Skip to main content

Alternative Fuels for Particulate Control in CI Engines

  • Chapter
  • First Online:
Engine Exhaust Particulates

Part of the book series: Energy, Environment, and Sustainability ((ENENSU))

Abstract

It is widely known that diesel combustion in a compression ignition (CI) engine produces and emits a significant amount of particulate matter (PM) which contributes to degradation in both health and environment. The origin of the soot formation depends on several factors, however, the main source of the soot emissions is the combustion of the diesel fuel itself. To circumvent this issue, studies have been conducted to explore and exploit the advantages of fuels with a lower sooting tendency. Around the world, the utilization of oxygenated biodiesels, such as fatty acid methyl esters (FAME), have been increasing to allow the reduction of PM emissions alongside the net CO2. Due to the FAMEs oxygen content, the fuel is oxidized more readily during the combustion process and thus emitting a significantly lower engine out concentration of PM emission than that of commercial diesel fuel. The utilization of the lighter alcohol fuels, methanol and ethanol neat and blended, is a good option to reduce the soot to zero levels. The reduction of soot to near zero levels introduces another advantage; the soot-NOx trade-off diminishes completely when utilizing exhaust gas recycling (EGR). The issue, however, is that the PN emission of nucleation mode particles is high when utilizing such fuels while ignition is hard to achieve with high octane number fuels in a CI engine.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Aatola H, Larmi M, Sarjovaara T, Mikkonen S (2009) Hydrotreated vegetable oil (HVO) as a renewable diesel fuel: trade-off between NOx, particulate emission, and fuel consumption of a heavy duty engine. SAE Int J Engines 1(1):1251–1262

    Article  Google Scholar 

  • Alfuso S, Auriemma M, Police G, Prati MV (1993) The effect of methyl-ester of rapeseed oil on combustion and emissions of DI diesel engines. SAE technical paper 932801

    Google Scholar 

  • Anneken DJ, Both S, Christoph R, Fieg G et al (2006) Fatty acids. Ullmann’s encyclopedia of industrial chemistry

    Google Scholar 

  • Assessment and Standards Division (Office of Transportation and Air Quality of the US Environmental Protection Agency) (2002) A comprehensive analysis of biodiesel impacts on exhaust emissions, EPA420-P-02-001

    Google Scholar 

  • Bamgboye AI, Hansen AC (2008) Prediction of cetane number of biodiesel fuel from the fatty acid methyl ester (FAME) composition. Int Agrophys 22(1):21–29

    Google Scholar 

  • Ban-Weiss GA, Chen JY, Buchholz BA, Dibble RW (2007) A numerical investigation into the anomalous slight NOx increase when burning biodiesel; a new (old) theory. Fuel Process Technol 88(7):659–667

    Article  Google Scholar 

  • Belgiorno G, Di Blasio G, Shamun S, Beatrice C et al (2018) Performance and emissions of diesel-biodiesel-ethanol blends in a light duty compression ignition engine. Fuel 217:78–90

    Article  Google Scholar 

  • Cardone M, Prati MV, Rocco V, Seggiano M et al (2002) Brassica carinata as an alternative oil crop for the production of biodiesel in Italy: engine performance and regulated and unregulated exhaust emissions. Environ Sci Technol 36(21):4656–4662

    Article  Google Scholar 

  • Collins CD (2007) Implementing phytoremediation of petroleum hydrocarbons. Methods Biotech 23:99–108

    Article  Google Scholar 

  • Diesel Engines for Additized Ethanol. http://www.iea-amf.org/content/fuel_information/ethanol/special_engines_ethanol/diesel_engines_ethanol. Cited 3 July 2018

  • DieselNet Fuel Regulations (2015) EU: Fuels: automotive diesel fuel

    Google Scholar 

  • Durbin TD, Collins JR, Norbeck JM, Smith MR (2000) effects of biodiesel, biodiesel blends, and a synthetic diesel on emissions from light heavy-duty diesel vehicles. Environ Sci Technol 34(3):349–355

    Article  Google Scholar 

  • Ejim CE, Fleck BA, Amirfazli A (2007) Analytical study for atomization of biodiesels and their blends in a typical injector: surface tension and viscosity effects. Fuel 86:1534–1544

    Article  Google Scholar 

  • Fazal MA, Haseeb ASMA, Masjuki HH (2014) A critical review on the tribological compatibility of automotive materials in palm biodiesel. Energy Convers Manage 79(1):180–186

    Article  Google Scholar 

  • Giechaskiel B, Chirico R, DeCarlo PF, Clairotte M et al (2010) Evaluation of the particle measurement programme (PMP) protocol to remove the vehicles’ exhaust aerosol volatile phase. Sci Total Environ 408(21):5106–5116

    Article  Google Scholar 

  • Graboski MS, McCormick RL (1998) Combustion of fat and vegetable oil derived fuels in diesel engines. Prog Energy Combust Sci 24(2):125–164

    Article  Google Scholar 

  • Habib Z, Parthasarathy R, Gollahalli S (2010) Performance and emission characteristics of biofuel in a small-scale gas turbine engine. Fuel 87(5):1701–1709

    Google Scholar 

  • Happonen M, Lädhe T, Messing ME, Sarjovaara T et al (2010) The comparison of particle oxidation and surface structure of diesel soot particles between fossil fuel and novel renewable diesel fuel. Fuel 89:4008–4013

    Article  Google Scholar 

  • Heikilä J, Virtanen A, Rönkkö T, Keskinen J et al (2009) Nanoparticle emissions from a heavy-duty engine running on alternative diesel fuels. Environ Sci Technol 43(24):9501–9506

    Article  Google Scholar 

  • Johansson M, Yang J, Ochoterena R, Gjirja S, Denbratt I (2013) NOx and soot emissions trends for RME, SME and PME fuels using engine and spray experiments in combination with simulations. Fuel 106:293–302

    Article  Google Scholar 

  • Kaiadi M, Johansson B, Lundgren M, Gaynor J (2013) Experimental investigation on different injection strategies for ethanol partially premixed combustion. SAE technical paper 2013-01-0281

    Google Scholar 

  • Kim D, Kim S, Oh S, No SY (2014) Engine performance and emission characteristics of hydrotreated vegetable oil in light duty diesel engines. Fuel 125:36–43

    Article  Google Scholar 

  • Kinoshita E, Myo T, Hamasaki K, Tajima H et al (2006) Diesel combustion characteristics of coconut oil and palm oil biodiesels. SAE technical paper 2006-01-3251

    Google Scholar 

  • Knothe G (2005) Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Process Technol 86(10):1059–1070

    Article  Google Scholar 

  • Kroeger CA (1986) A neat methanol direct injection combustion system for heavy-duty applications. SAE technical paper 861169

    Google Scholar 

  • Kuronen M, Mikkonen S, Aakko P, Murtonen T (2007) Hydrotreated vegetable oil as fuel for heavy duty diesel engines. SAE international, technical paper 2007-01-4031

    Google Scholar 

  • Lapuerta M, Armas O, Ballesteros R (2002) Diesel particulate emissions from biofuels derived from Spanish vegetable oils. SAE technical paper 2002-01-1657

    Google Scholar 

  • Lapuerta M, Villajos M, Agudelo JR, Boehman AL et al (2011) Key properties and blending strategies of hydrotreated vegetable oil as biofuel for diesel engines. Fuel Process Technol 92(12):2406–2411

    Article  Google Scholar 

  • Li H, Lea-Langton A, Andrews GE, Thompson M et al (2008) Comparison of exhaust emissions and particulate size distribution for diesel, biodiesel and cooking oil from a heavy duty DI diesel engine. SAE technical paper 2008-01-0076

    Google Scholar 

  • Marchetti JM, Miguel VU, Errazu AF (2007) Possible methods for biodiesel production. Renew Sustain Energy Rev 11(6):1300–1311

    Article  Google Scholar 

  • Matti MM (2007) Chemical characterization of particulate emissions from diesel engines: a review. J Aerosol Sci 38(11):1079–1118

    Article  Google Scholar 

  • Mayer A, Czerwinski J, Wyser M, Mattrel P et al (2005) Impact of RME/diesel blends on particle formation, particle filtration and PAH emissions. SAE technical paper 2005-01-1728

    Google Scholar 

  • McCormick RL, Alvarez JR, Graboski MS (2003) NOx solutions for biodiesel. National Renewable Energy Laboratory

    Google Scholar 

  • Mi HH, Lee WJ, Chen CB, Yang HH et al (2000) Effect of fuel aromatic content on PAH emission from a heavy-duty diesel engine. Chemosphere 41(11):1783–1790

    Article  Google Scholar 

  • Monyem A, Gerpen JH (2001) The effect of biodiesel oxidation on engine performance and emissions. Biomass Bioenerg 20(4):317–325

    Article  Google Scholar 

  • Mueller CJ, Musculus MP (2001) Glow plug assisted ignition and combustion of methanol in an optical DI diesel engine. SAE technical paper 2001-01-2004

    Google Scholar 

  • Munack A, Schröder O, Krahl J, Bünger J (2001) Comparison of relevant gas emissions from biodiesel and fossil diesel fuel. agricultural engineering international: the CIGR journal of scientific research and development; III: manuscript EE 01 001

    Google Scholar 

  • Murtonen T, Aakko-Saksa P, Murtonen M, Mikkonen S et al (2010) Emissions with heavy-duty diesel engines and vehicles using FAME, HVO and GTL fuels with and without DOC + POC aftertreatmen. SAE Int J Fuels Lubricants 22:147–166

    Google Scholar 

  • Nabi MN, Akhter MS, Shahadat MMZ (2006) Improvement of engine emissions with conventional diesel fuel and diesel-biodiesel blends. Bioresour Technol 97(3):372–378

    Article  Google Scholar 

  • Pham PX, Bodisco TA, Stevanovic S, Rahman MD et al (2013) Engine performance characteristics for biodiesels of different degrees of saturation and carbon chain lengths. SAE Int J Fuels Lubricants 6(1):188–198

    Article  Google Scholar 

  • Physical Properties of Pure Ethanol. https://wiki.anton-paar.com/en/ethanol/. Cited 15 Aug 2018

  • Physical Properties of Pure Methanol. http://www.methanol.org/wp-content/uploads/2016/06/Physical-Properties-of-Pure-Methanol.pdf. Cited 15 Aug 2018

  • Pickett LM, Siebers DL (2004) Soot in diesel fuel jets: effects of ambient temperature, ambient density, and injection pressure. Combust Flame 138(1–2):114–135

    Article  Google Scholar 

  • Schönborn A, Ladommatos N, Allan R, Williams J, Rogerson J (2008) Effect of the molecular structure of individual fatty acid alcohol esters (biodiesel) on the formation of NOx and particulate matter in the diesel combustion process. SAE Int J Fuels Lubricants 1(1):849–872

    Article  Google Scholar 

  • Schwab AW, Bagby MO, Freedman B (1978) Preparation and properties of diesel fuels from vegetable oils. Fuel 66(10):1372–1378

    Article  Google Scholar 

  • Shamun S, Shen M, Johansson B, Tunér M et al (2016) Exhaust PM emissions analysis of alcohol fueled heavy-duty engine utilizing PPC. SAE Int J Engines 9(4):2142–2152

    Article  Google Scholar 

  • Shamun S, HaÅŸimoÄŸlu C, Murcak A, Andersson Ö et al (2017a) Experimental investigation of methanol compression ignition in a high compression ratio HD engine using a Box-Behnken design. Fuel 209:624–633

    Article  Google Scholar 

  • Shamun S, Novakovic M, Malmborg VB, Preger C et al (2017b) Detailed characterization of particulate matter in alcohol exhaust emissions. In: The international symposium on diagnostics and modeling of combustion in internal combustion engines, 2017, 9, B304

    Article  Google Scholar 

  • Shukla PC, Shamun S, Gren L, Malmborg V et al (2018) Investigation of particle number emission characteristics in a heavy-duty compression ignition engine fueled with hydrotreated vegetable oil (HVO): SAE international. Technical paper 2018-01-0909

    Google Scholar 

  • Staat F, Gateau P (1995) The effects of rapeseed oil methyl ester on diesel engine performance, exhaust emissions and long-term behavior—a summary of three years of experimentation. SAE technical paper 950053

    Google Scholar 

  • Svensson S, Li C, Shamun S, Johansson B et al (2016) Potential levels of soot, NOx, HC and CO for methanol combustion. SAE technical paper 2016-01-0887

    Google Scholar 

  • Takesawa Y (1993) Study on palm oil for diesel substitute. Vegetable oils as transport fuels. FAO Press, Pisa

    Google Scholar 

  • Tinsdale M, Price P, Chen R (2010) The impact of biodiesel on particle number, size and mass emissions from a Euro4 diesel vehicle. SAE technical paper 2010-01-0796

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sam Shamun .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2019 Springer Nature Singapore Pte Ltd.

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Shamun, S., Garcia, P., Svensson, E. (2019). Alternative Fuels for Particulate Control in CI Engines. In: Agarwal, A., Dhar, A., Sharma, N., Shukla, P. (eds) Engine Exhaust Particulates. Energy, Environment, and Sustainability. Springer, Singapore. https://doi.org/10.1007/978-981-13-3299-9_9

Download citation

  • DOI: https://doi.org/10.1007/978-981-13-3299-9_9

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-13-3298-2

  • Online ISBN: 978-981-13-3299-9

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics