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Decomposition Behavior of Metal-Ion Exchanged Clays

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Fire Retardancy Behavior of Polymer/Clay Nanocomposites

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Abstract

This chapter deals with exploring the effect of different metal ions like Mg2+, Al3+, and Fe3+ present in/on MI-clays in altering the kinetics and/or decomposition mechanism of organic modifier, HDTMA-Br. The catalytic activity is seen to be a combined effect of Brønsted and Lewis acid characters associated with the metal ions. The effect varies significantly with the predominant cation in organically modified MI-clays (OMI-clays). Knowing the effect of each metal ion separately, the correlation between clay structural chemistry and organic decomposition onset is established.

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I.S. Zope, A. Dasari, G. Camino. Mater. Chem. Phys. 2015, 157, 69–79.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Nanyang Technological University, Singapore, Singapore

    Dr. Indraneel Suhas Zope

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  1. Dr. Indraneel Suhas Zope
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Zope, I.S. (2018). Decomposition Behavior of Metal-Ion Exchanged Clays. In: Fire Retardancy Behavior of Polymer/Clay Nanocomposites. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-8327-3_4

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