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Photo-responsive Dynamic Molecular Catalyst for Spatiotemporal Control of Chemical Reactions

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Designed Molecular Space in Material Science and Catalysis

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Abstract

Stimuli-responsive molecular catalyst enables multiple control of chemical reaction(s) to demonstrate highly sophisticated chemical transformations. Among them, photo-responsive dynamic molecular catalyst that changes the structure by photo-stimuli and switches the catalytic functions has recently attracted much interest due to the potential of photo-stimuli as clean and diverse noninvasive stimuli. This chapter focuses on the photo-responsive dynamic catalysts that reversibly switch the catalytic function on the basis of the dynamic conformation changes induced by external photo-stimuli. Recent progresses in the field of photo-responsive dynamic catalysts are highlighted. Although the progress is still small in present stage, this type of catalysts could open up new possibilities in various fields of scientific researches as well as synthetic chemistry.

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Authors and Affiliations

  1. Department of Industrial Chemistry, Tokyo University of Science, Shinjyuku-ku, Tokyo, Japan

    Tatsushi Imahori

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  1. Tatsushi Imahori
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Correspondence to Tatsushi Imahori .

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  1. Department of Environmental Science Graduate School of Fisheries and Environmental Sciences, Nagasaki University, Nagasaki, Japan

    Seiji Shirakawa

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Imahori, T. (2018). Photo-responsive Dynamic Molecular Catalyst for Spatiotemporal Control of Chemical Reactions. In: Shirakawa, S. (eds) Designed Molecular Space in Material Science and Catalysis. Springer, Singapore. https://doi.org/10.1007/978-981-13-1256-4_10

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