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Solvation Dynamics pp 103–127Cite as

Lewis Basic and H2O2 Solutions: O:⇔:O Compression

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Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 121))

Abstract

The OH− and the H2O2 possess each two excessive pairs of electron lone pairs “:” that form an O:⇔:O super−HB upon solvation. The O:⇔:O compression shortens the O:H nonbond and stiffens its phonon but relaxes the H–O bond oppositely. The H–O bond elongation emits energy to heat up the solution. Bond-order-deficiency shortens the solute H–O bond and stiffens its phonon to 3550 cm−1 for H2O2 and 3610 cm−1 for OH−. However, the O:⇔:O compression annihilates the weak cationic polarization. The H2O2 is less than the OH− capable of transiting the solvent H–O bonds and surface stress. The linear fraction coefficient f(C) suggests that the OH− be less sensitive to other solutes. The resultant of solvent exothermic H–O elongation by O:⇔:O compression and the solute endothermic H–O contraction by bond order deficiency heats up the solutions. Observations evidence not only the significance of the inter-lone-pair interaction but also the universality of the bond order-length-strength (BOLS) correlation to aqueous solutions.

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  1. School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore, Singapore

    Prof. Dr. Chang Q Sun

  2. Yangtze Normal University, 408100, Chongqing, China

    Prof. Dr. Chang Q Sun

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Sun, C.Q. (2019). Lewis Basic and H2O2 Solutions: O:⇔:O Compression. In: Solvation Dynamics. Springer Series in Chemical Physics, vol 121. Springer, Singapore. https://doi.org/10.1007/978-981-13-8441-7_5

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