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Ionic Liquid/Polyurethane/PEDOT:PSS Composite Actuators

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Soft Actuators
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Abstract

The transparent ionic liquid/polyurethane (IL/PU) gels were synthesized by addition reaction of polyol and diisocyanate in the presence of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. With increasing the IL content from 0 to 40 wt%, both ionic conductivity and electric-double-layer capacitance increased from 3.1 × 10−5 S/cm and 9.6 pF/cm2 to 8.8 × 10−5 S/cm and 277 pF/cm2, respectively, while the compression modulus slightly decreased from 0.49 to 0.44 MPa. The IL/PU/PEDOT:PSS composites were fabricated by sandwiching the IL/PU gel between two conductive polymer films made of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT:PSS) as soft and flexible electrodes. Upon application of an electric field, the IL/PU/PEDOT:PSS composite showed quick and intensive bending toward anode, where the bending displacement attained 3.8 mm at IL = 40 wt% and 2 V, corresponding to the strain of 0.32 %.

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References

  1. Osada Y, Okuzaki H, Hori H (1992) A polymer gel with electrically driven motility. Nature 355:242–244

    Article  CAS  Google Scholar 

  2. Yoshida R, Uchida K, Kaneko Y, Sakai K, Kikuchi A, Sakurai Y, Okano T (1995) Comb-type grafted hydrogels with rapid deswelling response to temperature changes. Nature 374:240–242

    Article  CAS  Google Scholar 

  3. Hirai T, Ogiwara T, Fujii K, Ueki T, Kinoshita K, Takasaki M (2009) Electrically active artificial pupil showing amoeba-like pseudopodial deformation. Adv Mater 21:2886–2888

    Article  CAS  Google Scholar 

  4. Yoshida R, Takahashi T, Yamaguchi T, Ichijo H (1996) Self-oscillating gel. J Am Chem Soc 118:5134–5135

    Article  CAS  Google Scholar 

  5. Smela E, Inganäs O, Lundström I (1995) Controlled folding of micrometer-sized structures. Science 268:1735–1738

    Article  CAS  Google Scholar 

  6. Otero TF, Cortés MT (2003) Artificial muscles with tactile sensitivity. Adv Mater 15:279–282

    Article  CAS  Google Scholar 

  7. Hara S, Zama T, Takashima W, Kaneto K (2005) Free-standing gel-like polypyrrole actuators doped with bis(perfluoroalkylsulfonyl)imide exhibiting extremely large strain. Smart Mater Struct 14:1501–1510

    Article  CAS  Google Scholar 

  8. Asaka K, Oguro K, Nishimura Y, Mizuhara M, Takenaka H (1995) Bending of polyelectrolyte membrane-platinum composites by electric stimuli I. Response characteristics to various waveforms. Polym J 27:436–440

    Article  CAS  Google Scholar 

  9. Lu W, Fadeev AG, Qi B, Smela E, Mattes BR, Ding J, Spinks GM, Mazurikiewicz J, Zhou D, Wallace GG, MacFarlane DR, Forsyth SA, Forsyth M (2002) Use of ionic liquid for π-conjugated polymer electrochemical devices. Science 297:983–987

    Article  CAS  Google Scholar 

  10. Lee JW, Yoo YT (2009) Anion effects in imidazolium ionic liquids on the performance of IPMCs. Sens Actuators B 137:539–546

    Article  CAS  Google Scholar 

  11. Fukushima T, Asaka K, Kosaka A, Aida T (2005) Fully plastic actuator through layer-by-layer casting with ionic-liquid-based bucky gel. Angew Chem Int Ed 44:2410–2413

    Article  CAS  Google Scholar 

  12. Bar-Cohen Y (ed) (2001) Electroactive polymer (EAP) actuators as artificial muscles, reality, potential and challenges. SPIE, Bellingham

    Google Scholar 

  13. Pelrine R, Kornbluh R, Pei Q, Joseph J (2000) High-speed electrically actuated elastomers with strain greater than 100 %. Science 287:836–839

    Article  CAS  Google Scholar 

  14. Inoue Y, Yan H, Okuzaki H (2011) Electromechanical properties and actuating behavior of ionic liquid/polydimethylsiloxane gels. Kobunshi Ronbunshu 68:122–126

    Article  CAS  Google Scholar 

  15. Goujon LJ, Khaldi A, Maziz A, Plesse C, Nguyen GTM, Aubert PH, Vidal F, Chevrot C, Teyssié D (2011) Flexible solid polymer electrolytes based on nitrile butadiene rubber/poly(ethylene oxide) interpenetrating polymer networks containing either LiTFSI or EMITFSI. Macromol 44:9683–9691

    Article  CAS  Google Scholar 

  16. Festin N, Maziz A, Plesse C, Teyssié D, Chevrot C, Vidal F (2013) Robust solid polymer electrolyte for conducting IPN actuators. Smart Mater Struct 22:104005

    Article  Google Scholar 

  17. Li Y, Masuda Y, Iriyama Y, Okuzaki H (2012) Stretchable and highly conductive polymer films. Trans Mater Res Soc Jpn 37:303–306

    Article  CAS  Google Scholar 

  18. Randles JEB (1947) Kinetics of rapid electrode reactions. Discuss Faraday Soc 1:11–19

    Article  Google Scholar 

  19. Imaizumi S, Kato Y, Kokubo H, Watanabe M (2012) Driving mechanism of ionic polymer actuators having electric double layer capacitor structures. J Phys Chem B 116:5080–5089

    Article  CAS  Google Scholar 

  20. Otero TF, Martinez JG, Hosaka K, Okuzaki H (2011) Electrochemical characterization of PEDOT-PSS-Sorbitol electrodes. Sorbitol changes cation to anion interchange during reactions. J Electroanal Chem 657:23–27

    Article  CAS  Google Scholar 

  21. Terasawa N, Mukai K, Asaka K (2012) Improved performance of an activated multi-walled carbon nanotube polymer actuator, compared with a single-walled carbon nanotube polymer actuator. Sens Actuators B 173:66–71

    Article  CAS  Google Scholar 

  22. Okuzaki H, Takagi S, Hishiki F, Tanigawa R (2014) Ionic liquid/polyurethane/PEDOT:PSS composites for electro-active polymer actuators. Sens Actuators B 194:59–63

    Article  CAS  Google Scholar 

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Correspondence to Hidenori Okuzaki .

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Okuzaki, H. (2019). Ionic Liquid/Polyurethane/PEDOT:PSS Composite Actuators. In: Asaka, K., Okuzaki, H. (eds) Soft Actuators. Springer, Singapore. https://doi.org/10.1007/978-981-13-6850-9_12

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