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New Polymeric Materials Based on Element-Blocks pp 49–58Cite as

Element-Blocks π-Conjugated Polymers by Post-element-Transformation Technique

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Abstract

The synthesis of a new class of π-conjugated polymers possessing versatile element-blocks is described. That is, regioregular organotitanium polymers having titanacyclopentadiene-2,5-diyl units, which are obtained from a low-valent titanium complex and diynes, are subjected to the polymer reactions with elements-containing electrophiles to produce π-conjugated polymers possessing unique element-blocks. Optoelectronic features of the resulting element-blocks π-conjugated polymers are also described.

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Authors and Affiliations

  1. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, Yokohama, Japan

    Ikuyoshi Tomita

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  1. Ikuyoshi Tomita
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Correspondence to Ikuyoshi Tomita .

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Editors and Affiliations

  1. Department of Polymer Chemistry, Kyoto University, Kyoto, Japan

    Yoshiki Chujo

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Tomita, I. (2019). Element-Blocks π-Conjugated Polymers by Post-element-Transformation Technique. In: Chujo, Y. (eds) New Polymeric Materials Based on Element-Blocks. Springer, Singapore. https://doi.org/10.1007/978-981-13-2889-3_3

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