier, F. Rodriguez-Reinoso, J. Rouquerol, K.S.W. Sing, Pure Appl. Chem. 87, 1051 (2015)

    Article  Google Scholar 

  38. J. Jagiello, J.P. Olivier, Carbon 55, 70 (2013)

    Article  Google Scholar 

  39. A.M. Puziy, O.I. Poddubnaya, B. Gawdzik, M. Sobiesiak, Adsorption 22, 459 (2016)

    Article  Google Scholar 

  40. J. Jagiello, J.P. Olivier, Adsorption 19, 777 (2013)

    Article  Google Scholar 

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Acknowledgements

V.V. Lisnyak thanks the Slovak Academic Information Agency (SAIA) for grant ID [20917] and acknowledges the International Visegrad Fund for scholarship ID number [51810574] in 2018.

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Authors and Affiliations

  1. Taras Shevchenko National University of Kyiv, Kyiv, 01601, Ukraine

    V. E. Diyuk, A. V. Yatsymyrskyi, L. M. Grishchenko, D. S. Horodetska, A. V. Vakaliuk, A. N. Zaderko & V. V. Lisnyak

  2. Chuiko Institute of Surface Chemistry of the National Academy of Science of Ukraine, Kyiv, 03164, Ukraine

    A. V. Mischanchuk

Authors
  1. V. E. Diyuk
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  2. A. V. Yatsymyrskyi
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  4. D. S. Horodetska
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  5. A. V. Vakaliuk
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  6. A. V. Mischanchuk
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Correspondence to V. V. Lisnyak .

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Editors and Affiliations

  1. Sumy State University, Sumy, Ukraine

    Alexander D. Pogrebnjak

  2. Sumy State University, Sumy, Ukraine

    Oleksandr Bondar

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Diyuk, V.E. et al. (2020). Surface Phosphorylated Activated Carbons: Preparation and Acidity Studies. In: Pogrebnjak, A., Bondar, O. (eds) Microstructure and Properties of Micro- and Nanoscale Materials, Films, and Coatings (NAP 2019). Springer Proceedings in Physics, vol 240. Springer, Singapore. https://doi.org/10.1007/978-981-15-1742-6_22

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  • DOI: https://doi.org/10.1007/978-981-15-1742-6_22

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  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-15-1741-9

  • Online ISBN: 978-981-15-1742-6

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