Abstract
This chapter introduces the application of solid-state NMR to characterize the framework structure of zeolite and zeotype materials. Zeolites are inorganic crystallites containing pores and cavities of molecular dimensions with well-defined structures. The framework of zeolite is composed of tetrahedra (TO4, T = Si, Al, B, P, etc.), which can be comprehensively characterized by the well-established and robust solid-state NMR techniques. Chemical environment of the metal or non-metal elements in zeolites and zeotype materials could be studied by the multi-nuclear MAS NMR spectroscopy including 29Si, 27Al, 31P, 17O NMR. Additionally, the detailed information about coordination, connectivity, and framework ordering can be obtained from multi-nuclear and two-dimensional NMR spectroscopy as well as distance constraints’ measurement. Moreover, the structure features and communication of cages and channels in porous materials can be extracted by 129Xe NMR spectroscopy.
Keywords
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Xu, J., Wang, Q., Li, S., Deng, F. (2019). Solid-State NMR Characterization of Framework Structure of Zeolites and Zeotype Materials. In: Solid-State NMR in Zeolite Catalysis. Lecture Notes in Chemistry, vol 103. Springer, Singapore. https://doi.org/10.1007/978-981-13-6967-4_3
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DOI: https://doi.org/10.1007/978-981-13-6967-4_3
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Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-6965-0
Online ISBN: 978-981-13-6967-4
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