Abstract
In the present study, calcium methoxide (Ca(OCH3)2) catalyst was synthesized by the methanolysis of calcined calcium carbonate. The prepared catalyst was then characterized by different physicochemical techniques. The optimization of various reaction parameters for the transesterification of Jatropha curcas oil (JCO) was done by using response surface methodology (RSM) coupled with central composite design (CCD) by using Design Expert software. The polynomial equations based on the second-order model were obtained for transesterification reaction. Independent variables, i.e., methanol to oil molar ratio, catalyst concentration, reaction temperature, and reaction time, were investigated in order to find the maximum value of % biodiesel yield. The adequacy of regression modeling was tested by using analysis of variance (ANOVA). It was observed that biodiesel yield of 90.76% was predicted at the optimal level of catalyst concentration (1 wt%), 9:1 methanol to oil molar ratio, reaction temperature (60 °C), and time (210 min).
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Blanco-Marigorta AM, Suárez-Medina J, Vera-Castellano A (2013) Exergetic analysis of a biodiesel production process from Jatropha curcas. Appl Energ 101:218–225
Boro J, Konwar LJ, Thakur AJ, Deka D (2014) Ba doped CaO derived from waste shells of Tstriatula (TS–CaO) as heterogeneous catalyst for biodiesel production. Fuel 129:182–187
Canakci M, Van Gerpen J (2001) Biodiesel production from oils and fats with high free fatty acids. Trans-ASAE 44(6):1429–1436
Deshmane VG, Adewuyi YG (2013) Synthesis and kinetics of biodiesel formation via calcium methoxide base catalyzed transesterification reaction in the absence and presence of ultrasound. Fuel 107:474–482
Encinar JM, Pardal A, Martínez G (2012) Transesterification of rapeseed oil in subcritical methanol conditions. Fuel Process Technol 94:40–46
Fukuda H, Kondo A, Noda H (2001) Biodiesel fuel production by transesterification of oils. J Biosci Bioeng 92(5):405–416
Hanh HD, Dong NT, Okitsu K et al (2009) Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field. Renew Energ 34:780–783
Helwani Z, Othman MR, Aziz N et al (2009) Solid heterogeneous catalysts for transesterification of triglycerides with methanol: a review. Appl Catal A 363:1–10
Konwar LJ, Boro J, Deka D (2014) Review on latest developments in biodiesel production using carbon-based catalysts. Renew Sust Energ Revi 29:546–564
Kouzu M, Kasuno T, Tajika M et al (2008) Active phase of calcium oxide used as solid base catalyst for transesterification of soybean oil with refluxing methanol. Appl Catal A: Gen 334(1):357–365
Lutz HD, Möller H, Schmidt M (1994) Lattice vibration spectra. Part LXXXII. Brucite-type hydroxides M(OH)2 (M = Ca, Mn Co, Fe, Cd)—IR and Raman spectra, neutron diffraction of Fe(OH)2. J Mol Struct 328:121–132
Mukherjee I, Ray PK (2006) A review of optimization techniques in metal cutting processes. Comp Ind Eng 50:15–34
Park YM, Lee DW, Kim DK et al (2008) The heterogeneous catalyst system for the continuous conversion of free fatty acids in used vegetable oils for the production of biodiesel. Catal Today 131(1):238–243
Silva GF, Camargo FL, Ferreira ALO (2011) Application of response surface methodology for optimization of biodiesel production by transesterification of soybean oil with ethanol. Fuel Process Technol 92:407–413
Tan KT, Lee KT (2009) Production of FAME by palm oil transesterification via supercritical methanol technology. Biomass Bioenerg 33:1096–1099
Theam KL, Islam A, Choo YM et al (2015) Biodiesel from low cost palm stearin using metal doped methoxide solid catalyst. Ind Crop Prod 76:281–289
Teo SH, Taufiq-Yap YH, Rashid U et al (2015) Hydrothermal effect on synthesis, characterization and catalytic properties of calcium methoxide for biodiesel production from crude Jatropha curcas. RSC Adv 5(6):4266–4276
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Mehta, K., Divya, N., Jha, M.K. (2019). Application of RSM for Optimizing the Biodiesel Production Catalyzed by Calcium Methoxide. In: Agnihotri, A., Reddy, K., Bansal, A. (eds) Sustainable Engineering. Lecture Notes in Civil Engineering, vol 30. Springer, Singapore. https://doi.org/10.1007/978-981-13-6717-5_8
Download citation
DOI: https://doi.org/10.1007/978-981-13-6717-5_8
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-6716-8
Online ISBN: 978-981-13-6717-5
eBook Packages: EngineeringEngineering (R0)