Abstract
Clay liners are commonly used in landfills to avoid the contaminant migration from the waste to the groundwater and the surrounding environment. Bentonite contains montmorillonite mineral that offers favourable properties such as low hydraulic conductivity, high adsorption capacity, high cation exchange capacity and capacity to retard the percolation of pollutant through sorption. However, properties of bentonite can be affected due to the presence of various heavy metals in the leachate. The present investigation was conducted to examine the change in hydraulic conductivity and sorption capacity of bentonites in the presence of zinc (Zn2+). Two different bentonites with different swelling, chemical and mineralogical composition were exposed to a series of consolidation test and batch study to examine the hydraulic conductivity and metal adsorption capacity for the geoenvironmental application. Langmuir and Freundlich models were used in order to understand the adsorption mechanism. Tests were performed at a various concentration of Zn2+ ranges from 100 to 1000 mg/L at room temperature and pH 5. The results indicate that with the increase in metal concentration hydraulic conductivity increases. Bentonite with a higher swelling capacity shows higher removal percentage and sorption capacity in comparison to bentonite of lower swelling capacity. The isotherm study predicts that equilibrium data obtained from the study fitted well with the Langmuir model. The study will assist the designer and engineer for opting bentonite type in the various geoenvironmental application.
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References
ASTM (1996) Standard test method for one-dimensional consolidation properties of soils. D 2435. American Society for Testing and Materials Philadelphia
ASTM (2000) Standard test methods for liquid limit, plastic limit, and plasticity index of soils. D 4318. American Society for Testing and Materials Philadelphia
ASTM (2008) Standard test methods for 24-h batch type measurement of contaminant sorption by soils and sediments. D4646-03. American Society for Testing and Materials West Conshohocken
ASTM (2012) Standard test methods for laboratory compaction characteristics of soil using standard effort. D 698, American Society for Testing and Materials Philadelphia
Barbier F, Duc G, Petit-Ramel M (2000) Adsorption of lead and cadmium ions from aqueous solution to the montmorillonite/water interface. Colloids Surf A 166:153–159
Baylan N, Meriçboyu AE (2016) Adsorption of lead and copper on bentonite and grape seed activated carbon in single-and binary-ion systems. Sep Sci Technol 51(14):2360–2368
Cerato AB, Lutenegger AJ (2002) Determination of surface area of fine-grained soils by the ethylene glycol monoethyl ether (EGME) method. Geotech Test J 25:1–7
Chapman HD (1965) Cation exchange capacity, Methods of soil analysis, part 2, chemical and microbiological properties, 2nd edn. Soil Science Society of America, Madison, Wisconsin, USA, pp 891–895
Dutta J, Mishra AK (2016) Influence of the presence of heavy metals on the behaviour of bentonites. Environ Earth Sci 75(11):1–10
Freitas ED, Carmo ACR, Neto AA, Vieira MGA (2017) Binary adsorption of silver and copper on Verde-lodo bentonite: kinetic and equilibrium study. Appl Clay Sci 137:69–76
Freundlich H (1906) Over the adsorption in solution. J Phys Chem 57:385–470
Langmuir I (1918) The adsorption of gases on plane surface of glass, mica and platinum. J Am Chem Soc 40:1361–1368
Liu ZR, Zhou SQ (2010) Adsorption of copper and nickel on Na-bentonite. Process Saf Environ Prot 88(1):62–66
Lo I, Luk A, Yang X (2004) Migration of heavy metals in saturated sand and bentonite/soil admixture. J Environ Eng 130(8):906–909. https://doi.org/10.1061/(ASCE)0733-9372(2004)130:8(906)
Mellah A, Chegrouche S (1997) The removal of zinc from aqueous solutions by natural bentonite. Water Res 31(3):621–629
Mishra AK, Ohtsubo M, Li LY, Higashi T (2010) Influence of the bentonite on the consolidation behaviour of soil bentonite mixtures. Carbonates Evaporites 25(1):43–49
Nakano A, Li LY, Ohtsubo M, Mishra AK (2008) Lead retention mechanisms and hydraulic conductivity studies of various bentonites for geoenvironment applications. Environ Technol 29:505–514
Ouhadi VR, Sedighi M (2003) Variation of experimental results of oedometer testing due to the changes of pore fluid. Deformation characteristics of geomaterials. A.A. Balkema, Rotterdam, Netherlands, pp 299–304
Ouhadi VR, Yong RN, Sedighi M (2006) Influence of heavy metal contaminants at variable pH regimes on rheological behaviour of bentonite. Appl Clay Sci 32:217–231
Potgieter JH, Potgieter-Vermaak SS, Kalibantonga PD (2006) Heavy metals removal from solution by palygorskite clay. Miner Eng 19(5):463–470
Pratt PF (1965) Sodium, methods of soil analysis, Part 2 chemical and microbiological properties, 2nd edn. Soil Science Society of America, Madison, Wisconsin, USA, pp 1031–1034
Sanchez AG, Ayuso EA, Blas O (1999) Sorption of heavy metals from industrial waste water by low-cost mineral silicates. Clay Miner 34(3):469–469
Taylor DW (1948) Fundamentals of soil mechanics. Wiley, New York
Terzaghi K (1943) Theoretical soil mechanics. Wiley, New York
Yavuz Ö, Altunkaynak Y, Güzel F (2003) Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Res 37(4):948–952
Yong RN, Warkentin BP (1975) Soil properties and behaviour. Elsevier, New York
Zhang X, Yang L, Li Y, Li H, Wang W, Ye B (2012) Impacts of lead/zinc mining and smelting on the environment and human health in China. Environ Monit Assess 184(4):2261–2273
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Ray, S., Mishra, A.K., Kalamdhad, A.S. (2020). Adsorption and Hydraulic Conductivity Studies on Bentonites in the Presence of Zinc. In: Prashant, A., Sachan, A., Desai, C. (eds) Advances in Computer Methods and Geomechanics . Lecture Notes in Civil Engineering, vol 55. Springer, Singapore. https://doi.org/10.1007/978-981-15-0886-8_40
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