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Multifield Coupling

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Solvation Dynamics

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 121))

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Abstract

Transiting the NaX/H2O solutions from liquid into ice VI (at PC1) and then into ice VII (PC2) phase at 298 K needs excessive pressures with respect to the same sequence of phase transition for pure water. PC1 and PC2 vary simultaneously with the solute type in the Hofmeister series order: I > Br > Cl > F ~ 0. However, the PC1 grows faster than the PC2 with the increase of NaI/H2O concentration, following the (P, T) path upwardly along the Liquid-VI phase boundary. The PC1 and PC2 meet then at the Liquid-VI-VII triple-phase junction at 3.3 GPa and 350 K. Observations confirmed that compression recovers the electrification-elongated O:H–O bond first and then proceeds the phase transitions, which requires excessive energy for the same sequence of phase transitions. Heating enhances the effect of salting on bond relaxation but opposite on polarization that dictates the surface stress of the solution. It is also confirmed that molecular undercoordination disperses the quasisolid phase boundaries and the room-temperature ice-quasisolid phase transition needs excessive pressure. Polarization by salt solvation and skin undercoordination and boundary reflection transit the phonon abundance-lifetime-stiffness cooperatively. An extension of the HB and anti-HB or super-HB clarifies the energetic storage and structural stability for the spontenous and constrained explosion of energetic carriers.

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  1. School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore, Singapore

    Prof. Dr. Chang Q Sun

  2. Yangtze Normal University, 408100, Chongqing, China

    Prof. Dr. Chang Q Sun

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Sun, C.Q. (2019). Multifield Coupling. In: Solvation Dynamics. Springer Series in Chemical Physics, vol 121. Springer, Singapore. https://doi.org/10.1007/978-981-13-8441-7_8

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