Abstract
The working fluids are very important for absorption cycles. They can not only affect the heating/cooling efficiency, but also determine the operating temperature range, cycle configuration, cost-effectiveness, safety, environmental-friendliness and so on. The most widely used working fluids are H2O/LiBr and NH3/H2O. H2O/LiBr has high efficiency but suffers from crystallization and disability to operate under sub-zero evaporation temperatures. NH3/H2O are suitable for low evaporation temperatures, but it usually requires rectification to increase the purity of the refrigerant. In addition, the NH3-based working fluids may not be used in some applications due to the safety concern. To address this problem, the HFC-based working fluids are alternative options. However, some HFCs need to be phased out due to their high global warming potential (GWP). Therefore, the low-GWP HFC-based and HFO-based working fluids are proposed. Advances in different novel working fluids are summarized, aiming for various objectives, including increasing efficiency, avoiding crystallization, avoiding rectification, increasing safety, as well as increasing sustainability. Noted that the introduced studies are mainly for absorption heating, with some also for absorption cooling, which can also be referenced for heating applications.
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References
Abumandour, E. S., Mutelet, F., & Alonso, D. (2016). Performance of an absorption heat transformer using new working binary systems composed of {ionic liquid and water}. Applied Thermal Engineering, 94, 579–589.
Abumandour, E. S., Mutelet, F., & Alonso, D. (2017). Are ionic liquids suitable as new components in working mixtures for absorption heat transformers? In Progress and Developments in Ionic Liquids. InTech.
Boman, D. B., Hoysall, D. C., Staedter, M. A., Goyal, A., Ponkala, M. J., & Garimella, S. (2017). A method for comparison of absorption heat pump working pairs. International Journal of Refrigeration, 77, 149–175.
Chen, W., & Bai, Y. (2016). Thermal performance of an absorption-refrigeration system with [emim] Cu2Cl5/NH3 as working fluid. Energy, 112, 332–341.
Chen, W., & Liang, S. (2016). Thermodynamic analysis of absorption heat transformers using [mmim] DMP/H2O and [mmim]DMP/CH3OH as working fluids. Applied Thermal Engineering, 99, 846–856.
Chen, W., Liang, S., Guo, Y., Cheng, K., Gui, X., & Tang, D. (2012). Thermodynamic performances of [mmim] DMP/methanol absorption refrigeration. Journal of Thermal Science, 21(6), 557–563.
Chen, W., Liang, S., Guo, Y., & Tang, D. (2014). Thermodynamic analysis of an absorption system using [bmim] Zn2Cl5/NH3 as the working pair. Energy Conversion and Management, 85, 13–19.
Dong, L., Zheng, D., Li, J., Nie, N., & Wu, X. (2013). Suitability prediction and affinity regularity assessment of H2O + imidazolium ionic liquid working pairs of absorption cycle by excess property criteria and UNIFAC model. Fluid Phase Equilibria, 348, 1–8.
Dong, L., Zheng, D., Nie, N., & Li, Y. (2012a). Performance prediction of absorption refrigeration cycle based on the measurements of vapor pressure and heat capacity of H2O + [DMIM] DMP system. Applied Energy, 98, 326–332.
Dong, L., Zheng, D. X., & Wu, X. H. (2012b). Working pair selection of compression and absorption hybrid cycles through predicting the activity coefficients of hydrofluorocarbon + ionic liquid systems by the UNIFAC model. Industrial and Engineering Chemistry Research, 51(12), 4741–4747.
Kim, Y. J., Kim, S., Joshi, Y. K., Fedorov, A. G., & Kohl, P. A. (2012). Thermodynamic analysis of an absorption refrigeration system with ionic-liquid/refrigerant mixture as a working fluid. Energy, 44(1), 1005–1016.
Kim, S., & Kohl, P. A. (2013). Theoretical and experimental investigation of an absorption refrigeration system using R134/[bmim][PF6] working fluid. Industrial and Engineering Chemistry Research, 52(37), 13459–13465.
Kim, S., Patel, N., & Kohl, P. A. (2013). Performance simulation of ionic liquid and hydrofluorocarbon working fluids for an absorption refrigeration system. Industrial and Engineering Chemistry Research, 52(19), 6329–6335.
Martín, Á., & Bermejo, M. D. (2010). Thermodynamic analysis of absorption refrigeration cycles using ionic liquid + supercritical CO2 pairs. The Journal of Supercritical Fluids, 55(2), 852–859.
NIST Standard Reference Database 23. (2013). NIST reference fluid thermodynamic and transport properties–REFPROP, v9.1.
Ruiz, E., Ferro, V. R., De Riva, J., Moreno, D., & Palomar, J. (2014). Evaluation of ionic liquids as absorbents for ammonia absorption refrigeration cycles using COSMO-based process simulations. Applied Energy, 123, 281–291.
Smith, J. M., Van Ness, H. C., & Abbott, M. M. (2002). Introduction to chemical engineering thermodynamics (6th ed.). New York: McGraw-Hill.
Sun, G. M., Hunag, W. J., Zheng, D. X., Dong, L., & Wu, X. H. (2014). Vapor-liquid equilibrium prediction of ammonia-ionic liquid working pairs of absorption cycle using UNIFAC model. Chinese Journal of Chemical Engineering, 22(1), 72–78.
Vega, L. F., Vilaseca, O., Llovell, F., & Andreu, J. S. (2010). Modeling ionic liquids and the solubility of gases in them: recent advances and perspectives. Fluid Phase Equilibria, 294(1), 15–30.
Wang, M., Becker, T. M., & Ferreira, C. A. I. (2017). Assessment of vapor-liquid equilibrium models for ionic liquid based working pairs in absorption cycles. International Journal of Refrigeration. https://doi.org/10.1016/j.ijrefrig.2017.09.021.
Wang, M., & Infante Ferreira, C. A. (2016). Screening criteria for ILs used in NH3 based absorption heat pump systems. In International Refrigeration and Air Conditioning Conference. Paper 1690. http://docs.lib.purdue.edu/iracc/1690.
Wang, J. Z., & Zheng, D. X. (2008). Performance analysis of absorption cooling cycle utilizing TFE-[BMIm]Br as working fluid. Journal of Engineering Thermophysics, 29(11), 1813–1816.
Wu, W. (2019). Novel ionic-liquid-based low-GWP working fluids used for hybrid low-temperature absorption cooling. Energy Procedia, 158, 1620–1625.
Wu, W., Wang, B., Shi, W., & Li, X. (2013). Crystallization analysis and control of ammonia-based air source absorption heat pump in cold regions. Advances in Mechanical Engineering, 5, 140341.
Wu, W., Wang, B., You, T., Wang, J., Shi, W., & Li, X. (2018a). Compression-assisted absorption cycles using ammonia and various ionic liquids for cleaner heating. Journal of Cleaner Production, 195, 890–907.
Wu, W., You, T., Zhang, H., & Li, X. (2018b). Comparisons of different ionic liquids combined with trans-1, 3, 3, 3-tetrafluoropropene (R1234ze (E)) as absorption working fluids. International Journal of Refrigeration, 88, 45–57.
Wu, W., Zhang, X., Li, X., Shi, W., & Wang, B. (2012). Comparisons of different working pairs and cycles on the performance of absorption heat pump for heating and domestic hot water in cold regions. Applied Thermal Engineering, 48, 349–358.
Wu, W., Zhang, H., You, T., & Li, X. (2017a). Thermodynamic investigation and comparison of absorption cycles using hydrofluoroolefins and ionic liquid. Industrial and Engineering Chemistry Research, 56(35), 9906–9916.
Wu, W., Zhang, H., You, T., & Li, X. (2017b). Performance comparison of absorption heating cycles using various low-GWP and natural refrigerants. International Journal of Refrigeration, 82, 56–70.
Yokozeki, A., & Shiflett, M. B. (2007). Vapor–liquid equilibria of ammonia + ionic liquid mixtures. Applied Energy, 84(12), 1258–1273.
Yokozeki, A., & Shiflett, M. B. (2010). Water solubility in ionic liquids and application to absorption cycles. Industrial and Engineering Chemistry Research, 49(19), 9496–9503.
Zhang, X., & Hu, D. (2011). Performance simulation of the absorption chiller using water and ionic liquid 1-ethyl-3-methylimidazolium dimethylphosphate as the working pair. Applied Thermal Engineering, 31(16), 3316–3321.
Zhang, X., & Hu, D. (2012). Performance analysis of the single-stage absorption heat transformer using a new working pair composed of ionic liquid and water. Applied Thermal Engineering, 37, 129–135.
Zheng, D., Dong, L., Huang, W., Wu, X., & Nie, N. (2014). A review of imidazolium ionic liquids research and development towards working pair of absorption cycle. Renewable and Sustainable Energy Reviews, 37, 47–68.
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Wu, W., Li, X., You, T. (2020). Advances in Novel Working Fluids for Absorption Heat Pump. In: Absorption Heating Technologies. Springer, Singapore. https://doi.org/10.1007/978-981-15-0470-9_7
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DOI: https://doi.org/10.1007/978-981-15-0470-9_7
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