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Optimization of Delignification Process from Red Meranti Wood Sawdust (RMWS) Pretreated with Acidified Sodium Chlorite

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Advances in Material Sciences and Engineering

Abstract

Delignification is a process to remove the lignin content from lignocellulosic biomass to increase hydrolysis efficiency. In other word, the process ensures cellulose parts are more accessible. In the present research, there are two objectives; (i) to optimize the operating parameters of acidified sodium chlorite pretreatment for delignification of RMWS, and (ii) to characterize the RMWS used as feedstock. The two significant variables, reaction temperature and ratio of sodium chlorite to sawdust were optimized using response surface methodology and experiments were performed according to a central composite experimental design in order to enhance the delignification process as well as holocellulose recovery. The experimental design was expressed based on preliminary work and screening process using the combined severity, which ranged from 0.76 to 1.64 for chlorite solution and temperature range from 65 to 85 °C. The experimental results showed the most optimal condition of acidified pretreatment of RMWS was 1.42 for the ratio of sodium chlorite to RMWS at an optimal temperature at 70 °C, resulted with 97% of lignin removal. These results are important for further treatment to finally extract the cellulose.

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References

  1. Popa VI (2018) Biomass for fuels and biomaterials. In Biomass as renewable raw material to obtain bioproducts of high-tech value. Elsevier, pp 1–37

    Google Scholar 

  2. Watkins D, Hosur M, Tcherbi-narteh A, Jeelani S (2014) Extraction and characterization of lignin from different biomass resources. Integr Med Res 4:26–32

    Google Scholar 

  3. Malaysia Timber Industrial Board: National Timber Industry Policy. Ministry of Plantation Industries and Commodities Malaysia

    Google Scholar 

  4. Iqbal HMN, Kyazze G, Keshavarz T (2013) Advances in the valorization of lignocellulosic materials by biotechnology: an overview. BioResources 8(2):3157–3176

    Google Scholar 

  5. Ahn Y, Hu DH, Hong JH, Lee SH, Kim HJ, Kim H (2012) Effect of co-solvent on the spinnability and properties of electrospun cellulose nanofiber. Carbohydr, Polym

    Book  Google Scholar 

  6. Mohammadinejad R, Karimi S, Iravani S, Varma RS (2005) Plant-derived nanostructures: types and applications, http://xlink.rsc.org/?DOI=C5GC01403D

  7. Putro JN, Soetaredjo FE, Lin S-Y, Ju Y-H, Ismadji S (2016) Pretreatment and conversion of lignocellulose biomass into valuable chemicals. RSC Adv 6:46834–46852

    Article  Google Scholar 

  8. Fernandes MC, Ferro MD, Paulino AFC, Mendes JAS, Gravitis J, Evtuguin DV, Xavier AMRB (2015) Enzymatic saccharification and bioethanol production from Cynara cardunculus pretreated by steam explosion. Bioresour Technol 186:309–315

    Article  Google Scholar 

  9. Romero I, López-Linares JC, Moya M, Castro E (2018) Optimization of sugar recovery from rapeseed straw pretreated with FeCl3. Bioresour Technol 268:204–211

    Article  Google Scholar 

  10. Nilsson B, Se L (2016) Extraction of logging residues for bioenergy: effects of operational methods on fuel quality and biomass losses in the forest. Linnaeus University Press

    Google Scholar 

  11. Isikgor FH, Becer CR (2015) Lignocellulosic biomass: a sustainable platform for the production of bio-based chemicals and polymers. Polym Chem 6:4497–4559

    Article  Google Scholar 

  12. Studer MH, DeMartini JD, Davis MF, Sykes RW, Davison B, Keller M, Tuskan GA, Wyman CE (2011) Lignin content in natural Populus variants affects sugar release. Proc Natl Acad Sci 108:6300–6305

    Article  Google Scholar 

  13. Sukri SSM, Sakinah AM (2018) Production of high commercial value xylooligosaccharides from Meranti wood sawdust using immobilised xylanase. Appl Biochem Biotechnol 184(1):278–290

    Article  Google Scholar 

  14. Sluiter A, Ruiz R, Scarlata C, Sluiter J, Templeton D, Sluiter A, Ruiz R, Scarlata C, Sluiter J, Templeton D (2008) Determination of extractives in biomass laboratory analytical procedure (LAP) Issue date : 7/17/2005. Determination of Extractives in Biomass Laboratory Analytical Procedure (LAP)

    Google Scholar 

  15. Sluiter A, Hames B, Ruiz R, Scarlata C, Sluiter J, Templeton D, Nrel DC (2011) Determination of structural carbohydrates and lignin in biomass determination of structural carbohydrates and lignin in biomass

    Google Scholar 

  16. Sluiter A, Hames B, Hyman D, Payne C, Ruiz R, Scarlata C, Sluiter J, Templeton D, Nrel JW (2008) Determination of total solids in biomass and total dissolved solids in liquid process samples. National Renewable Energy Laboratory 9

    Google Scholar 

  17. Wise LE, Maxine M, D’Addieco AA (1946) Chlorite holocellulose, its fractionation and bearing on summative wood analysis and on studies on the hemicelluloses. Tech Assoc Pulp Pap Ind 29:210–218

    Google Scholar 

  18. Kumar R, Hu F, Hubbell CA, Ragauskas AJ, Wyman CE (2013) Comparison of laboratory delignification methods, their selectivity, and impacts on physiochemical characteristics of cellulosic biomass. Bioresour Technol 130:372–381

    Article  Google Scholar 

  19. Duret X, Fredon E, Masson E, Desharnais L, Gérardin P (2013) Optimization of acid pretreatment in order to increase the phenolic content of Picea abies bark by surface response methodology. BioResources

    Google Scholar 

  20. Nadia Rabetafika H, Bchir B, Blecker C, Paquot M, Wathelet B (2014) Comparative study of alkaline extraction process of hemicelluloses from pear pomace

    Google Scholar 

  21. ASTM D1106-96 (2001) Standard test method for acid-insoluble lignin in wood

    Google Scholar 

  22. Han JS, Rowell JS (2008) Chemical composition of fibers. Cellulose 283:83–134

    Google Scholar 

  23. Technical Association of Pulp and Paper Industry (2007) TAPPI: TAPPI T 204 cm-07—Solvent extractives of wood and pulp

    Google Scholar 

  24. Winandy JE, Rowell RM (2005) Chemistry of wood strength. In: Handbook of wood chemistry and wood composites

    Google Scholar 

  25. Kumar AK, Sharma S (2017) Recent updates on different methods of pretreatment of lignocellulosic feedstocks : a review. Bioresour Bioprocess

    Google Scholar 

  26. Gierer J (1986) Chemistry of delignification. Wood Sci Technol 20:1–33

    Article  Google Scholar 

  27. Ververis C, Georghiou K, Christodoulakis N, Santas P, Santas R (2004) Fiber dimensions, lignin and cellulose content of various plant materials and their suitability for paper production. Ind Crops Prod 19:245–254

    Article  Google Scholar 

  28. Abdul Rahman, SN, Mimi Sakinah A (2018) Influenced factors in the delignification process of Red Meranti wood sawdust. J Chem Eng Ind Biotechnol Open Access 3:26–36

    Google Scholar 

  29. Brahim M, Boussetta N, Grimi N, Vorobiev E, Zieger-Devin I, Brosse N (2017) Pretreatment optimization from rapeseed straw and lignin characterization. Ind Crop Prod 95:643–650

    Article  Google Scholar 

  30. Anderson MJ, Whitcomb PJ, Kraber SL, Adams W (2009) Stat-ease handbook for experimenters. Stat-Ease, Inc

    Google Scholar 

  31. Mason RL, Gunst RF, Hess JL (2015) Statistical design and analysis of experiments—with applications to engineering and science, 2nd edn

    Google Scholar 

  32. Rabemanolontsoa H, Saka S (2016) Various pretreatments of lignocellulosics

    Google Scholar 

  33. Zularisam AW, Ismail AF, Salim MR, Sakinah M, Matsuura T (2009) Application of coagulation-ultrafiltration hybrid process for drinking water treatment: optimization of operating conditions using experimental design. Sep Purif Technol

    Google Scholar 

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Acknowledgements

This research was supported by internal grants, Universiti Malaysia Pahang, RDU1703325 and PGRS1803111.

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Correspondence to Abdul Munaim Mimi Sakinah .

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Siti Noredyani, A.R., Zularisam, A.W., Noormazlinah, A., Mimi Sakinah, A.M. (2020). Optimization of Delignification Process from Red Meranti Wood Sawdust (RMWS) Pretreated with Acidified Sodium Chlorite. In: Awang, M., Emamian, S., Yusof, F. (eds) Advances in Material Sciences and Engineering. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-13-8297-0_18

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  • DOI: https://doi.org/10.1007/978-981-13-8297-0_18

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