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Luminescent Lanthanide Coordination Glasses

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Assembled Lanthanide Complexes with Advanced Photophysical Properties

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Abstract

Construction of luminescent Eu(III) coordination glasses [Eu(hfa)3(o-dpeb)]2, [Eu(hfa)3(m-dpeb)]3, and [Eu(hfa)3(p-dpeb)] n (o-, m-, p-dpeb: 1,2-, 1,3-, 1,4-bis(diphenylphosphorylethynyl)benzene) are reported. The coordination structures and glass formability were dependent on the regiochemistry of substitution in regard to the internal phenylene core. Single-crystal X-ray analyses and DFT calculations revealed dimer, trimer, and polymer structures of Eu(III) coordination glasses. All of these compounds exhibited glass transition temperature in the range of 25–96 °C, and strong luminescence was also observed with intrinsic emission quantum yields above 70%.

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Authors and Affiliations

  1. Hokkaido University, Sapporo, Hokkaido, Japan

    Yuichi Hirai

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  1. Yuichi Hirai
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Correspondence to Yuichi Hirai .

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Hirai, Y. (2018). Luminescent Lanthanide Coordination Glasses. In: Assembled Lanthanide Complexes with Advanced Photophysical Properties. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-8932-9_4

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