Abstract
This chapter mainly introduces physical deformation theory of IPMC actuator. At first a series of comparative experiments focused on water content and polymer backbones of IPMC were designed and performed to disclose the actuation mechanisms of relaxation and slow anode deformation. Then a multi-physical model was set up which emphasized on water-related transport process and various eigen stresses. Through numerical analysis, inter-coupling between cation and water, pressure and hydration effects were investigated on the transport process. And in contrast to hydrostatic pressure, osmotic pressure and electrostatic stress and their properties with cation and water concentrations were analyzed to explain IPMC deformation evolvement with water content. Finally, model simplification was discussed for deformation prediction in engineering application.
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Shahinpoor M, Bar-Cohen Y, Simpson JO, Smith J (1998) Ionic polymer-metal composites (IPMCs) as biomimetic sensors, actuators and artificial muscles – a review. Smart MaterStruct 7(6):R15–R30
Shahinpoor M, Kim KJ (2001) Ionic polymer-metal composites: I. Fundamentals. Smart Mater Struct 10(4):819–833
Bar-Cohen Y, Leary S, Yavrouian A, Oguro K, Tadokoro S, Harrison J, Smith J, Su J (2000) Challenges to the application of IPMC as actuators of planetary mechanisms. Proc SPIE 3987:140–146
Shahinpoor M, Kim KJ (2005) Ionic polymer–metal composites: IV. Industrial and medical applications. Smart Mater Struct 14(1):197–214
Mirfakhrai T, Madden JDW, Baughman RH (2007) Polymer artificial muscles. Mater Today 10(4):30–38
Calvert P (2009) Hydrogels for soft machines. Adv Mater 21(7):743–756
Zhu Z, Asaka K, Chang L, Takagi K, Chen H (2013) Physical interpretation of deformation evolvement with water content of ionic polymer-metal composite actuator. J Appl Phys 114(18):184902
Li JY, Nemat-Nasser S (2000) Micromechanical analysis of ionic clustering in Nafion perfluorinated membrane. Mech Mater 32(5):303–314
Nemat-Nasser S (2002) Micromechanics of actuation of ionic polymer-metal composites. J Appl Phys 92(5):2899–2915
Gennes PG d, Okumura K, Shahinpoor M, Kim KJ (2000) Mechanoelectric effects in ionic gels. Europhys Lett 50(4):513–518
Tadokoro S, Yamagami S, Takamori T, Oguro K (2000) Modeling of Nafion-Pt composite actuators (ICPF) by ionic motion. Proc SPIE 3987:92–102
Asaka K, Oguro K (2000) Bending of polyelectrolyte membrane platinum composites by electric stimuli: part II. Response kinetics. J Electroanal Chem 480(1–2):186–198
Yamaue T, Mukai H, Asaka K, Doi M (2005) Electrostress diffusion coupling model for polyelectrolyte gels. Macromolecules 38(4):1349–1356
Enikov ET, Seo GS (2005) Analysis of water and proton fluxes in ion-exchange polymer–metal composite (IPMC) actuators subjected to large external potentials. Sens Actuators A 122(2):264–272
Zhu Z, Chang L, Asaka K, Wang Y, Chen H, Zhao H, Li D (2014) Comparative experimental investigation on the actuation mechanisms of ionic polymer–metal composites with different backbones and water contents. J Appl Phys 115(12):124903
Chang L, Chen H, Zhu Z, Li B (2012) Manufacturing process and electrode properties of palladium-electroded ionic polymer–metal composite. Smart Mater Struct 21(6):065018
Zhu Z, Chen H, Wang Y, Luo B, Chang L, Li B (2011) NMR study on the mechanisms of ionic polymer-metal composites deformation with water content. Europhys Lett 96:27005
Okada T, Xie G, Gorseth O, Kjelstrup S, Nakamura N, Arimura T (1998) Ion and water transport characteristics of Nafion membranes as electrolytes. Electrochim Acta 43(24):3741–3747
Zhu Z, Chen H, Chang L, Li B (2011) Dynamic model of ion and water transport in ionic polymer-metal composites. AIP Adv 1(4):040702
See supplementary material at https://doi.org/10.1063/1.4818412 for the details of the equivalent blocking stress (Part A), the electrostatic stress(Part B), the equation simplification (Part C) and the dynamic transport process of the cation and water (Part D)
Wallmersperger T, Akle BJ, Leo DJ, Kroplin B (2008) Electrochemical response in ionic polymer transducers: an experimental and theoretical study. Compos Sci Technol 68(5):1173–1180
Pugal D, Kim KJ, Aabloo A (2011) An explicit physics-based model of ionic polymer-metal composite actuators. J Appl Phys 110(8):084904
Zhu Z, Asaka K, Chang L, Takagi K (2013) Multiphysics of ionic polymer–metal composite actuator. J Appl Phys 114:084902
Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, Ithaca
Gong Y, Tang C-y, Tsui C-p, Fan J (2009) Modelling of ionic polymer–metal composites by a multi-field finite element method. Int J Mech Sci 51:741–751
Toi Y, Kang SS (2005) Finite element analysis of two-dimensional electrochemical–mechanical response of ionic conducting polymer–metal composite beams. Comput Struct 83(31–32):2573–2583
Park JK, Jones PJ, Sahagun C, Page KA, Hussey DS, Jacobson DL, Morgan SE, Moore RB (2010) Electrically stimulated gradients in water and counterion concentrations within electroactive polymer actuators. Soft Matter 6(7):1444–1452
Porfiri M (2009) Influence of electrode surface roughness and steric effects on the nonlinear electromechanical behavior of ionic polymer metal composites. Phys Rev E 79(4):041503
Choi P, Datta R (2003) Sorption in proton-exchange membranes an explanation of Schroeder’s paradox. J Electrochem Soc 150(12):E601–E607
Evans CE, Noble RD, Nazeri-Thompson S, Nazeri B, Koval CA (2006) Role of conditioning on water uptake and hydraulic permeability of Nafion® membranes. J Membr Sci 279(1–2):521–528
Salehpoor K, Shahinpoor M, Razani A (1998) Role of ion transport in actuation of ionic polymeric-platinum composite (IPMC) artificial muscles. SPIE Smart Struct Mater 3330:50–58
Bonomo C, Fortuna L, Giannone P, Graziani S (2006) A circuit to model the electrical behavior of an ionic polymer-metal composite. IEEE TransCircuits Syst I 53(2):338–350
Asaka K, Nakabo Y, Mukai T, Luo ZW (2003). In Sice Annual Conference (2003), vol. 1–3, pp 1666–1669
Zhu Z, Wang Y, Liu Y, Asaka K, Sun X, Chang L, Lu P (2016) Application-oriented simplification of actuation mechanism and physical model for ionic polymer-metal composites. J Appl Phys 120:034901
Pugal D, Kim KJ, Punning A, Kasemagi H, Kruusmaa M, Aabloo A (2008) A self-oscillating ionic polymer-metal composite bending actuator. J Appl Phys 103:084908
Wallmersperger T, Leo DJ, Kothera CS (2007) Transport modeling in ionomeric polymer transducers and its relationship to electromechanical coupling. J Appl Phys 101:024912
Zhu Z, Chang L, Takagi K, Wang Y, Chen H, Li D (2014) Water content criterion for relaxation deformation of Nafion based ionic polymer metal composites doped with alkali cations. Appl Phys Lett 105(5):054103
Wang Y, Chen H, Wang Y, Zhu Z, Li D (2014) Effect of dehydration on the mechanical and physicochemical properties of gold- and palladium-Ionomeric Polymer-Metal Composite (IPMC) actuators. Electrochim Acta 129:450–458
Zhu Z, Horiuchi T, Kruusamae K, Chang L, Asaka K (2016) Influence of ambient humidity on the voltage response of ionic polymer–metal composite sensor. J Phys Chem B 120:3215–3225
Zhao H (2011) Diffuse-charge dynamics of ionic liquids in electrochemical systems. Phys Rev E 84:051504
Pugal D, Solin P, Aabloo A, Kim KJ (2013) IPMC mechanoelectrical transduction: its scalability and optimization. Smart Mater Struct 22:125029
Fotsing YK, Tan X (2012) Bias-dependent impedance model for ionic polymer-metal composites. J Appl Phys 111:124907
Farinholt KM, Leo DJ (2008) Modeling the electrical impedance response of ionic polymer transducers. J Appl Phys 104:014512
Chang L, Asaka K, Zhu Z, Wang Y, Chen H, Li D (2014) Effects of surface roughening on the mass transport and mechanical properties of ionic polymer-metal composite. J Appl Phys 115(24):244901
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IPMC shows a large negative relaxation (AVI 120604 kb)
IPMC shows a zero relaxation (AVI 120604 kb)
IPMC shows a positive relaxation (AVI 120604 kb)
IPMC shows no relaxation (AVI 120604 kb)
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Zhu, Z., Chen, H., Chang, L. (2019). IPMC Actuation Mechanisms and Multi-physical Modeling. In: Asaka, K., Okuzaki, H. (eds) Soft Actuators. Springer, Singapore. https://doi.org/10.1007/978-981-13-6850-9_28
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DOI: https://doi.org/10.1007/978-981-13-6850-9_28
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