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Triboluminescence of Lanthanide Coordination Polymers

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Assembled Lanthanide Complexes with Advanced Photophysical Properties

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Abstract

Triboluminescence (TL) and photoluminescence (PL) of novel lanthanide (Ln(III)) coordination polymers [Ln(hfa)3(dpf)] n (dpf: 2,5-bis(diphenylphosphoryl)furan, Ln=Tb, Gd, Eu) are reported. The coordination polymers exhibited bright TL due to the face-to-face arrangement of substituents between single polymer chains. The observation of TL in a series of Eu(III) coordination polymers and a Gd(III) compound indicated that both hfa ligands and Ln(III) ions were excited under grinding. Significant PL/TL spectral differences in [Tb,Eu(hfa)3(dpf)] n due to distinct excitation processes upon grinding and UV irradiation were observed for the first time.

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Authors and Affiliations

  1. Hokkaido University, Sapporo, Hokkaido, Japan

    Yuichi Hirai

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  1. Yuichi Hirai
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Correspondence to Yuichi Hirai .

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Hirai, Y. (2018). Triboluminescence of Lanthanide Coordination Polymers. In: Assembled Lanthanide Complexes with Advanced Photophysical Properties. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-8932-9_6

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