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Transistor Application and Intercalation Chemistry of π-Conjugated Hydrocarbon Molecules

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Physics and Chemistry of Carbon-Based Materials

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Abstract

In this chapter, field-effect transistors (FETs) are reported using π-conjugated hydrocarbon molecules (polycyclic hydrocarbons). The p-channel FET properties are recorded for the FETs using polycyclic aromatic hydrocarbons. Currently, the highest field-effect mobility (μ) that polycyclic hydrocarbon FETs reach is 21 cm2 V−1 s−1 for 3,10-ditetradecylpicene, which is one of phenacene-type molecules. Thus, the recent FETs of polycyclic hydrocarbons show excellent FET characteristics, suggesting that the materials are promising as active layers for future practical organic FET devices. In this chapter, the recent advancement of the FETs using polycyclic hydrocarbons are reported completely, in particular the FETs using extended π-conjugated hydrocarbon molecules, such as phenacene, and the FETs using fullerene molecules are also reported. Furthermore, intercalation chemistry of the π-conjugated hydrocarbon molecules is reported, which facilitates realization of novel physical properties, such as superconductivity and ferromagnetism.

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Authors and Affiliations

  1. Research Institute for Interdisciplinary Science, Okayama University, Okayama, Japan

    Yoshihiro Kubozono & Shino Hamao

  2. Department of Electric and Electronic Engineering, Okayama University, Okayama, Japan

    Takahiro Mikami, Yuma Shimo & Yasuhiko Hayashi

  3. Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University, Okayama, Japan

    Hideki Okamoto

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  1. Yoshihiro Kubozono
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Correspondence to Yoshihiro Kubozono .

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    Yoshihiro Kubozono

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Kubozono, Y., Hamao, S., Mikami, T., Shimo, Y., Hayashi, Y., Okamoto, H. (2019). Transistor Application and Intercalation Chemistry of π-Conjugated Hydrocarbon Molecules. In: Kubozono, Y. (eds) Physics and Chemistry of Carbon-Based Materials. Springer, Singapore. https://doi.org/10.1007/978-981-13-3417-7_8

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