Abstract
The effects of Zr and Cu content on mechanical properties, glass forming ability and thermal stability of Zr63.68−xCu16.2+x Ni10.12 Al10 (x = 0, 0.45, 0.9, 1.35, 1.8, 2.25, 2.7) bulk metallic glasses (BMGs) has been studied. The specimens with diameters of 2, 4 and 6 mm cut from the same ladder-shaped BMG rod by copper mold suction casting method were used in the present investigation. The results show that with the increase of Cu content and the decrease of Zr content the prepared alloy specimens with diameter of 2 mm are completely amorphous. The plastic strain shows the trend of increasing at first and then decreasing. At x = 1.8, the plastic strain reaches the maximum and its value is 38.74%, about 4.3 times of Zr63.68Cu16.2Ni10.12Al10 (BMG) 9.10%. The elastic modulus is 51,757 MPa, the yield strength is 2079 MPa, the compressive strength and the fracture strength are 3861 MPa. With the increase of specimens size, there is obvious scale effect in plastic strain. It is also found that the plastic strain is up to 30.94% for specimens with diameter of 4 mm, showing a great plasticity. With the increase of Cu atoms and the decrease of Zr atoms, the width of the super-cooled liquid region (ΔTx = Tx − Tg) and parameter (γ = Tx/(Tg + Tl)) both increase first and then decrease, the maximum values can reach 98 and 0.395 respectively at x = 1.35. The parameter γ tends to be constant at x = 1.8–2.7.
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C.T. Liu, L. Heatherly, D.S. Eaton, Test environments and mechanical properties of Zr-base bulk amorphous alloys. Metall. Mater. Trans. A 29, 1811–1820 (1998)
X.L. Guo, D.J. Li, Y.M. Wang, J.B. Qiang, C. Dong, Fracture behavior of bulk amorphous alloy Zr65A17.5Ni10Cu17.5 under uniaxial compression at room temperature. Acta. Metall. Sin. 39, 1089–1093 (2003)
J.S. Huang, Y. Liu, S.Q. Chen, Z.M. Liu, B.Y. Huang. Research progress and application of Zr based amorphous alloys. Chin. J. Nonferr. Met. 13, 1321–1332 (2003)
D.C. Hofmann, J.Y. Suh, A. Wiest, G. Duan, M.L. Lind, Designing metallic glass matrix composites with high toughness and tensile ductility. Nature 451, 1085–1089 (2008)
L.Y. Chen, Z.D. Fu, G.Q. Zhang, X.P. Hao, Q.K. Jiang, New class of plastic bulk metallic glas. Phys. Rev. Lett. 100, 652–663 (2008)
Z. Tan, Y.F. Xue, X.W. Cheng, L. Zhang, W.W. Chen, L. Wang, H.F. Zhang, H.M. Fu, Effect of element fitting on compositions optimization of Al-Cu-Ti amorphous alloy by mechanical alloying. Trans. Nonferr. Met. Soc. China 25, 3348–3353 (2015)
F. Jiang, L. He, M.B. Zhong, Z.H. Han, Q. Zhao, Orientation effect of pre-introduced shear bands in a bulk-metallic glass on its “work-ductilising”. Mater. Sci. Eng. A 496, 285–290 (2008)
M.Q. Jiang, Research progress in plasticity theory of amorphous alloys. Mater. China 33, 257–264 (2014)
C. Sun, H.W. Chen, Y.F. Xue, C. Chen, J. Liu, J. Teng, Study on low temperature dynamic compressive properties of Ti40Zr25Ni8Cu9Be18 bulk amorphous alloys. Rare Met. Mater. Eng. 43, 960–963 (2014)
L. Liu, H. Song, X.J. Zhao, W. Liu, Effect of sample size on Pd based bulk amorphous alloy internal shear bands. Rare Met. Mater. Eng. 44, 1522–1526 (2015)
N.Q. Pan, Z.H. Du, Z.W. Zhu, X.Y. Lei, L.Z. Xu, Temperature rise and fracture temperature rise in the shear band of Zr-Ti-Ni-Cu-Be bulk amorphous alloy. Chin. J. Nonferr. Met. 26, 973–979 (2016)
Z.F. Zhang, R.T. Qu, Z.Q. Liu, Research progress in fracture behavior and strength theory of metallic glass. Acta Metall. Sin. 52, 1171–1182 (2016)
Y.J. Sun, Y.H. Zhai, Low temperature compressive deformation behavior of ZrCuNiAl bulk amorphous alloys. Heat Treat. Met. 41, 25–28 (2016)
H.B. Yu, X. Shen, Z. Wang, L. Gu, W.H. Wang, H.Y. Bai, Tensile plasticity in metallic glasses with pronounced β relaxations. Phys. Rev. Lett. 108, 015504 (2012)
Y.H. Liu, G. Wang, M.X. Pan, W.H. Wang, Super plastic bulk metallic glasses at room temperature. Science 315, 1385–1388 (2007)
H.B. Yu, W.H. Wang, H.Y. Bai, Y. Wu, M.W. Chen, Phys. Rev. B 81, 220201 (2010)
H.L. Peng, M.Z. Li, W.H. Wang, Structural signature of plastic deformation in metallic glasses. Phys. Rev. Lett. 106, 135503 (2011)
M.H. Lee et al., Phys. Status Solidi RRL 3, 46–49 (2009)
J.M. Park, D.H. Kim, J. Eckert, Internal state modulation-mediated plasticity enhancement in monolithic Ti-based bulk metallic glass. Intermetallics 29, 70–74 (2012)
Z.W. Zhu, L. Gu, G.Q. Xie, W. Zhang, A. Inoue, H.F. Zhang, Z.Q. Hu, Relation between icosahedral short-range ordering and plastic deformation in Zr-Nb-Cu-Ni-Al bulk metallic glasses. Acta Mater. 559, 2814–2822 (2011)
Q. Wang, C.T. Lin, Y. Yang, Y.D. Dong, Phys. Lett. 106 (2011) 215505
F.L. Liu, Y.J. Guo, J.H. Yan, G.N. Tang, Formation mechanism of compressibility related to shear band of bulk metallic glass. Mater. Herald B. 28, 117–121 (2014)
D. Ma, A.D. Stoica, X.L. Wang, Power-law scaling and fractal nature of medium-range order in metallic glasses. Nat. Mater. 8, 30–34 (2009)
C.T. Liu, L. Heatherly, D.S. Easton, Test environments and mechanical properties of Zr-base bulk amorphous alloys. Metall. Mater. Trans. A 29, 1811–1820 (1998)
W.J. Wright, R. Saha, W.D. Nix, Deformation mechanisms of the Zr40Ti14Ni10Cu12Be24 bulk metallic glass. Mater. Trans. 42, 642–649 (2001)
W.H. Wang, C. Dong, C.H. Shek, Bulk metallic glasses. Mater. Sci. Eng. R 44, 45–89 (2004)
W.L. Johnson, Bulk glass-forming metallic alloys: science and technology. MRS Bull. 24, 42–56 (1999)
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant No. 51661016, 51571105, 51551101, 51661017); Wenzhou city public welfare science and technology project (2011CB612203); The National Basic Research Program of China (973 Program) (Grant No. 2011CB612203).
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Li, C., Yin, J., Ding, J., Zhu, F., Zhao, Y., Kou, S. (2018). Effect of Zr and Cu on Mechanical Properties, Glass Forming Ability and Thermal Stability of Zr63.68Cu16.2 Ni10.12 Al10 Amorphous Alloy. In: Han, Y. (eds) Advanced Functional Materials. CMC 2017. Springer, Singapore. https://doi.org/10.1007/978-981-13-0110-0_26
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DOI: https://doi.org/10.1007/978-981-13-0110-0_26
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