Abstract
The use of reinforcements from natural or animal sources has recently taken relevance because it is a good way of obtaining improved polymers while reducing the environmental impact of the poultry industry, and at the same time, it allows to take advantage of the large amount of waste materials that is frequently considered useless. Styrene-butadiene copolymer (SBS) is used in a wide range of applications, for example, in shoes, adhesives, tires, plastic and asphalt modifiers, among others. However, SBS has limitations due to its mechanical and thermal properties; in some cases, it has been reinforced with particles in order to improve its thermomechanical behavior. Chicken feathers (CFs) represent a waste material from the poultry farming that has not been widely used in the polymer industry yet. Furthermore, in some cases, its final disposal management implies additional costs. CFs is mainly composed of keratin, a mix of proteins that have good mechanical and thermal properties. In the present work, CFs were milled and mixed with SBS with the aim of preparing SBS-CF composites. Composite materials were produced by means of a melt-mixing technique, and the effect of zinc oxide (ZnO) as coupling agent was evaluated. Three different concentrations of CFs at varying mixing speeds were tested with the aim of assessing their effect on the SBS-CF composites properties. The composites thermal properties were measured by means of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and dynamic mechanical analysis (DMA), while their morphologic properties were evaluated by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM).
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References
Askeland D 3rd (ed) (1998) The science and engineering of materials. PWS Pub Co, Richmond
Belarmino DD, Ladchumananandasivam R, Belarmino LD, Pimental JRM, da Rocha BG, Galvao AO, Andrade SMB (2012) Physical and morphological structure of chicken feathers (keratin biofiber) in natural, chemically and thermally modified forms. Mater Sci Appl 3:887–893
Feughelman M (1994) A model for the mechanical properties of the α-keratin cortex. Text Res J 64:236–239
Reddy N, Hu C, Yan K, Yang Y (2011) Thermoplastic films from cyanoethylated chicken feathers. Mater Sci Eng C 31(8):1706–1710
Senoz E, Wool RP, McChalicher CW, Hong CK (2012) Physical and chemical changes in feather keratin during pyrolysis. Polym Degrad Stab 97(3):297–307
Khosa MA, Wu J, Ullah A (2013) Chemical modification, characterization and application of chicken feathers as novel bioabsorbents. R Soc Chem Adv 43:20800–20810
Huda S, Yang Y (2008) Composites from ground chicken quill and polypropylene. Compos Sci Technol 68:790–798
Jimenez Cervantes Amieva E, Velasco Santos C, Martínez Hernández AL, Rivera Armenta JL, Mendoza Martínez AM, Castaño VM (2015) Composites from chicken feathers quill and recycled polypropylene. J Compos Mater 49(3):275–283
Barone JR, Schmidt WF (2005) Polyethylene reinforced with keratin fibers obtained from chicken feathers. Comp Sci Technol 65:173–181
Oladele IO, Okoro AM, Omotoyinbo JA, Khoathane MC (2018) Evaluation of the mechanical properties of chemically modified chicken feather fibers reinforced high density polyethylene composites. J Taibah Univ Sci 12:56–63
Yazid MIM, Supri AG, Zainuddin F, Musa L (2013) Recycled high density polyethylene/natural rubber/chicken feather fibers (RHDPE/NR/CFF) composites: the effects of fiber loading and benzyl urea. Adv Mater Res 795:582–586
Martínez-Hernández AL, Santiago-Valtierra AL, Alvarez-Ponce MJ (2008) Chemical modification of keratin biofibers by graft polymerisation of methyl methacrylate using redox initiation. Mater Res Innov 12:184–191)
Cheng S, Lau KT, Liu T, Zhao Y, Lam PM, Yin Y (2009) Mechanical and thermal properties of chicken feather fiber/PLA green composites. Compos Part B Eng 40(7):650–654
Özmen U, Baba BO (2017) Thermal characterization of chicken feather/PLA biocomposites. J Thermal Anal Calorim 129:347–355
Sánchez-Olivares G, Sánchez-Solis A, Calderas F, Alongi J (2017) Keratin fibres derived from tannery industry wastes for flame retarded PLA composites. Polym Degrad Stab 140:42–54
Subramani T, Krishnan S, Ganesan SK, Nagarajan G (2014) Investigation of mechanical properties in polyester and phenyl-ester composites reinforced with chicken feather fiber. Int J Eng Res Appl 4:93–104
Mishra SC, Nayak NB (2010) An Investigation of dielectric properties of chicken feather reinforced epoxy matrix composite. J Reinf Plast Compos 29:2691–2697
Gokce O, Kasap M, Akpinar G, Ozkoc G (2017) Preparation, characterization, and in vitro evaluation of chicken feather fiber-thermoplastic polyurethane composites. J Appl Polym Sci 45338:1–9
Pourjavaheri F, Jones OAH, Mohaddes F, Sherkat F, Gupta A, Shanks RA (2016) Green plastics: utilizing chicken feather keratin in thermoplastic polyurethane composites to enhance thermo-mechanical properties. In: Society of Plastic Engineers annual technical conference (SPE-ANTEC), May 2016
Janowska G, Kucharsk-Jastrzabek A, Prochon M, Przepiorkowska A (2013) Thermal properties and combustibility of elastomer–protein composites. Part II, Composites NBR–keratin. J Therm Anal Calorim 113:933–938
Jong L (2006) Effect of soy protein concentrate in elastomer composites. Compos Part A Appl Sci Manuf 37:438–446
Prochon M, Janowska G, Przepiorkowska A, Kucharska-Jastrzabek A (2012) Thermal properties and combustibility of elastomer-protein composites. J Therm Anal Calorim 109:1563–1570
Sreenlvasan DP, Sujlth A, Rajesh C (2017) Cure, mechanical and swelling properties of biocomposites from chicken feather fiber and acrylonitrile butadiene rubber. J Polym Environ 1–10
Brebu M, Spiridon I (2011) Thermal degradation of keratin waste. J Anal Appl Pyrolysis 91(2):288–295
Méndez-Hernández ML, Salazar-Cruz BA, Rivera-Armenta JL, Estrada-Moreno IA, Chavez-Cinco MY (2018) Preparation and characterization of composites from copolymer styrene-butadiene and chicken feathers. Polimeros. Ciencia e Tecnologia (accepted to publish 2018)
Hill P, Brantley H, Van Dyke M (2010) Some properties of keratin biomaterials: kerateines. Biomaterials 31(4):585–593
Winandy JE, Muehl JH, Micales JA, Raina A, Schmidt W (2003) Potential of chicken feather fibre in wood MDF composites. Proc EcoComp 2003(20):1–6
Supri AG, Ismail H (2013) Recycled high density polyethylene/natural rubber/chicken feather fibers (RHDPE/NR/CFF) composites: the effect of fiber loading and benzyl urea. Polym Plast Tehcnol Eng 52:1316–1322
Prochoń M, Ntumba YHT (2015) Effects of biopolymer keratin waste sources in XNBR compounds. Rubber Chem Technol 88:258–275
Xiao-Chun Y, Fang-Ying L, Yu-Feng H, Wang Y, Rong-Min W (2013) Study on effective extraction of chicken feather keratins and their films for controlling drug release. Biomater Sci 1:528–536
Jong L (2015) Influence of protein hydrolysis on the mechanical properties of natural rubber composites reinforced with soy proteins particles. Ind Crops Prod 102–109
Zhan M, Wool RP (2016) Mechanical properties of composites with chicken feather and glass fibers. J Appl Polym Sci 133:1–15
Ghani SA, Ismail H, Azimi EA (2017) The effect of maleic anhydride on properties of recycled high density polyethylene/tyre dust/chicken feathers fibers (r-HDPE/TD/CFF) composites. Chiang mai J Sci 44:649–659
Díaz de León CL, Olivas-Armendariz I, Hernández Paz JF, Gómez-Esparza CD, Reyes-Blas H, Hernández-González M, Velasco-Santos C, Rivera-Armenta JL, Rodríguez-González CA (2017) Synthesis by sol-gel and cytotoxicity of zinc oxide nanoparticles using wasted alkaline batteries. Dig J Nanomater Biostruct 12:371–379
Salas G, Rosas N, Galeas S, Guerrero V, Debut A (2016) Synthesis de nanopartículas de ZnO por el método de Pechini. Revista Politécnica 38:1–5
Ghani SA, Izzuddeen M (2014) Tensile properties, swelling behavior, and morphology analysis of recycled high density polyethylene/natural rubber/chicken feather fibers (R-HDPE/NR/CFF) composites: the effect of caprolactam. Adv Mater Res 844:293–296
Villareal DS, Rivera JL, Rivas V, Diaz NP, Páramo U, Gallardo NV, Chávez MY (2017) Manufacturing of composites from chicken feathers and polyvinyl Chloride (PVC). Handb Compos Renew Mater 159–174
Acknowledgments
The authors wish to thank The National Council for Science and Technology of Mexico (CONACYT) for the support to IvánAlziri Estrada-Moreno (72016) through the Program of Cátedras-CONACYT (604). We also wish to thank the National Laboratory of Nanotechnology (Nanotech) for the facilities provided and to Karla Campos for its valuable collaboration during the present research.
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Castillo-Castillo, C. et al. (2018). Evaluation of Elastomeric Composites Reinforced with Chicken Feathers. In: Sidhu, S., Bains, P., Zitoune, R., Yazdani, M. (eds) Futuristic Composites . Materials Horizons: From Nature to Nanomaterials. Springer, Singapore. https://doi.org/10.1007/978-981-13-2417-8_15
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DOI: https://doi.org/10.1007/978-981-13-2417-8_15
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