Abstract
A poly 3-methylthiophene/nano-TiO2 composite was prepared by in situ oxidative polymerization technique. We explored properties of the composite when nano-TiO2 was modified and unmodified, researched the representation of the composite with different molar ratios of 3-methylthiophene and anhydrous FeCl3, different mass ratios of 3-methylthiophene and nano-TiO2. The results show that the photoelectric property of poly-3-methylthiophene/modified nano-TiO2 composite is better than that of unmodified nano-TiO2 composite. When the molar ratio of 3-methylthiophene and anhydrous FeCl3 is 1:2, the mass ratio of 3-methylthiophene and nano-TiO2 is 2:1, the composite material has good optical properties.
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References
H. Shirakawa, E. Louis, A. MacDiarmid, C.K. Chiang, A.J. Heeger, Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH)X. J. Chem. Soc. Chemi. Commun. 10, 578–580 (1977)
H. Naarmann, Synthesis of electrically conducting polymers. Angew. Makromol. Chem. 109, 295–338 (1982)
C.O. Yoon, H.K. Sung, J.H. Kim, E. Barsoukov, J.H. Kim, The effect of low-temperature conditions on the electrochemical polymerization of polypyrrole films with high density, high electrical conductivity and high stability. Synth. Met. 99, 201–212 (1999)
J. Koh, J. Kim, B. Kim, J. Kim, E. Kim, Highly efficient, iodine-free dye-sensitized solar cells with solid-state synthesis of conducting polymers. Adv. Mater. 23, 1641–1646 (2011)
N. Hebestreit, J. Hofmann, U. Rammelt, W. Plieth, Physical and electrochemical characterization of nanocomposites formed from polythiophene and titaniumdioxide. Electrochim. Acta 48, 1779–1788 (2003)
G.D. Sharma, P. Suresh, S. Kumar Sharma, M.S. Roy, Optical and electrical properties of hybrid photovoltaic devices from poly(3-phenyl hydrazone thiophene) (PPHT) and TiO2 blend films. Sol. Energy Mater. Sol. Cells 92, 1–70 (2008)
Y. Li, Conducting polymers. Prog. Chem. 14, 207–211 (2002)
Y. Du, K. Cai, Research progress in electrical properties of polythiophene, polythiophene derivatives and polythiophene based composites. Mater. Rev. 24, 69–73 (2010)
X. Li, M. Huang, H. Shen, Preparation and properties of polythiophene nanocomposites, chemical industry and engineering progress. Chem. Ind. Eng. Prog. 26, 1243–1245 (2007)
T. Hai, R. Sugimoto, Effect of molar ratio of oxidizer/3-hexylthiophene monomer in chemical oxidative polymerization of poly(3-hexylthiophene). J. Mol. Struct. 1146, 660–668 (2017)
A.G.R. Morales, M.O.C. Guzmán, C.C. Arteaga, A brief review on fabrication and applications of auto-organized TiO2 nanotube arrays. Corros. Rev. 29, 105–121 (2011)
H. Irie, Y. Watanabe, K. Hashimoto, Nitrogen-concentration dependence on photocatalytic activity of TiO2−X NX powders. J. Phys. Chem. B. 107, 5483–5486 (2003)
O. Carp, C. Huisman, A. Reller, Photoinduced reactivity of titanium dioxide. Prog. Solid State Chem. 32, 33–177 (2004)
P. Vanlaeke, A. Swinnen, I. Haeldermans, G. Vanhoyland, T. Aernouts, D. Cheyns, C. Deibel, J. D’Haen, P. Heremans, J. Poortmans, J.V. Manca, P3HT/PCBM bulk heterojunction solar cells: relation between morphology and electro-optical characteristics. Sol. Energy Mater. Sol. Cells 90, 2150–2158 (2006)
S. Li, M. Ma, Y. Wei, X.S. Hong, Y.H. Wang, Preparation of PTh/TiO2 nanocomposite by solid-state method and its photocatalytic activity under visible light irradiation. Chem. Res. Appl. 21, 1627–1631 (2009)
S. Xue, Q. Liu, Preparation of Polythiophene/Polypyrrole/TiO2 composite conductive polymers by solid-state method and its anti-corrosion properties for stainless steel. Chin. J. Inorg. Chem. 33, 98–102 (2016)
J. Yu, H. Jiang, C. Shi, Study on surface modification of TiO2 via in situ polymerization. Chem. Produc. Tech. 11, 21–23 (2004)
K. Wang, J. Niu, K. Chen, Surface modification of TiO2 and its influence on thermal insulation property of coatings. Dye Fini. 35, 1–5 (2009)
X.H. Peng, Organic surface modification of titanium dioxide and electrophoretic properties of the resulting materials. J. B Univ. Chem. Technol. (Nat. Sci. Ed.) 33, 11–14 (2006)
H. Yin, J. Jiang, Studies of preparation and conductivity of γ-Fe2O3/polythiophene nanocomposites. J. Funct. Mater. 36, 1524–1527 (2005)
W. Zhang, Y. He, Q. Qi, Preparation of porous TiO2 film of photocatalyst by microemulsion templating. J. Funct. Mater. 36, 1590–1593 (2005)
S. Yu, J. Yang, J. Gu, Study on the inductive effect conjugative and orientation effect of methyl substituent. J. B Norm. Univ. (Nat. Sci.) 42, 506–509 (2006)
Y. Wang, J. Wang, J. Yue, Q. Luo, D. Wang, Recent development of conducting polymer nanocomposites. Chem. Ind. Tim. 21, 73–77 (2007)
Acknowledgements
This work was financially supported by a program of education department (No. 17ZB0049) of Sichuan province, and the program of innovative entrepreneurship training (No. 201610616063) of provincial college students.
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Gao, L., Yan, X., Yang, X., Ma, W., Du, H. (2018). Preparation and Photoelectric Property of Poly-3-Methylthiophene/Nano-TiO2 Composite. In: Han, Y. (eds) Advanced Functional Materials. CMC 2017. Springer, Singapore. https://doi.org/10.1007/978-981-13-0110-0_6
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DOI: https://doi.org/10.1007/978-981-13-0110-0_6
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