Advertisement

Luminescent Lanthanide Coordination Glasses

  • Yuichi Hirai
Chapter
Part of the Springer Theses book series (Springer Theses)

Abstract

Construction of luminescent Eu(III) coordination glasses [Eu(hfa)3(o-dpeb)]2, [Eu(hfa)3(m-dpeb)]3, and [Eu(hfa)3(p-dpeb)] n (o-, m-, p-dpeb: 1,2-, 1,3-, 1,4-bis(diphenylphosphorylethynyl)benzene) are reported. The coordination structures and glass formability were dependent on the regiochemistry of substitution in regard to the internal phenylene core. Single-crystal X-ray analyses and DFT calculations revealed dimer, trimer, and polymer structures of Eu(III) coordination glasses. All of these compounds exhibited glass transition temperature in the range of 25–96 °C, and strong luminescence was also observed with intrinsic emission quantum yields above 70%.

Keywords

Luminescence Europium Glass transition Amorphous 

References

  1. 1.
    S.J. Wang, W.J. Oldham, R.A. Hudack, G.C. Bazan, J. Am. Chem. Soc. 122, 5695–5709 (2000)CrossRefGoogle Scholar
  2. 2.
    S.Y. Reece, J.A. Hamel, K. Sung, T.D. Jarvi, A.J. Esswein, J.J.H. Pijpers, D.G. Nocera, Sci. 334, 645–648 (2011)CrossRefGoogle Scholar
  3. 3.
    R.D.L. Smith, M.S. Prevot, R.D. Fagan, Z.P. Zhang, P.A. Sedach, M.K.J. Siu, S. Trudel, C.P. Berlinguette, Sci. 340, 60–63 (2013)CrossRefGoogle Scholar
  4. 4.
    V.L. Deringer, W. Zhang, M. Lumeij, S. Maintz, M. Wuttig, R. Mazzarello, R. Dronskowski, Angew. Chem. Int. Ed. 53, 10817–10820 (2014)CrossRefGoogle Scholar
  5. 5.
    Y. Shirota, J. Mater. Chem. 10, 1–25 (2000)CrossRefGoogle Scholar
  6. 6.
    Y. Shirota, J. Mater. Chem. 15, 75–93 (2005)CrossRefGoogle Scholar
  7. 7.
    A. Mishra, P. Bäuerle, Angew. Chem. Int. Ed. 51, 2020–2067 (2012)CrossRefGoogle Scholar
  8. 8.
    J.C.S. Costa, L.J. Santos, Phys. Chem. C 117, 10919–10928 (2013)CrossRefGoogle Scholar
  9. 9.
    H. Nakano, T. Tanino, T. Takahashi, H. Ando, Y. Shirota, J. Mater. Chem. 18, 242–246 (2008)CrossRefGoogle Scholar
  10. 10.
    H. Nakano, S. Seki, H. Kageyama, Phys. Chem. Chem. Phys. 12, 7772–7774 (2010)CrossRefGoogle Scholar
  11. 11.
    Z. Li, Q. Dong, Y. Li, B. Xu, M. Deng, J. Pei, J. Zhang, F. Chen, S. Wen, Y. Gao, W. Tian, J. Mater. Chem. 21, 2159–2168 (2011)CrossRefGoogle Scholar
  12. 12.
    M. Grucela-Zajac, K. Bijak, S. Kula, M. Filapek, M. Wiacek, H. Janeczek, L. Skorka, J. Gasiorowski, K. Hingerl, N.S. Sariciftci, N. Nosidlak, G. Lewinska, J. Sanetra, E. Schab-Balcerzak, J. Phys. Chem. C 118, 13070–13086 (2014)CrossRefGoogle Scholar
  13. 13.
    J.-C.G. Bünzli, Chem. Rev. 110, 2729–2755 (2010)CrossRefGoogle Scholar
  14. 14.
    S.V. Eliseeva, J.-C.G. Bünzli, Chem. Soc. Rev. 39, 189–227 (2010)CrossRefGoogle Scholar
  15. 15.
    P. Nockemann, E. Beurer, K. Driesen, R. Van Deun, K. Van Hecke, L. Van Meervelt, K. Binnemans, Chem. Commun. 34, 4354–4356 (2005)CrossRefGoogle Scholar
  16. 16.
    S. Petoud, G. Muller, E.G. Moore, J.D. Xu, J. Sokolnicki, J.P. Riehl, U.N. Le, S.M. Cohen, K.N. Raymond, J. Am. Chem. Soc. 129, 77–83 (2007)CrossRefGoogle Scholar
  17. 17.
    S.J. Butler, D. Parker, Chem. Soc. Rev. 42, 1652–1666 (2013)CrossRefGoogle Scholar
  18. 18.
    A.P. Bassett, S.W. Magennis, P.B. Glover, D.J. Lewis, N. Spencer, S. Parsons, R.M. Williams, L. De Cola, Z. Pikramenou, J. Am. Chem. Soc. 126, 9413–9424 (2004)CrossRefGoogle Scholar
  19. 19.
    L. Armelao, S. Quici, F. Barigelletti, G. Accorsi, G. Bottaro, M. Cavazzini, E. Tondello, Coord. Chem. Rev. 254, 487–505 (2010)CrossRefGoogle Scholar
  20. 20.
    M.R. Robinson, M.B. O’Regan, G.C. Bazan, Chem. Commun. 254, 1645–1646 (2000)CrossRefGoogle Scholar
  21. 21.
    Y. Hasegawa, K. Murakoshi, Y. Wada, S. Yanagida, J.H. Kim, N. Nakashima, T. Yamanaka, Chem. Phys. Lett. 248, 8–12 (1996)CrossRefGoogle Scholar
  22. 22.
    Y. Hasegawa, K. Sogabe, Y. Wada, T. Kitamura, N. Nakashima, S. Yanagida, Chem. Lett. 1, 35–36 (1999)CrossRefGoogle Scholar
  23. 23.
    H.F. Brito, O.M.L. Malta, M.C.F.C. Felinto, E.E.S. Teotonio, Chem. Met. Enolates, chapter 3, 131 (2009)Google Scholar
  24. 24.
    N.B.D. Lima, S.M.C. Gonçalves, S.A. Junior, A.M. Simas, Sci. Rep. 3, 1–8 (2013)CrossRefGoogle Scholar
  25. 25.
    S.M. Borisov, O.S. Wolfbeis, Anal. Chem. 78, 5094–5101 (2006)CrossRefGoogle Scholar
  26. 26.
    G.E. Khalil, K. Lau, G.D. Phelan, B. Carlson, M. Gouterman, J.B. Callis, L.R. Dalton, Rev. Sci. Instrum. 75, 192–206 (2004)CrossRefGoogle Scholar
  27. 27.
    S.V. Eliseeva, D.N. Pleshkov, K.A. Lyssenko, L.S. Lepnev, J.-C.G. Bünzli, N.P. Kuzmina, Inorg. Chem. 49, 9300–9311 (2010)CrossRefGoogle Scholar
  28. 28.
    K. Nakamura, Y. Hasegawa, H. Kawai, N. Yasuda, Y. Wada, S. Yanagida, J. Alloys. Compd. 408, 771–775 (2006)CrossRefGoogle Scholar
  29. 29.
    K. Miyata, T. Ohba, A. Kobayashi, M. Kato, T. Nakanishi, K. Fushimi, Y. Hasegawa, ChemPlusChem 77, 277–280 (2012)CrossRefGoogle Scholar
  30. 30.
    K. Miyata, Y. Konno, T. Nakanishi, A. Kobayashi, M. Kato, K. Fushimi, Y. Hasegawa, Angew. Chem. Int. Ed. 52, 6413–6416 (2013)CrossRefGoogle Scholar
  31. 31.
    I.V. Alabugin, S.V. Kovalenko, J. Am. Chem. Soc. 124, 9052–9053 (2002)CrossRefGoogle Scholar
  32. 32.
    P. Suresh, S. Srimurugan, B. Babu, H.N. Pati, Acta Chim. Slov. 55, 453–457 (2008)Google Scholar
  33. 33.
    J. Tirado-Rives, W.L. Jorgensen, J. Chem. Theory Comput. 4, 297–306 (2008)CrossRefGoogle Scholar
  34. 34.
    M. Dolg, H. Stoll, A. Savin, H. Preuss, Theor. Chim. Acta 75, 173–194 (1989)CrossRefGoogle Scholar
  35. 35.
    L. Maron, O. Einstein, J. Phys. Chem. A 104, 7140–7143 (2000)CrossRefGoogle Scholar
  36. 36.
    M.J. Frisch et al. Gaussian 09, Revision D.01. (Gaussian, Inc., Wallingford CT, 2009)Google Scholar
  37. 37.
    J. Ueda, S. Tanabe, J. Am. Ceram. Soc. 93, 3084–3087 (2010)CrossRefGoogle Scholar
  38. 38.
    E. Ueta, H. Nakano, Y. Shirota, Chem. Lett. 23, 2397–2400 (1994)CrossRefGoogle Scholar
  39. 39.
    M.D. Ediger, C.A. Angell, S.R. Nagel, J. Phys. Chem. 100, 13200–13212 (1996)CrossRefGoogle Scholar
  40. 40.
    M. Todoki, Sen’i Gakkaishi 65, 385–393 (2009)Google Scholar
  41. 41.
    K. Nakamura, Y. Hasegawa, Y. Wada, S. Yanagida, Chem. Phys. Lett. 398, 500–504 (2004)CrossRefGoogle Scholar

Copyright information

© Springer Nature Singapore Pte Ltd. 2018

Authors and Affiliations

  1. 1.Hokkaido UniversitySapporo, HokkaidoJapan

Personalised recommendations