Abstract
In this chapter, preparation, structures, and photoresponsive properties of various azobenzene–siloxane hybrid nanomaterials based on the design of element blocks are described. Hydrolysis and polycondensation reactions accompanied by self-assembly of different types of azobenzene-functionalized alkoxysilane precursors yield hybrids with ordered mesostructures. Lamellar films show reversible d-spacing changes and macroscopic bending–unbending motion by partial trans–cis photoisomerization of the azobenzene groups. Further, incorporation of a cage oligosiloxane into the precursor leads to the formation of cylindrical assemblies, in which efficient photoisomerization of azobenzene is achieved. These findings will contribute to the creation of novel photoresponsive materials.
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References
Ercole F, Davis TP, Evans RA (2010) Photo-responsive systems and biomaterials: photochromic polymers, light-triggered self-assembly, surface modification, fluorescence modulation and beyond. Polym Chem 1:37–54
Yagai S, Kitamura A (2008) Recent advances in photoresponsive supramolecular self-assemblies. Chem Soc Rev 37:1520–1529
Bandarab HMD, Burdette SC (2012) Photoisomerization in different classes of azobenzene. Chem Soc Rev 41:1809–1825
White TJ, Tabiryan NV, Serak SV et al (2008) A high frequency photodriven polymer oscillator. Soft Matter 4:1796–1798
Yamada M, Kondo M, Mamiya J et al (2008) Photomobile polymer materials: toward light-driven motors. Angew Chem Int Ed 47:4986–4988
Yamada M, Kondo M, Miyasato R et al (2009) Photomobile polymer materials: various three-dimensional movements. J Mater Chem 19:60–62
Gelebart AH, Mulder DJ, Varga M et al (2017) Making waves in a photoactive polymer film. Nature 546(29):632–647
Hoffmann F, Cornelius M, Morell J et al (2006) Silica-based mesoporous organic-inorganic hybrid materials. Angew Chem Int Ed 45:3216–3251
Liu N, Chen Z, Dunphy DR et al (2003) Photoresponsive nanocomposites formed by self-assembly of an azobenzene-modified silane. Angew Chem Int Ed 42:1731–1734
Liu N, Dunphy DR, Atanassov P et al (2003) Photoregulation of mass transport through a photoresponsive azobenzene modified nanoporous membrane. Nano Lett 4(4):551–554
Angelos S, Choi E, Vogtle F et al (2007) Photo-driven exclusion of molecules from mesostructured silica nanoparticles. J Phys Chem C 111(18):6589–6592
Angelos S, Yang YW, Khashab NM et al (2009) Dual controlled nanoparticles exhibiting AND logic. J Am Chem Soc 131(32):11344–11346
Lu J, Choi E, Tamanoi F et al (2008) Light-activated nanoimpeller-controlled drug release in cancer cells. Small 4(4):421–426
Alvaro M, Benitez M, Das D et al (2005) Reversible porosity changes in photoresponsive azobenzene-containing periodic mesoporous silicas. Chem Mater 17(20):4958–4964
Besson E, Mehdi V, Lerner DA et al (2005) Photoresponsive ordered hybrid materials containing a bridged azobenzene group. J Mater Chem 15:803–809
Shimojima A, Kuroda K (2006) Designed synthesis of nanostructured siloxane–organic hybrids from amphiphilic silicon-based precursors. Chem Rec 6:53–63
Chemtob A, Ni L, Croutxé-Barghorn C et al (2014) Ordered hybrids from template-free organosilane self-assembly. Chem Eur J 20:1790–1806
Liu N, Yu K, Smarsly B et al (2002) Self-directed assembly of photoactive hybrid silicates derived from an azobenzene-bridged silsesquioxane. J Am Chem Soc 124(49):14540–14541
Guo S, Sugawara-Narutaki A, Okubo T et al (2013) Synthesis of ordered photoresponsive azobenzene–siloxane hybrids by self-assembly. J Mater Chem C 1:6989–6995
Guo S, Chaikittisilp W, Okubo T et al (2014) Azobenzene–siloxane hybrids with lamellar structures from bridged-type alkoxysilyl precursors. RSC Adv 4:25319–25325
Ogawa M, Ishii T, Miyamoto N et al (2001) Photocontrol of the basal spacing of azobenzene-magadiite intercalation compound. Adv Mater 13(14):1107–1109
Nabetani Y, Takamura H, Masui D et al (2011) A photoactivated artificial muscle model unit: reversible, photoinduced sliding of nanosheets. J Am Chem Soc 133:17130–17133
Guo S, Matsukawa K, Miyata T et al (2015) Photoinduced bending of self-assembled azobenzene–siloxane hybrid. J Am Chem Soc 137:15434–15440
Guo S, Sasaki J, Tsujiuchi S et al (2017) Role of cubic siloxane cages in mesostructure formation and photoisomerization of azobenzene–siloxane hybrid. Chem Lett 46(8):1237–1239
Ide T, Ozama Y, Matsui K (2011) Photochemistry of azobenezene in sol-gel systems. J Non-Cryst Solids 357:100–104
Ueda M, Kim HB, Ichimura K (1994) Photochemical and thermal isomerization of azobenzene derivatives in sol-gel bulk materials. Chem Mater 6(10):1771–1775
Ueda M, Kim HB, Ikeda T et al (1993) Photoisomerizability of an azobenzene covalently attached to silica-gel matrix. J Non-Cryst Solids 163:125–132
Guo S, Okubo T, Kuroda K et al (2016) A photoresponsive azobenzene-bridged cubic silsesquioxane network. J Sol-Gel Sci Technol 79:262–269
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Guo, S., Kuroda, K., Shimojima, A. (2019). Design of Element Blocks for Photoresponsive Organosiloxane-Based Materials. In: Chujo, Y. (eds) New Polymeric Materials Based on Element-Blocks. Springer, Singapore. https://doi.org/10.1007/978-981-13-2889-3_14
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DOI: https://doi.org/10.1007/978-981-13-2889-3_14
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