Abstract
Ionic polymer shows great potential to imitate natural mechanical sensation because of ion-migration mechanism. In this chapter, sensing properties of IPMC sensor were introduced. Under a bending deformation, how ambient humidity influenced the voltage response of IPMC was investigated. And then the effect of various cations on the electrical responses of IPMC at various ambient humidities was revealed by a series of experiments. The electrical response evolvement with water content and cation type was explained thoroughly based on transport theory. Further, a multi-physical model was set up for IPMC sensor by utilizing the same equations for IPMC actuator. Numerical results showed that the model was capable to fit the voltage and current response of IPMC with various cations at different humidities well. Finally, we presented a new concept of ionic polymer senor based on deeply understanding on sensing mechanism. A 3 × 3 pressure sensor array was presented, which showed much higher voltage. It proved that ionic polymer sensor can work as a pressure sensor, not a cantilever anymore. It makes us believe that ionic polymer sensor is a promising direction and still far from well developed.
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References
Hall JE (2010) Guyton and Hall textbook of medical physiology, 12th edn. Elsevier Health Sciences, Philadelphia, pp 57–69
Shahinpoor M (1995, May) New effect in ionic polymeric gels: the ionic flexogelectric effect. In: Smart structures and materials 1995: smart materials, vol 2441, pp 42–54. International Society for Optics and Photonics
Shahinpoor M, Kim K (2001) Ionic polymer-metal composites: I. Fundamentals. Smart Mater Struct 10(4):819
Kamamichi N, Yamakita M, Asaka K, Luo Z, Mukai T (2007, October) Sensor property of a novel EAP device with ionic-liquid-based bucky gel. In Sensors, 2007 IEEE, pp 221–224
Wu Y, Alici G, Madden J, Spinks G, Wallace G (2007) Soft mechanical sensors through reverse actuation in polypyrrole. Adv Funct Mater 17(16):3216–3222
Kruusamäe K, Punning A, Aabloo A, Asaka K (2015) Self-sensing ionic polymer actuators: a review. Actuators 4(1):17–38
Tiwari R, Kim K (2012) IPMC as a mechanoelectric energy harvester: tailored properties. Smart Mater Struct 22(1):015017
Shahinpoor M, Bar-Cohen Y, Xue T, Harrison J, Smith J (1998, July) Some experimental results on ionic polymer-metal composites (IPMC) as biomimetic sensors and actuators. In Smart structures and materials 1998: smart materials technologies, vol 3324, pp 251–268. International Society for Optics and Photonics
Wang J, Sato H, Xu C, Taya M (2009) Bioinspired design of tactile sensors based on flemion. J Appl Phys 105(8):083515
Konyo M, Konishi Y, Tadokoro S, Kishima T (2004) Development of velocity sensor using ionic polymer-metal composites. Proc SPIE 5385 Smart Struct Mater 5385:307–318
Bonomo C, Fortuna L, Giannone P, Graziani S (2005) A method to characterize the deformation of an IPMC sensing membrane. Sensors Actuators A 123–124:146–154
Bahramzadeh Y, Shahinpoor M (2011) Dynamic curvature sensing employing ionic polymer-metal composite sensors. Smart Mater Struct 20:094011
Lipomi D, Vosgueritchian M, Tee B, Hellstrom S, Lee J, Fox C, Bao Z (2011) Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes. Nat Nanotechnol 6(12):788–792
Yang Y, Zhang H, Lin Z, Zhou Y, Jing Q, Su Y, Yang J, Chen J, Hu C, Wang Z (2013) Human skin based triboelectric nanogenerators for harvesting biomechanical energy and as self-powered active tactile sensor system. ACS Nano 7(10):9213–9222
Gao Q, Meguro H, Okamoto S, Kimura M (2012) Flexible tactile sensor using the reversible deformation of poly(3-hexylthiophene) nanofiber assemblies. Langmuir 28(51):17593–17596
Someya T, Sekitani T, Iba S, Kato Y, Kawaguchi H, Sakurai T (2004) A large-area, flexible pressure sensor matrix with organic field-effect transistors for artificial skin applications. Proc Natl Acad Sci 101(27):9966–9970
Newbury K, Leo D (2002) Electromechanical modeling and characterization of ionic polymer benders. J Intell Mater Syst Struct 13(1):51–60
Farinholt K, Leo D (2004) Modeling of electromechanical charge sensing in ionic polymer transducers. Mech Mater 36(5–6):421–433
Zhu Z, Chen H, Wang Y, Luo B, Chang L, Li B, Chen L (2011) NMR study on mechanisms of ionic polymer-metal composites deformation with water content. EPL (Europhys Lett) 96(2):27005
Shahinpoor M, Kim K (2002) Mass transfer induced hydraulic actuation in ionic polymer-metal composites. J Intell Mater Syst Struct 13(6):369–376
Lu Z, Polizos G, Macdonald D, Manias E (2008) State of water in perfluorosulfonic ionomer (Nafion 117) proton exchange membranes. J Electrochem Soc 155(2):B163–B171
Fujiwara N, Asaka K, Nishimura Y, Oguro K, Torikai E (2000) Preparation of gold-solid polymer electrolyte composites as electric stimuli-responsive materials. Chem Mater 12(6):1750
Zhu Z, Horiuchi T, Kruusamäe K, Chang L, Asaka K (2016) Influence of ambient humidity on the voltage response of ionic polymer–metal composite sensor. J Phys Chem B 120(12):3215–3225
Liu F, Han G, Cheng W, Wu Q (2015) Sorption isotherm of southern yellow pine-high density polyethylene composites. Dent Mater 8:368–378
Must I, Johanson U, Kaasik F, Poldsalu I, Punning A, Aabloo A (2013) Charging a supercapacitor-like laminate with ambient moisture: from a humidity sensor to an energy harvester. Phys Chem Chem Phys 15:9605
Mauritz K, Moore R (2004) State of understanding of Nafion. Chem Rev 104(10):4535–4586
Zhu Z, Horiuchi T, Kruusamäe K, Chang L, Asaka K (2016) The effect of ambient humidity on the electrical response of ion-migration-based polymer sensor with various cations. Smart Mater Struct 25(5):055024
Zhu Z, Horiuchi T, Takagi K, Takeda J, Chang L, Asaka K (2016) Effects of cation on electrical responses of ionic polymer-metal composite sensors at various ambient humidities. J Appl Phys 120(8):084906
Zhu Z, Chang L, Asaka K, Wang Y, Chen H, Zhao H, Li D (2014) Comparative experimental investigation on the actuation mechanisms of ionic polymer–metal composites with different backbones and water contents. J Appl Phys 115(12):124903
Zhu Z, Asaka K, Chang L, Takagi K, Chen H (2013) Physical interpretation of deformation evolvement with water content of ionic polymer-metal composite actuator. J Appl Phys 114(18):184902
Zhu Z, Chang L, Horiuchi T, Takagi K, Aabloo A, Asaka K (2016) Multi-physical model of cation and water transport in ionic polymer-metal composite sensors. J Appl Phys 119(12):124901
Li J, Nemat-Nasser S (2000) Micromechanical analysis of ionic clustering in Nafion perfluorinated membrane. Mech Mater 32(5):303
Boyce M, Arruda E (2000) Constitutive models of rubber elasticity: a review. Rubber Chem Technol 73(3):504–523
Arruda E, Boyce M (1993) A three-dimensional constitutive model for the large stretch behavior of rubber elastic materials. J Mech Phys Solids 41(2):389–412
Hong L (2015) Ph.D. thesis, Michigan State University, East Lansing
Bonomo C, Fortuna L, Giannone P, Graziani S (2006) A circuit to model the electrical behavior of an ionic polymer-metal composite. IEEE Trans Circuits Syst I Regul Pap 53(2):338–350
Wang Y, Zhu Z, Chen H, Luo B, Chang L, Wang Y, Li D (2014) Effects of preparation steps on the physical parameters and electromechanical properties of IPMC actuators. Smart Mater Struct 23(12):125015
Chen Z, Tan X, Will A, Ziel C (2007) A dynamic model for ionic polymer–metal composite sensors. Smart Mater Struct 16(4):1477
Gao F, Weiland L (2010) Ionic polymer transducers in sensing: Implications of the streaming potential hypothesis for varied electrode architecture and loading rate. J Appl Phys 108(3):034910
Shen Q, Kim K, Wang T (2014) Electrode of ionic polymer-metal composite sensors: modeling and experimental investigation. J Appl Phys 115(19):194902
Akle B, Habchi W, Wallmersperger T, Akle E, Leo D (2011) High surface area electrodes in ionic polymer transducers: numerical and experimental investigations of the electro-chemical behavior. J Appl Phys 109(7):074509
Chang L, Asaka K, Zhu Z, Wang Y, Chen H, Li D (2014) Effects of surface roughening on the mass transport and mechanical properties of ionic polymer-metal composite. J Appl Phys 115(24):244901
Palmre V, Pugal D, Kim K (2014, March) Effects of electrode surface structure on the mechanoelectrical transduction of IPMC sensors. In Electroactive Polymer Actuators and Devices (EAPAD) 2014, vol 9056, p 905605. International Society for Optics and Photonics
Xie G, Okada T (1996) Pumping effects in water movement accompanying cation transport across Nafion 117 membranes. Electrochim Acta 41(9):1569–1571
Zhu Z, Asaka K, Chang L, Takagi K, Chen H (2013) Multiphysics of ionic polymer–metal composite actuator. J Appl Phys 114(8):084902
Nemat-Nasser S, Wu Y (2003) Comparative experimental study of ionic polymer–metal composites with different backbone ionomers and in various cation forms. J Appl Phys 93(9):5255–5267
Wang Y, Chen H, Wang Y, Zhu Z, Li D (2014) Effect of dehydration on the mechanical and physicochemical properties of gold-and palladium-ionomeric polymer-metal composite (IPMC) actuators. Electrochim Acta 129:450–458
Zhu Z, Wang Y, Hu X, Sun X, Chang L, Lu P (2016) An easily fabricated high performance ionic polymer based sensor network. Appl Phys Lett 109(7):073504
Gudarzi M, Smolinski P, Wang Q (2017) Compression and shear mode ionic polymer-metal composite (IPMC) pressure sensors. Sensors Actuators A Phys 260:99–111
Kocer B, Zangrilli U, Akle B, Weiland L (2015) Experimental and theoretical investigation of ionic polymer transducers in shear sensing. J Intell Mater Syst Struct 26(15):2042–2054
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Zhu, Z., Chen, H., Wang, Y. (2019). Sensing Properties and Physical Model of Ionic Polymer. In: Asaka, K., Okuzaki, H. (eds) Soft Actuators. Springer, Singapore. https://doi.org/10.1007/978-981-13-6850-9_29
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DOI: https://doi.org/10.1007/978-981-13-6850-9_29
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