Abstract
In this study, thermally pre-reduced graphene oxide films were prepared, with respect to different microwave irradiation time and the electrical properties of those films were investigated. The interaction of GO films under intense microwave irradiation was also examined. It was found that the response of GO films to microwave irradiation was not obvious, while significant reduction could be observed for thermally pre-reduced GO films during microwave treatment. The reduction by microwave irradiation of pre-reduced GO films was confirmed through X-ray photoelectron spectroscopy (XPS) and raman spectroscopy. Compared with that of GO films, electrical conductivity of thermally pre-reduced GO films, under microwave irradiation for 5 min, was increased by three orders of magnitude approximately. The results indicated that pre-reduced GO films were effective microwave absorbent, with conversing microwave energy to heat, thus contributing to the restoration of graphite lattice and enhancing connectivity of existing graphite domains.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
S. Yongchao, E.T. Samulski, Synthesis of water soluble graphene. Nano Lett. 8(6), 1679–1682 (2008)
P.W. Liu, Z. Jin, G. Kstsukis, L.W. Drahushuk, M.S. Strano, Layered and scrolled nanocomposites with aligned semi-infinite graphene inclusions at the platelet limit. Science 353(6297), 364–368 (2016)
H. Chen, F. Guo, Y. Liu, T. Huang, B. Zheng, N. Ananth, et al., A defect-free principle for advanced graphene cathode of aluminum-ion battery. Adv. Mater. 29 (2017)
Z. Liu, Z. Li, Z. Xu, Z. Xia, X. Hu, L. Kou et al., Wet-Spun Continuous Graphene Films. Chem. Mater. 26(23), 6786–6795 (2014)
D.A. Dikin, S. Stankovich, E.J. Zimney, R.D. Piner, G.H.B. Dommett, G. Evmenenko et al., Preparation and characterization of graphene oxide paper. Nature 448(7152), 457–460 (2007)
S. Pei, J. Zhao, J. Du, W. Ren, H.-M. Cheng, Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon 48(15), 4466–4474 (2010)
S. Obata, H. Tanaka, K. Saiki, Electrical and spectroscopic investigations on the reduction mechanism of graphene oxide. Carbon 55, 126–132 (2013)
D. Chen, L. Li, L. Guo, An environment-friendly preparation of reduced graphene oxide nanosheets via amino acid. Nanotechnology 22(32), 325601 (2011)
M. Zhang, L. Huang, J. Chen, C. Li, G. Shi, Ultratough, ultrastrong, and highly conductive graphene films with arbitrary sizes. Adv. Mater. 26(45), 7588–7592 (2014)
W. Chen, L. Yan, P.R. Bangal, Preparation of graphene by the rapid and mild thermal reduction of graphene oxide induced by microwaves. Carbon 48, 1146–1152 (2010)
A.M. Schwenke, S. Hoeppener, U.S. Schuber, Synthesis and modification of carbon nanomaterials utilizing microwave heating. Adv. Mater. 27, 4113–4141 (2015)
C. Wen, N. Zhao, D.W. Zhang et al., Efficient reduction and exfoliation of graphite oxide by sequential chemical reduction and microwave irradiation. Synth. Met. 194, 71–76 (2014)
Y. Zhu, S. Murali, M.D. Stoller et al., Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors. Carbon 48, 2106–2122 (2010)
M.A. Hassan, V. Abdelsayed, A.E.R.S. Khder et al., Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic media. J. Mater. Chem. 19, 3832–3837 (2009)
V. Damien, Y. Jieun, K. Jacob et al., High-quality graphene via microwave reduction of solution exfoliated graphene oxide. Science 353(6306), 1413–1416 (2016)
Funding
The present work is supported by the Research Project (No. JC 15-01-03) of National University of Defense Technology.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Lin, S., Yuan, S., Zhang, J., Jiang, D. (2018). Effects of Microwave Irradiation on Electricity of Graphene Oxide Films. In: Han, Y. (eds) Advanced Functional Materials. CMC 2017. Springer, Singapore. https://doi.org/10.1007/978-981-13-0110-0_10
Download citation
DOI: https://doi.org/10.1007/978-981-13-0110-0_10
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-0109-4
Online ISBN: 978-981-13-0110-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)