Abstract
This chapter includes a series of phase diagrams of AlN-based non-oxide systems. The phase diagrams are collected from that of several systems, i.e., AlN–Al2O3, AlN–SiC, AlN–Al2OC–SiC, and Al4C3–AlN–SiC. They are constructed by solid phases of quaternary AlN–Al4C3–Al2O3–SiC system, in which the AlN–Al2OC–SiC system was revealed to be a phase diagram of solid solution with tetrahedral [MX4] wurtzite structure (see Appendix Table A.5). Especially, the phase relations of ternary Al4C3–AlN–SiC system have attracted much attention. In addition, AlN–SiC–R2O3 (R = light rare earths) systems exist R2(Al1−xSix)O3(N1−xCx) solid solution with K2NiF4 structure. All these phase diagrams of AlN-based non-oxide ceramics systems are very important for crystal chemistry and physical chemistry.
The original version of this chapter was revised: Belated corrections have been incorporated. The erratum to this chapter is available at https://doi.org/10.1007/978-981-13-0463-7_5
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
FACT FTOxCN oxycarbonitride database. http://www.crct.polymtl.ca/fact/documentation/FTOxCN/FTOxCN_documentation.htm
McCauley JW, Corbin ND (1983) High temperature reactions and microstructures in the Al2O3-AlN system. NATO ASI Ser, Ser E Prog Nitrogen Ceram 111–118
McCauley JW, Corbin ND (1979) Phase relations and reaction sintering of transparent cubic aluminum oxynitride spinel (ALON). J Am Ceram Soc 62(9–10):476–479
Thompson DP, Korgul P, Hendry A (1983) The structural characterisation of SiAlON polytypoids. Progress in nitrogen ceramics. Springer, Netherlands, pp 61–74
Barry TI, Dinsdale AT, Gisby JA et al (1992) The compound energy model for ionic solutions with applications to solid oxides. J Phase Equilibr 13(5):459–475
Hillert M, Jonsson S (1999) Report No. TRITA-MAC 399. Royal Institute of Technology, Stockholm
Mao H, Selleby M (2007) Thermodynamic reassessment of the Si3N4-AlN-Al2O3-SiO2 system-modeling of the SiAlON and liquid phases. CALPHAD Comput Coupling Phase Diagr Thermochem 31(2):269–280
Larrere Y, Willer B, Lihrmann JM et al (1984) Dagrammes d’équilibre stable et métastable dans le système Al2O3-Al4C3. Revue internationale des hautes températures et des réfractaires 21(1):3–18
Foster LM, Long G, Hunter MS (1956) Reactions between aluminum oxide and carbon the Al2O3–Al4C3 phase diagram. J Am Ceram Soc 39(1):1–11
Pavlyuchkov D, Fabrichnaya O, Herrmann M et al (2012) Thermodynamic assessments of the Al2O3–Al4C3–AlN and Al4C3–AlN–SiC systems. J Phase Equilibr Diffus 33(5):357–368
Qiu C, Metselaar R (1995) Thermodynamic evaluation of the Al2O3-Al4C3 system stability of Al-Oxycarbides. Zeitschrift Fur Metallkunde 86(3):198–205
Qiu C, Metselaar R (1997) Phase relations in the aluminum carbide-aluminum nitride-aluminum oxide system. J Am Ceram Soc 80(8):2013–2020
Lihrmann JM, Tirlocq J, Descamps P et al (1999) Thermodynamics of the Al–C–O system and properties of SiC–AlN–Al2OC composites. J Eur Ceram Soc 19(16):2781–2787
Zangvil A, Ruh R (1988) Phase relationships in the silicon carbide-aluminum nitride system. J Am Ceram Soc 71(10):884–890
Rafaniello W, Plichta MR, Virkar AV (1983) Investigation of phase stability in the system SiC-AlN. J Am Ceram Soc 66(4):272–276
Schneider A, Schober R (1994) New materials in the AlCON-system. In: Proceedings of International Conference Ceramic Processing Science and Technology, Friedrichshafen (Germany), 11–14, Sept 1994
Oden LL, McCune RA (1987) Phase equilibria in the Al–Si–C system. Metall Mater Trans A 18(12):2005–2014
Inoue Z, Inomata Y, Tanaka H et al (1980) X-ray crystallographic data on aluminum silicon carbide, α-Al4SiC4 and Al4Si2C5. J Mater Sci 15(3):575–580
Oscroft RJ, Korgul P, Thompson DP (1989) British ceramics proceedings. Complex microstructure, vol. 42. Maney Publishing, London, pp 33–47
Kidwell BL, Oden LL, McCune RA (1984) 2Al4C3SiC: a new intermediate phase in the Al–Si–C system. J Appl Crystallogr 17(6):481–482
Barczak VJ (1961) Optical and X-ray powder diffraction data for Al4SiC4. J Am Ceram Soc 44(6):299
Groebner J, Lukas HL, Aldinger F (1996) Thermodynamic calculation of the ternary system Al–Si–C. CALPHAD Comput Coupling Phase Diagr Thermochem 20(2):247–254
Schneider G, Gauckler LJ, Petzow G (1979) Phase equilibria in the Si, Al, Be/C, N system. Ceramurgia Int 5(3):101–104
Jeffrey GA, Wu V (1966) The structure of the aluminum carbonitrides. II. Acta Crystallogr 20(4):538–547
Oden LL, McCune RA (1990) Contribution to the phase diagram Al4C3-AlN-SiC. J Am Ceram Soc 73(6):1529–1533
Burton BP, Walle AVD, Kattner U (2006) First principles phase diagram calculations for the wurtzite-structure systems AlN-GaN, GaN-InN, and AlN-InN. J Appl Phys 100(11):113528/1–113528/6
Huang ZK, Yan DS, Tien TY (1990) Compound formation and melting behavior in the AB compound and rare earth oxide systems. J Solid State Chem 85(1):51–55
Marchand R (1976) Oxynitrides with potassium nickel(II) tetrafluoride structure. Ln2AlO3N compounds (Ln = lanthanum, neodymium, samarium). Comptes Rendus de l’ Academie des Sciences Serie IIc. Chemie 282(7):329–331
Yen TS, Kuo CK, Han WL et al (1983) Phase equilibria in the systems rare-earth sesquioxide-beryllium oxide. J Am Ceram Soc 66(12):860–862
Huang ZK, Tien TY (1996) Solid-liquid reaction in the Si3N4–AlN–Y2O3 system under 1 MPa of nitrogen. J Am Ceram Soc 79(6):1717–1719
Huang ZK, Rosenflanz A, Chen IW (1997) Pressureless sintering of Si3N4 ceramic using AlN and rare-earth oxides. J Am Ceram Soc 80(5):1256–1262
Kouhik B (2002) Liquid phase sintering of SiC ceramics with rare earth sesquioxides. Ph.D. Thesis, University of Stuttgart, Stuttgart. http://citeseerx.ist/psu.edu/viewdoc/download?doi=10.1.1.632.4758&rep1&type = pdf
Jack KH (1976) SiAlONs and related nitrogen ceramics. J Mater Sci 11(6):1135–1158
Weiss J, Greil P, Gauckler LJ (1982) The systme Al–Mg–O–N. J Am Ceram Soc 65(5):C68–C69
Sun WY, Ma LT, Yan DS (1990) Phase relationship in Mg–Al–O–N system. Sci Bull (Chinese) 35(14):1189–1192
Kuang SF, Huang ZK, Sun WY et al (1990) Phase relationships in the system MgO–Si3N4–AlN. J Mater Sci Lett 9(1):69–71
Sun WY, Yen TS (1989) Phase relationships in the system Ca–Al–O–N. Mater Lett 8(5):150–152
Komeya K, Tsuge A, Inoue H et al (1982) Effect of CaCO3 addition on the sintering of AlN. J Mater Sci Lett 1(8):325–326
Sun WY, Yen TS (1989) Phase relationships in the system Nd–Al–O–N. Mater Lett 8(5):145–149
Sun WY., Chen JX, Jia YX et al (1990) Phase relationships in the system R2O3–AlN–Al2O3 (R = Ce,Pr,Nd,Sm). China Sci A(9):990–998
Kaiser A, Telle R, Herrmann M et al (2001) Subsolidus phase relationships of the β-SiAlON solid solution in the oxygen-rich part of the Nd–Si–Al–ON system. Zeitschrift für Metallkunde 92(10):1163–1169
Schneider G, Gauckler LJ, Petzow G (1980) Phase equilibria in the system AlN–Si3N4–Be3N2. J Am Ceram Soc 63(1–2):32–35
Rabenau A, Eckerlin P (1960) Special ceramics. In: Popper P (ed) Academic Press, vol 1. New York, pp 136–143
Gauckler LJ (1975) Equilibrium in the systems Si, Al/N, O and Si, Al, Be/N, O. Ph.D. Dissertation, University of Stuttgart, Stuttgart, Germany
Chen YH, Sun WZ, Wu LE et al (2013) Phase relations in SiC–AlN–R2O3 (R = Nd, Gd, Yb, Y) systems. J Phase Equilibr Diffus 34(1):3–8
Pan WG, Wu LE, Jiang Y et al (2017) Solid solution and phase relations in SiC–AlN–Pr2O3 system. J Phase Equilibr Diffus 38(5):676–683
Jiang Y, Wu LE, Huang ZK (2014) Solid-solution of nitrogen-containing rare earth aluminates R2AlO3N (R = Nd and Sm). Ceram Eng Sci Proc 34(2):95–99
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Huang, Z., Wu, L. (2018). AlN-Based Ceramics Systems. In: Phase Equilibria Diagrams of High Temperature Non-oxide Ceramics. Springer, Singapore. https://doi.org/10.1007/978-981-13-0463-7_3
Download citation
DOI: https://doi.org/10.1007/978-981-13-0463-7_3
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-0462-0
Online ISBN: 978-981-13-0463-7
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)