Abstract
The thermal degradation of unsaturated polyester resin and composite fiberglass containing aluminum phosphate as additive flame retardant were investigated. A new phosphate type fire retardant is developed using aluminum phosphate embedded in unsaturated polyester resin with varies weight ratio (0–50%). The modified unsaturated polyester then combined with seven layer of fiberglass reinforcement to produce composite fiberglass boat panels. The effects of aluminum phosphate on structural and thermal properties were evaluated on both unsaturated polyester resin and composite fiberglass using Fourier Transform Infrared (FTIR) and thermogravimetric analysis (TGA). Addition of aluminum phosphate in modified unsaturated polyester observed increases in weight residue due to formation char layer. Thermal properties and structural bonding observed in both modified unsaturated polyester and composite fiberglass show that oxygen has a great influenced in the interaction between phosphate group, aluminum and silica in both systems.
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References
Beyler CL Hirschler MM (2005) Thermal decomposition of polymers. In: SFPE handbook of fire protection engineering, 3rd edn, pp 110–131
Leopoldshafen E, Dresden P, Str H (2012) Phosphorus polyesters as halogen-free polymeric flame retardants in poly(butylene terephthalate)—influence of the chemical structure
Ricciardi MR, Antonucci V, Giordano M, Zarrelli M (2012) Thermal decomposition and fire behavior of glass fiber-reinforced polyester resin composites containing phosphate-based fire-retardant additives. J Fire Sci 30(4):318–330
Hapuarachchi TD, Peijs T (2009) Aluminium trihydroxide in combination with ammonium polyphosphate as flame retardants for unsaturated polyester resin. Express Polym. Lett. 3(11):743–751
Saat AM, Malik AA, Azmi A, Latif MFA, Ramlee NE, Johan MR (2017) Effect of aluminum phosphate on structural and flame retardant properties of composites fibreglass. ARPN J Eng Appl Sci 12(4):1315–1318
Saat AM, Johan MR (2017) Enhanced thermal and structural properties of partially phosphorylated polyvinyl alcohol—aluminum phosphate (PPVA-AlPO4) nanocomposites with aluminium nitrate source. AIP Conf Proc 1901(130011):1–8
Bastiurea M, Rodeanu MS, Dima D, Murarescu M, Andrei G (2015) Thermal and mechanical properties of polyester composites with graphene oxide and graphite. Dig J Nanomater Biostructures 10(2):521–533
Pan LL, Li GY, Su YC, Lian JS (2012) Fire retardant mechanism analysis between ammonium polyphosphate and triphenyl phosphate in unsaturated polyester resin. Polym Degrad Stab 97(9):1801–1806
Al Bayaty SA, Farhan AJ (2015) Polyester and unsaturated polyester reinforcement by Toner Carbon Nano Powder (TCNP) composites. Int J Appl Innov Eng Mange 4(3):139–146
Siddharthan KS, Mohan S, Elayaperumal A (2014) Mechanical and thermal properties of glass/polyester composite with glycerol as additive. Int J Eng Trends Technol 7(2):61–64
Saat AM, Johan MR (2016) Effect of aluminum source on the structural and thermal properties of partially phosphorylated polyvinyl alcohol composite (PPVA)—aluminum phosphate (PPVA-AlPO4) nanocomposite. Key Eng Mater 701(3):291–294
Acknowledgements
This work was financially supported by UniKL Short Term Grant (UniKL/Cori/STRG/16035 & UniKL/Cori/STRG/15126). Author also appreciates of the collaboration with Nanotechnology and Catalyst Research, Universiti Malaya, Kuala Lumpur, Malaysia. The author gratefully acknowledge on both of support.
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Saat, A.M. et al. (2020). Thermal Degradation of Unsaturated Polyester and Composite Fiberglass Embedded with Aluminium Phosphate. In: Saw, C., Woo, T., a/l Karam Singh, S., Asmara Bin Salim, D. (eds) Advancement in Emerging Technologies and Engineering Applications. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-15-0002-2_13
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DOI: https://doi.org/10.1007/978-981-15-0002-2_13
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