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Preparation, Characterization, Types and Applications of Polysaccharide Nanocomposites

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Green Biopolymers and their Nanocomposites

Part of the book series: Materials Horizons: From Nature to Nanomaterials ((MHFNN))

Abstract

The threat of in-appropriate discard of polymer to the environment can be tackled by using a suitable biodegradable polymeric material like the polysaccharide. Materials of various mechanical and thermal properties based on the need can be synthesized by using polysaccharide reinforced with compatible nanostructures. These types of composites can be a potential alternative for the conventional materials. The nanocomposites made from biopolymer are having the advantages such as good reinforcing capacity, high specific mechanical strength, less energy consumption, high strength for its weight ratio and good biodegradability over conventional inorganic filler materials. Reinforcing with polysaccharide nanoparticles has many advantages such as good compatibility which poses them as ideal materials in the processing stages of nano-polymer composites for medicinal applications. The properties like biocompatibility and antimicrobial properties are very well used in the fields of biomedicine. The nanocomposites are finding immense applications in electrical, electronic and mechanical fields, based on their physical properties. This chapter summarizes current knowledge on polysaccharides, nanocomposite preparation using various methods, different types of nanocomposites, properties of nanocomposites based on the structure and their applications.

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References

  1. Angellier H, Choisnard L, Molina-Boisseau S, Ozil P, Dufresne A (2004) Optimization of the preparation of aqueous suspensions of waxy maize starch nanocrystals using a response surface methodology. Biomacromolecules 5(4):1545–1551

    Article  CAS  Google Scholar 

  2. Angellier H, Molina-Boisseau S, Dole P, Dufresne A (2006) Thermoplastic starch-waxy maize starch nanocrystals nanocomposites. Biomacromolecules 7(2):531–539

    Article  CAS  Google Scholar 

  3. Anglès MN, Dufresne A (2000) Plasticized starch/tunicin whiskers nanocomposites: 1. Structural analysis. Macromolecules 33(22):8344–8353

    Article  Google Scholar 

  4. Babaee M, Jonoobi M, Hamzeh Y, Ashori A (2015) Biodegradability and mechanical properties of reinforced starch nanocomposites using cellulose nanofibers. Carbohydr Polym 132:1–8

    Article  CAS  Google Scholar 

  5. Campos A, Teodoro KBR, Teixeira EM, Corrêa AC, Marconcini JM, Wood DF, Williams TG, Mattoso LHC (2013) Properties of thermoplastic starch and TPS/polycaprolactone blend reinforced with sisal whiskers using extrusion process. Polym Eng Sci 53(4):800–808

    Article  CAS  Google Scholar 

  6. Chen Y, Liu C, Chang PR, Cao X, Anderson DP (2009) Bionanocomposites based on pea starch and cellulose nano whiskers hydrolyzed from pea hull fibre: effect of hydrolysis time. Carbohydr Polym 76(4):607–615

    Article  CAS  Google Scholar 

  7. Chen ZG, Wang PW, Wei B, Mo XM, Cui FZ (2010) Electrospun collagen-chitosan nanofiber: a biomimetic extracellular matrix for endothelial cell and smooth muscle cell. Acta Biomater 6:372–382

    Article  CAS  Google Scholar 

  8. Chung Y, Kim JC, Kim YH, Tae G, Lee SY, Kim K, Kwon IC (2010) The effect of surface functionalization of PLGA nanoparticles by heparin- or chitosan-conjugated pluronic on tumor targeting. J Controlled Release 143:374–382

    Article  CAS  Google Scholar 

  9. Chung Y, Tae G, Yuk SH (2006) A facile method to prepare heparin-functionalized nanoparticles for controlled release of growth factors. Biomaterials 27:2621–2626

    Article  CAS  Google Scholar 

  10. De Azeredo HMC (2009) Nanocomposites for food packaging applications. Food Res Int 42:1240–1253

    Article  CAS  Google Scholar 

  11. Dehnad D, Emam-Djomeh Z, Mirzaei H, Jafaria SM, Dadashib S (2014) Optimization of physical and mechanical properties for chitosan-nanocellulosebiocomposites. Carbohydr Polym 105:222–228

    Article  CAS  Google Scholar 

  12. Deng H, Wang X, Liu P, Ding B, Du Y, Li G, Hu X, Yang J (2011) Enhanced bacterial inhibition activity of layer-by-layer structured polysaccharide film-coated cellulose nanofibrous mats via addition of layered silicate. Carbohydr Polym 100:239–245

    Article  CAS  Google Scholar 

  13. Du J, Hsieh YL (2009) Cellulose/chitosan hybrid nanofibers from electrospinning of their ester derivatives. Cellulose 16:247–260

    Article  CAS  Google Scholar 

  14. Duan B, Sun P, Wang X, Yang C (2011) Preparation and properties of starch nanocrystals/carboxymethyl chitosan nanocomposite films. Starch 63:528–535

    Article  CAS  Google Scholar 

  15. Duan B, Wang M (2010) Customized Ca-P/PHBV nanocomposite scaffolds for bone tissue engineering: Design, fabrication, surface modification and sustained release of growth factor. J R Soc Interface 7:S615–S629

    Google Scholar 

  16. Dufresne A (2012) Nanocellulose: from nature to high performance tailored materials. Walter de Gruyter GmbH & Co KG, Berlin/Boston

    Google Scholar 

  17. Dufresne A (2014) Crystalline starch based nanoparticles. Curr Opin Colloid Interface Sci 19:397–408

    Article  CAS  Google Scholar 

  18. Dufresne A, Thomas S, Pothan LA (2013) (eds) Biopolymer nanocomposites: processing, properties and applications. Wiley, Hoboken, New Jersey, pp 1–10

    Google Scholar 

  19. El Miri N, Abdelouahdi K, Barakat A, Zahouily M, Fihri A, Solhye A, Achaby ME (2015) Bio-nanocomposite films reinforced with cellulose nanocrystals: rheology of film-forming solutions, transparency, water vapour barrier and tensile properties of films. Carbohydr Polym 129:156–167

    Google Scholar 

  20. Fang B, Wan Y, Tang T, Gao C, Dai K (2009) Proliferation and osteoblastic differentiation of human bone marrow stromal cells on hydroxyapatite/bacterial cellulose nanocomposite scaffolds. Tissue Eng Part A 15:1091–1098

    Article  CAS  Google Scholar 

  21. Fernandes SCM, Oliveira L, Freire CSR, Silvestre AJD, Neto CP, Gandini A, Desbriéres J (2009) Novel transparent nanocomposite films based on chitosan and bacterial cellulose. Green Chem 11:2023–2029

    Article  CAS  Google Scholar 

  22. Filip J, Sefcovicova J, Tomcik P, Gemeiner P, Tkac J (2011) A hyaluronic acid dispersed carbon nanotube electrode used for a mediatorless NADH sensing and biosensing. Talanta 84:355–361

    Article  CAS  Google Scholar 

  23. Garcia NL, Ribba L, Dufresne A, Aranguren MI, Goyanes S (2009) Physico mechanical properties of biodegradable starch nanocomposites. Macromol Mater Eng 294:169–177

    Article  CAS  Google Scholar 

  24. Gong JL, Wang XY, Zeng GM, Chen L, Deng J, Zhang X, Niu Q et al (2012) Copper (II) removal by pectin–iron oxide magnetic nanocomposite adsorbent. Chem Eng J 185–186:100–107

    Article  CAS  Google Scholar 

  25. Gopalan Nair K, Dufresne A (2003) Crab shell chitin whisker reinforced natural rubber nanocomposites processing and swelling behaviour. Biomacromolecules 4:657–665

    Article  CAS  Google Scholar 

  26. Habibi Y, Goffin AL, Schiltz N, Duquesne E, Dubois PH, Dufresne A (2008) Bionanocomposites based on poly(e-caprolactone)-grafted cellulose nanocrystals by ring opening polymerization. J Mat Chem 18:5002–5010

    Article  CAS  Google Scholar 

  27. Huang C, Chen R, Ke Q, Morsi Y, Zhang K, Mo X (2011) Electrospun collagen–chitosan–TPU nanofibrous scaffolds for tissue engineered tubular grafts. Colloids Surf B 82:307–315

    Article  CAS  Google Scholar 

  28. Huang J, Chang PR, Lin N, Dufresne A (2015) Polysaccharide-based nanocrystals: chemistry and applications, Wiley-VCH, Verlag GmbH & Co. KGaA, Chemical Industry Press, Weinheim, Germany

    Google Scholar 

  29. Huang F, Wu X, Yu Y, Lu Y (2015) Preparation and properties of cellulose laurate (CL)/starch nanocrystals acetate (SNA) bio-nanocomposites. Polymers 7:1331–1345

    Article  CAS  Google Scholar 

  30. Huang LY, Yang MC (2006) Hemocompatibility of layer-by-layer hyaluronic acid/heparin nanostructure coating on stainless steel for cardiovascular stents and its use for drug delivery. J Nanosci Nanotechnol 6:3163–3170

    Article  CAS  Google Scholar 

  31. Janaki V, Vijayaraghavan K, Oh B, Lee K, Muthuchelian K, Ramasamy AK, Kamal-Kannan S (2012) Starch/polyaniline nanocomposite for enhanced removal of reactive dyes from synthetic effluent. Carbohydr Polym 90:1437–1444

    Article  CAS  Google Scholar 

  32. Javid A, Ahmadian S, Saboury AA, Kalantarc SM, Zarchid SR (2014) Novel biodegradable heparin-coated nanocomposite system for targeted drug delivery. RSC Adv 4:13719–13728

    Article  CAS  Google Scholar 

  33. Kaushik A, Singh M, Verma G (2010) Green nanocomposites based on thermoplastic starch and steam exploded cellulose nanofibrils from wheat straw. Carbohydr Polym 82:337–345

    Article  CAS  Google Scholar 

  34. Ke D, Liu S, Dai K, Zhou J, Zhang L, Peng T (2009) CdS/regenerated cellulose nanocomposite films for highly efficient photocatalytic H2 production under visible light irradiation. J Phys Chem 113:16021–16026

    Article  CAS  Google Scholar 

  35. Kemp MM, Kumar A, Clement D, Ajayan P, Mousa S, Linhardt RJ (2009) Hyaluronan- and heparin-reduced silver nanoparticles with antimicrobial properties. Nanomedicine 4:421–429

    Article  CAS  Google Scholar 

  36. Kemp MM, Kumar A, Mousa S, Dyskin E, Yalcin M, Ajayan P, Linhardt RJ, Mousa SA (2009) Gold and silver nanoparticles conjugated with heparin derivative possess anti-angiogenesis properties. Nanotechnology 20:455104

    Article  CAS  Google Scholar 

  37. Kemp MM, Kumar A, Mousa S, Park TJ, Ajayan P, Kubotera N, Mousa SA, Linhardt RL (2009) Synthesis of gold and silver nanoparticles stabilized with glycosaminoglycans having distinctive biological activities. Biomacromolecules 10:589–595

    Article  CAS  Google Scholar 

  38. Kim JS, Kim M, Won DA, Tae G (2015) Preparation of nanosize alginate gel using pluronic based nano-carrier as a template. Eur Polym J 72:632–641

    Article  CAS  Google Scholar 

  39. Kim DH, Park SY, Kim J, Park M (2010) Preparation and properties of the single-walled carbon nanotube/cellulose nanocomposites using N-methylmorpholine-N-oxide monohydrate. J Appl Polym Sci 117:3588–3594

    CAS  Google Scholar 

  40. Kumar A, Gullapalli H, Balakrishnan K, Botello-Mendez A, Vajtai R, Terrones M, Ajayan PM (2011) Flexible ZnO–cellulose nanocomposite for multisource energy conversion. Small 7:2173–2178

    Article  CAS  Google Scholar 

  41. Kvien I, Sugiyama J, Votrubec M, Oksman K (2007) Characterization of starch based nanocomposites. J Mater Sci 42:8163–8171

    Article  CAS  Google Scholar 

  42. Kwon IK, Matsuda T (2005) Co-electrospun nanofiber fabrics of poly(l-lactide-co-ε-caprolactone) with type I collagen or heparin. Biomacromolecules 6:2096–2105

    Article  CAS  Google Scholar 

  43. Le Corre D, Bras J, Choisnard L, Dufresne A (2012) Optimization of the batch preparation of starch nanocrystals to reach daily time-scale. Starch 64:489–496

    Google Scholar 

  44. Le Corre D, Bras J, Dufresne A (2010) Starch nanoparticles: a review. Biomacromolecules 11:1139–1153

    Article  CAS  Google Scholar 

  45. Le Corre D, Bras J, Dufresne A (2011) Ceramic membrane filtration for isolating starch nanocrystals. Carbohydr Polym 86:1565–1572

    Google Scholar 

  46. Le Corre D, Bras J, Dufresne A (2011) Evidence of micro and nano-scaled particles during starch nanocrystals preparation and their isolation. Biomacromolecules 12:3039–3046

    Article  CAS  Google Scholar 

  47. Le Corre D, Vahanian E, Dufresne A, Bras J (2012) Enzymatic pretreatment for preparing starch nanocrystals. Biomacromolecules 13:132–137

    Google Scholar 

  48. Lee K, Lee H, Bae KH, Park TG (2010) Heparin immobilized gold nanoparticles for targeted detection and apoptotic death of metastatic cancer cells. Biomaterials 31:6530–6536

    Article  CAS  Google Scholar 

  49. Lee KY, Mooney DJ (2012) Alginate: properties and biomedical applications. Prog Polym Sci 37:106–126

    Article  CAS  Google Scholar 

  50. Lenichaya MV, Aleksandrova GP, Feoktistova LP, Sapozhnikov AN, Sukhov BG, Trofimov BA (2011) Formation kinetics of gold nanoparticles in the galactomannan polysaccharide matrix. Dokl Chem 440:282–285

    Article  CAS  Google Scholar 

  51. Li J, He A, Han CC, Fang D, Hsiao BS, Chu B (2006) Electrospinning of hyaluronic acid (HA) and HA/gelatin blends. Macromol Rapid Commun 27:114–120

    Article  CAS  Google Scholar 

  52. Li J, Hou Y, Chen X, Ding X, Liu Y, Shen X, Cai K (2014) Recyclable heparin and chitosan conjugated magnetic nanocomposites for selective removal of low-density lipoprotein from plasma. Mater Sci Mater Med 25:1055–1064

    CAS  Google Scholar 

  53. Li Q, Zhou J, Zhang L (2009) Structure and properties of the nanocomposite films of chitosan reinforced with cellulose whiskers. J Polym Sci Pol Phys 47:1069–1077

    Article  CAS  Google Scholar 

  54. Lin N, Dufresne A (2014) Surface chemistry, morphological analysis and properties of cellulose nanocrystals with gradient sulfation degrees. Nanoscale 6:5384–5393

    Article  CAS  Google Scholar 

  55. Liu Z, Jiao Y, Wang Y, Zhoua C, Zhang Z (2008) Polysaccharides-based nanoparticles as drug delivery systems. Adv Drug Delivery Rev 60:1650–1662

    Article  CAS  Google Scholar 

  56. Liu H, Xie F, Yu L, Chen L, Li L (2009) Thermal processing of starch-based polymers. Prog Polym Sci 34:1348–1368

    Article  CAS  Google Scholar 

  57. Luong ND, Pahimanolis N, Hippi U, Korhonen JT, Ruokolainen J, Johansson LS, Nam JD, Seppala J (2011) Graphene/cellulose nanocomposite paper with high electrical and mechanical performances. J Mater Chem 21:13991–13998

    Article  CAS  Google Scholar 

  58. Maeda N, Miao J, Simmons TJ, Dordick JS, Linhardt RJ (2014) Composite polysaccharide fibers prepared by electrospinning and coating. Carbohydr Polym 102:950–955

    Article  CAS  Google Scholar 

  59. Malainine ME, Dufresne A, Dupeyre D, Mahrouzab M, Vuong R, Vignon MR (2003) Structure and morphology of cladodes and spines of Opuntiaficus-indica. Cellulose extraction and characterisation. Carbohydr Polym 51:77–83

    Article  CAS  Google Scholar 

  60. Marques PAAP, Trindade T, Neto CP (2006) Titanium dioxide/cellulose nanocomposites prepared by a controlled hydrolysis method. Compos Sci Technol 66:1038–1044

    Article  CAS  Google Scholar 

  61. Mathew AP, Dufresne A (2002) Morphological investigation of nanocomposites from sorbitol plasticized starch and tunicinwhiskers. Biomacromolecules 3:609–617

    Article  CAS  Google Scholar 

  62. Miao J, Pangule RC, Paskaleva EE, Hwangh EE, Kane RS, Linhardt RJ, Dordick JS (2011) Lysostaphin-functionalized cellulose fibers with antistaphylococcal activity for wound healing applications. Biomaterials 32:9557–9567

    Article  CAS  Google Scholar 

  63. Miao J, Zhang F, Takieddin M, Mousa S, Linhardt RJ (2012) Adsorption of doxorubicin on poly(methyl methacrylate)–chitosan–heparin-coated activated carbon beads. Langmuir 28:4396–4403

    Article  CAS  Google Scholar 

  64. Millon LE, Guhados G, Wan W (2008) Anisotropic polyvinyl alcohol—bacterial cellulose nanocomposite for biomedical applications. Biomed Mater Res Part B 86B:444–452

    Article  CAS  Google Scholar 

  65. Miyauchi M, Miao J, Simmons TJ, Lee JW, Doherty TV, Dordick JS, Linhardt RJ (2010) Conductive cable fibers with insulating surface prepared by coaxial electrospinning of multiwalled nanotubes and cellulose. Biomacromolecules 11:2440–2445

    Article  CAS  Google Scholar 

  66. Murugesan S, Park TJ, Yang H, Mousa S, Linhardt RJ (2006) Blood compatible carbon nanotubes—nano-based neoproteoglycans. Langmuir 22:3461–3463

    Article  CAS  Google Scholar 

  67. Oyarzun-Ampuero FA, Brea J, Loza MI, Torresa D, Alonso MJ (2009) Chitosan–hyaluronic acid nanoparticles loaded with heparin for the treatment of asthma. Int J Pharm 381:122–129

    Article  CAS  Google Scholar 

  68. Pandey S, Goswami GK, Nanada KK (2013) Green synthesis of polysaccharide/gold nanoparticle nanocomposite: an efficient ammonia sensor. Carbohydr Polym 94:229–234

    Article  CAS  Google Scholar 

  69. Park SY, Chung JW, Priestley RD, Kwak SY (2012) Covalent assembly of metal nanoparticles on cellulose fabric and its antimicrobial activity. Cellulose 19: 2141–2151

    Article  CAS  Google Scholar 

  70. Pinto RJB, Marques PAAP, Neto CP, Trindade T, Daina S, Sadocco P (2009) Antibacterial activity of nanocomposites of silver and bacterial or vegetable cellulosic fibers. Acta Biomater 5:2279–2289

    Article  CAS  Google Scholar 

  71. Popp J, Lakner Z, Harangi-Rakos M, Fari M (2014) The effect of bioenergy expansion: food, energy, and environment. Renew Sust Energy Rev 32:559–578

    Article  Google Scholar 

  72. Pushparaj VL, Shaijumon MM, Kumar A, Murugesan S, Ci L, Vajtai R, Linhardt RJ, Nalamasu O, Ajayan PM (2007) Flexible energy storage devices based on nanocomposite paper. Proc Natl Acad Sci U S A 104:13574–13577

    Article  CAS  Google Scholar 

  73. Putaux JL, Molina-Boisseau S, Momaur T, Dufresne A (2003) Platelet nanocrystals resulting from the disruption of waxy maize starch granules by acid hydrolysis. Biomacromolecules 4:1198–1202

    Article  CAS  Google Scholar 

  74. Rinaudo M (2006) Chitin and chitosan: properties and applications. Prog Polym Sci 31:603–632

    Article  CAS  Google Scholar 

  75. Robyn A, Kim S, Travis K, Gwen L, Lisbeth G (2016) Evaluation of the impact of freezing preparation techniques on the characterisation of alginate hydrogels by cryo-SEM. Eur Polym J (82):1–15

    Google Scholar 

  76. Salaberria AM, Diaz RH, Labidi J, Fernandes SCM (2015) Role of chitin nanocrystals and nanofibers on physical, mechanical and functional properties in thermoplastic starch films. Food Hydrocolloid 46:93–102

    Article  CAS  Google Scholar 

  77. Satyanarayana KG, Arizaga GGC, Wypych F (2009) Biodegradable composites based on lingo cellulosic fibers—an overview. Prog Polym Sci 34:982–1021

    Article  CAS  Google Scholar 

  78. Schmidtke C, Kreuziger AM, Alpers D, Jacobsen A, Leshch Y, Eggers R, Kloust H, Tran H, Ostermann J, Schotten T, Thiem J, Thimm J, Weller H (2013) Glycoconjugated amphiphilic polymers via click-chemistry for the encapsulation of quantum dots. Langmuir 29:12593–12600

    Article  CAS  Google Scholar 

  79. Shimazaki Y, Miyazaki Y, Takezawa Y, Nogi M, Abe K, Ifuku S, Yano H (2007) Excellent thermal conductivity of transparent cellulose nanofiber/epoxy resin nanocomposites. Biomacromolecules 8:2976–2978

    Article  CAS  Google Scholar 

  80. Silva AR, Unali G (2011) Controlled silver delivery by silver–cellulose nanocomposites prepared by a one-pot green synthesis assisted by microwaves. Nanotechnology 22:315605

    Article  CAS  Google Scholar 

  81. Svagan AJ, Jensen P, Dvinskikh SV, Furo I, Berglund, LA (2010) Towards tailored hierarchical structures in cellulose nanocomposite biofoams prepared by freezing/freeze-drying. J Mat Chem 20:6646–6654

    Article  CAS  Google Scholar 

  82. Tan Q, Tang H, Hu J, Zhou X, Tao Y, Wu Z (2011) Controlled release of chitosan/heparin nanoparticle-delivered VEGF enhances regeneration of decellularized tissue-engineered scaffolds. Int J Nanomed 6:929–942

    Google Scholar 

  83. Tokarev A, Long J, Guari Y, Larionova J, Quignard F, Agulhon P, Robitzer M, Molnar G, Salmon L, Bouzzeksou A (2013) Spin crossover polysaccharide nanocomposites. New J Chem 37:3420–3432

    Article  CAS  Google Scholar 

  84. Trandafilovic LV, Bozanic DK, Dimitrijevic-Brankovic S, Luyt AS, Djoković V (2012) Fabrication and antibacterial properties of ZnO–alginate nanocomposites. Carbohydr Polym 88(1):263–269

    Article  CAS  Google Scholar 

  85. Travan A, Marisch E, Donati I, Benincasa M, Giazzon M, Felisari L, Paoletti S (2011) Silver–polysaccharide nanocomposite antimicrobial coatings for methacrylic thermosets. Acta Biomater 7:337–346

    Article  CAS  Google Scholar 

  86. Trovatti E, Fernandes SCM, Rubatat L, Perez DDS, Freire CSR, Silvestre AJD, Neto CP (2012) Pullulan–nanofibrillated cellulose composite films with improved thermal and mechanical properties. Compos Sci Technol 72(13):1556–1561

    Article  CAS  Google Scholar 

  87. Turkoglu M, Gursay A, Eroglu L, Okar I (1997) Effect of aqueous polymer dispersions on properties of diclofenac/alginate beads and in vivo evaluation in rats. STP Pharma Sci 7:135–140

    CAS  Google Scholar 

  88. Vigneshwaran N, Kumar S, Kathe AA, Varadarajan PV, Prasad V (2006) Functional finishing of cotton fabrics using zinc oxide–soluble starch nanocomposites. Nanotechnology 17:5087–5095

    Article  CAS  Google Scholar 

  89. Viguié J, Molina-Boisseau S, Dufresne A (2007) Processing and characterization of waxy maize starch films plasticized by sorbitol and reinforced with starch nanocrystals. Macromol Biosci 7:1206–1216

    Article  CAS  Google Scholar 

  90. Vilela C, Freire CSR, Marques PAAP, Trindade T, Neto CP, Fardim P (2010) Synthesis and characterization of new CaCO3/cellulose nanocomposites prepared by controlled hydrolysis of dimethylcarbonate. Carbohydr Polym 79(4):1150–1156

    Article  CAS  Google Scholar 

  91. Volpato FZ, Almodovar J, Erickson K, Popat KC, Migliaresi C, Kipper M (2012) Preservation of FGF-2 bioactivity using heparin-based nanoparticles, and their delivery from electrospun chitosan fibers. J Acta Biomater 8:1551–1559

    Google Scholar 

  92. Vongchan P, Wutti-In Y, Sajomsang W, Gonil P, Kothan S, Linhardtd RJ (2011) N,N,N-Trimethyl chitosan nanoparticles for the delivery of monoclonal antibodies against hepatocellular carcinoma cells. Carbohydr Polym 85(1):215–220

    Article  CAS  Google Scholar 

  93. Wang M, Olszewska A, Walther A, Malho JM, Schacher FH, Ruokolainen J, Ankerfors M, Laine J, Berglund LA, Österberg M, Ikkala O (2011) Colloidal ionic assembly between anionic native cellulose nanofibrils and cationic block copolymer micelles into biomimetic nanocomposites. Biomacromolecules 12(6):2074–2081

    Article  CAS  Google Scholar 

  94. Wang B, Liu X, Ji Y, Ren KF, Ji J (2012) Fast and long-acting antibacterial properties of chitosan-Ag/polyvinyl pyrrolidone nanocomposite films. Carbohydr Polym 90(1):8–15

    Article  CAS  Google Scholar 

  95. Webster M, Miao J, Lynch B, Green DS, Jones-Sawyer R, Linhardt RJ, Mendenhall (2013) Tunable thermo‐responsive Poly(N‐vinylcaprolactam) cellulose nanofibers: synthesis, characterization, and fabrication. J Macromol Mater Eng 298:447–453

    Article  CAS  Google Scholar 

  96. Yuk SH, Oh KS, Cho SH, Lee BS, Kim SY, Kwak BK, Kim K, Kwon IC (2011) Glycol chitosan/heparin iron oxide nanoparticles with a tumor-targeting characteristic for magnetic resonance imaging. Biomacromolecules 12(6):2335–2343

    Article  CAS  Google Scholar 

  97. Zhang X, Huang J, Chang PR, Li J, Chen Y, Wang D, Yu J, Cheng J (2010) Structure and properties of polysaccharide nanocrystal-doped supramolecular hydrogels based on cyclodextrin inclusion. Polymer 51(19):4398–4407

    Article  CAS  Google Scholar 

  98. Zobel HF (1988) Molecules to granules: a comprehensive starch review. Starch 40(2):44–50

    Article  CAS  Google Scholar 

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Gowthami, S., Angayarkanny, S. (2019). Preparation, Characterization, Types and Applications of Polysaccharide Nanocomposites. In: Gnanasekaran, D. (eds) Green Biopolymers and their Nanocomposites. Materials Horizons: From Nature to Nanomaterials. Springer, Singapore. https://doi.org/10.1007/978-981-13-8063-1_16

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