Abstract
Tooth-colored dental resins are widely used. Dental resins divide broadly into two categories: chemical-curing type and light-curing type. In this chapter, we discuss the photochemistry in dentistry such as several sorts of curing system and reaction. In order to understand resin materials for dental purposes, two main points have to be concerned: One is “adhesion” or “bonding” to tooth substrates, and the other is “curing” for setting of resin-based materials. Dental resins themselves do not provide bonding ability to tooth substrates; tooth-colored dental resins need additional adhesives before dental resin filling. Without setting through polymerization of dental monomers, resin-based materials cannot stably exist in a severe oral condition. Insufficient polymerization causes dental resin degradation and secondary caries. In order to improve polymerization, initiators for curing and curing devices have been developed to improve polymerization. Therefore, at first the structure of tooth is explained in brief to understand “adhesion” to tooth substrates, enamel and dentin. Then, the history of the development of tooth-colored dental resins and adhesive resins is then introduced. Next, curing systems used in dental resin materials are explained. Moreover, toxicity of dental resin and future research opportunities are included.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ten Cate, A.R.: Oral Historogy: Development, Structure and Function, 7th edn. Mosby, St Luis, Mussouri (2008)
Imbeni, V., Nalla, R.K., Bosi, C., Kinney, J.H., Ritchie, R.O.: On the in vitro fracture toughness of human dentin. J. Biomed. Mater. Res. A 66, 1–9 (2003)
Braly, A., Darnell, L.A, Mann, A.B., Teaford, M.F., Weihs, T.P.: The effect of prism orientation on the indentation testing of human molar enamel. Arch. Oral Biol. 52(9), 856–860 (2007)
Laurance-Young, P., Bozec, L., Gracia, L., Rees, G., Lippert, F., Lynch, R.J., Knowles, J.C.: A review of the structure of human and bovine dental hard tissues and their physicochemical behaviour in relation to erosive challenge and remineralisation. J. Dent. 39(4), 266–272 (2011)
Kinney, J.H., Marshall, S.J., Marshall, G.W.: The mechanical properties of human dentin: a critical review and re-evaluation of the dental literature. Crit. Rev. Oral Biol. Med. 14(1), 13–29 (2003)
Xue, J., Zavgorodniy, A.V., Kennedy, B.J., Swain, M.V., Li, W.: X-ray microdiffraction, TEM characterization and texture analysis of human dentin and enamel. J. Microsc. 251(2), 144–153 (2013)
Van Landuyt, K.L., Snauwaert, J., De Munck, J., Peumans, M., Yoshida, Y., Poitevin, A., Coutinho, E., Suzuki, K., Lambrechts, P., Van Meerbeek, B.: Systematic review of the chemical composition of contemporary dental adhesives. Biomaterials 28(26), 3757–3785 (2007)
Nakabayashi, N., Nakamura, M., Yasuda, N.: Hybrid layer as a dentin-bonding mechanism. J. Esthet. Dent. 3(4), 133–138 (1991)
Nakabayashi, N., Kojima, K., Masuhara, E.: The promotion of adhesion by the infiltration of monomers into tooth substrates. J. Biomed. Mater. Sci. 16, 265–273 (1982)
Gwinnett, A.J.: Moist versus dry dentin: its effect on shear bond strength. Am. J. Dent. 5, 127–129 (1992)
Kanca, J.: Effect of resin primer solvents and surface wetness on resin composite bond strength to dentin. Am. J. Dent. 5, 213–215 (1992)
Tay, F.R., Gwinnett, A.J., Wei, S.H.: The overwet phenomenon: a transmission electron microscopic study of surface moisture in the acid-conditioned, resin–dentin interface. Am. J. Dent. 9, 161–166 (1996)
Peumans, M., Kanumilli, P., De Munck, J., Van Landuyt, K., Lambrechts, P., Van Meerbeek, B.: Clinical effectiveness of contemporary adhesives: a systematic review of current clinical trials. Dent. Mater. 21, 864–881 (2005)
Peumans, M., De Munck, J., Van Landuyt, K.L., Poitevin, A., Lambrechts, P., Van Meerbeek, B.: Eight-year clinical evaluation of a two-step self-etch adhesive with and without selective enamel etching. Dent. Mater. 1176–1184 (2010)
Akimoto, N., Takamizu, M., Momoi, Y.: 10-year clinical evaluation of a self-etching adhesive system. Oper. Dent. 32, 3–10 (2007)
Carvalho, R.M., Chersoni, S., Frankenberger, R., Pashley, D.H., Prati, C., Tay, F.R.: A challenge to the conventional wisdom that simultaneous etching and resin infiltration always occurs in self-etch adhesives. Biomaterials 26, 1035–1042 (2005)
Salz, U., Mucke, A., Zimmermann, J., Tay, F.R., Pashley, D.H.: pKa value and buffering capacity of acidic monomers commonly used in self-etching primers. J. Adhes. Dent. 8, 143–150 (2006)
Chan, K.M., Tay, F.R., King, N.M., Imazato, S., Pashley, D.H.: Bonding of mild self-etching primers/adhesives to dentin with thick smear layers. Am. J. Dent. 16, 340–346 (2003)
Yoshida, Y., Nagakane, K., Fukuda, R., Nakayama, Y., Okazaki, M., Shintani, H., Inoue, S., Tagawa, Y., Suzuki, K., De Munck, J., Van Meerbeek, B.: Comparative study on adhesive performance of functional monomers. J. Dent. Res. 83(6), 454–458 (2004)
Yoshihara, K., Yoshida, Y., Nagaoka, N., Fukegawa, D., Hayakawa, S., Mine, A., Nakamura, M., Minagi, S., Osaka, A., Suzuki, K., Van Meerbeek, B.: Nano-controlled molecular interaction at adhesive interfaces for hard tissue reconstruction. Acta Biomater. 6(9), 3573–3582 (2010)
Oguri, M., Yoshida, Y., Yoshihara, K., Miyauchi, T., Nakamura, Y., Shimoda, S., Hanabusa, M., Momoi, Y., Van Meerbeek, B.: Effects of functional monomers and photo-initiators on the degree of conversion of a dental adhesive. Acta Biomater. 8(5), 1928–1934 (2012)
Sideridou, I.D., Achilias, D.S., Karava, O.: Reactivity of benzoyl peroxide/amine system as an initiator for the free radical polymerization of dental and orthopaedic dimethacrylate monomers: effect of the amine and monomer chemical structure. Macromolecules 39, 2072–2080 (2006)
Kwon, T.Y., Bagheri, R., Kim, Y.K., Kim, K.H., Burrow, M.F.: Cure mechanisms in materials for use in esthetic dentistry. J. Invest. Clin. Dent. 3(1), 3–16 (2012)
Jakubiak, J., Allonas, X., Fouassier, J.P., Sionkowska, A., Andrzejewska, E., Linden, L.A., Rabek, J.F.: Camphorquinone-amines photoinitiating systems for the initiation of free radical polymerization. Polymer 44, 5219–5226 (2003)
Yu, Q., Nauman, S., Santerre, J.P., Zhu, S.: UV photopolymerization behavior of dimethacrylate oligomers with camphorquinone/amine initiator system. J. Appl. Polym. Sci. 82, 1107–1117 (2001)
Watts, D.C.: Reaction kinetics and mechanics in photo-polymerised networks. Dent. Mater. 21(1), 27–35 (2005)
Jandt, K.D., Mills, R.W.: A brief history of LED photopolymerization. Dent. Mater. 29(6), 605–617 (2013)
Rueggeberg, F.A.: State-of-the-art: dental photocuring–a review. Dent. Mater. 27(1), 39–52 (2011)
Fano, V., Shatel, M., Tanzi, M.L.: Release phenomena and toxicity in polymer-based dental restorative materials. Acta Biomed. 78(3), 190–197 (2007)
Mallineni, S.K., Nuvvula, S., Matinlinna, J.P., Yiu, C.K., King, N.M.: Biocompatibility of various dental materials in contemporary dentistry: a narrative insight. J. Invest.Clin. Dent. 4(1), 9–19 (2013)
Söderholm, K.J., Mariotti, A.: BIS-GMA–based resins in dentistry: are they safe? J. Am. Dent. Assoc. 130(2), 201–209 (1999)
Schweikl, H., Spagnuolo, G., Schmalz, G.: Genetic and cellular toxicology of dental resin monomers. J. Dent. Res. 85(10), 870–877 (2006). Review
Schweikl, H., Hartmann, A., Hiller, K.A., Spagnuolo, G., Bolay, C., Brockhoff, G., Schmalz, G.: Inhibition of TEGDMA and HEMA-induced genotoxicity and cell cycle arrest by N-acetylcysteine. Dent. Mater. 23(6), 688–695 (2007)
Ferracane, J.L.: Resin-based composite performance: are there some things we can’t predict? Dent. Mater. 29(1), 51–58 (2013)
Geurtsen, W., Spahl, W., Muller, K., Leyhausen, G.: Aqueous extracts from dentin adhesives contain cytotoxic chemicals. J. Biomed. Mater. Res. 48, 772–777 (1999)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this chapter
Cite this chapter
Yoshihara, K., Yoshida, Y. (2018). Dental Resin. In: Ito, Y. (eds) Photochemistry for Biomedical Applications. Springer, Singapore. https://doi.org/10.1007/978-981-13-0152-0_7
Download citation
DOI: https://doi.org/10.1007/978-981-13-0152-0_7
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-0151-3
Online ISBN: 978-981-13-0152-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)