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Electronic and Geometric Structures of Cluster Encapsulated Fullerenes

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Physics and Chemistry of Carbon-Based Materials

Abstract

Fullerene cages often encapsulate mono-metal atom, multiple-metal atoms, metal–carbide clusters, metal nitrides, and so on. The entrapped metal atoms donate electrons to the fullerene cages which induces the change of their electronic structure. It has been known so far that the amounts of transferred electrons depend on the number of entrapped atoms and the entrapped species. Ultraviolet photoelectron spectroscopy is a powerful technique to determine the electronic structure and has been used to reveal the electronic structure of fullerenes as well as their cage structure with an aid of theoretical calculation. The electronic structure of endohedral fullerenes revealed by photoelectron spectroscopy is described in this chapter. Geometrical structure of endohedral fullerenes deduced by theoretical calculation is also presented.

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Author information

Authors and Affiliations

  1. Research Laboratory for Surface Science, Okayama University, Okayama, Japan

    Takafumi Miyazaki

  2. Graduate School of Science and Engineering, Ehime University, Matsuyama, Japan

    Shojun Hino

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  1. Takafumi Miyazaki
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  2. Shojun Hino
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Correspondence to Takafumi Miyazaki .

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Editors and Affiliations

  1. Research Institute for Interdisciplinary Science, Okayama University, Okayama, Japan

    Yoshihiro Kubozono

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Miyazaki, T., Hino, S. (2019). Electronic and Geometric Structures of Cluster Encapsulated Fullerenes. In: Kubozono, Y. (eds) Physics and Chemistry of Carbon-Based Materials. Springer, Singapore. https://doi.org/10.1007/978-981-13-3417-7_5

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