Abstract
Every year, a huge amount of waste materials containing toxic substances are produced throughout the world, which causes serious damage to the environment and poses threats to human health. Among available techniques of immobilization of toxic elements in harmful by-products is geopolymerization which has been considered as an effective approach to deal with many environmental issues. Apart from being utilised as alternatives for Portland cements in construction, geopolymer materials are also used as binders in waste solidification and stabilization systems . This study focuses on the potential application of geopolymeric systems in coping with hazardous wastes regarding the immobilization mechanism and factors influencing the immobilization efficiency, which provides a better understanding of the stabilization of pollutants through geopolymerization in order to stimulate further research on addressing the hazardous waste.
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Phair, J.W., van Deventer, J.S.J., Smith, J.D.: Effect of Al source and alkali activation on Pb and Cu immobilisation in fly-ash based geopolymers. Appl. Geochem. 19, 423–434 (2004). doi:10.1016/S0883-2927(03)00151-3
Nwaichi, E.O., Dhankher, O.P.: Heavy metals contaminated environments and the road map with phytoremediation. J. Environ. Prot. 7, 41–51 (2016). doi:10.4236/jep.2016.71004
Adaska, W.S., Tresouthick, S.W., West, P.B.: Solidification and stabilization of wastes using portland cement. Report Number: EB071.02 W, Portland Cement Association (1991)
Glasser, F.P.: Fundamental aspects of cement solidification and stabilisation. J. Hazard. Mater. 52, 151–170 (1997)
Davidovits, J.: Geopolymers-inorganic polymeric new materials. J. Therm. Anal. 37(8), 1633–1656 (1991)
Davidovits, J.: Properties of geopolymer cements. In: Proceedings of the First International Conference on Alkaline Cements and Concretes, pp. 131–49. Kiev State Technical University, Kiev, Ukraine (1994)
Davidovits, J.: Geopolymer chemistry and sustainable development. The Poly(sialate) terminology: a very useful and simple model for the promotion and understanding of green-chemistry. In: Davidovits, J. (ed.) Proceedings of the World Congress Geopolymer, Saint Quentin (2005)
Duxson, P., Fernández-Jiménez, A., Provis, J.L., et al.: Geopolymer technology: the current state of the art. J. Mater. Sci. 42, 2917 (2007b). doi:10.1007/s10853-006-0637-z
Duxson, P., Provis, J.L., Lukey, G.C., van Deventer, J.S.J.: The role of inorganic polymer technology in the development of green concrete. Cem. Concr. Res. 37(12), 1590–1597 (2007a)
Lloyd, N., Rangan, V.: Geopolymer concrete-sustainable cementless concrete. In: Tenth ACI International Conference on Recent Advances in Concrete Technology and Sustainability Issues, pp. 33–53, 12 October 2009
Neupane, K.: Fly ash and GGBFS based powder-activated geopolymer binders: a viable sustainable alternative of portland cement in concrete industry. Mech. Mater. 103, 110–122 (2016). doi:10.1016/j.mechmat.2016.09.012
Palomo, A., de la Fuente, J.I.L.: Alkali-activated cementitous materials: alternative matrices for the immobilisation of hazardous wastes- part I. Stabilisation of boron. Cem. Concr. Res. 33, 281–288 (2003)
Provis, J.L.: Immobilisation of toxic wastes in geopolymers. In: Provis, J.L., van Deventer, J.S.J. (eds.) Geopolymers: Structures, Processing, Properties and Industrial Applications, 1st edn. Woodhead, Cambridge (2009)
Glukhovsky, V.D.: Soil Silicates. Gosstroyizdat, Kiev (1959). p. 154
Fernández-Jiménez, A., Palomo, A., Sobrados, I., Sanz, J.: The role played by the reactive alumina content in the alkaline activation of fly ashes. Microporous Mesoporous Mater. 91, 111–119 (2006). doi:10.1016/j.micromeso.2005.11.015
Palomo, A., Krivenko, P., Garcia-Lodeiro, I., et al.: A review on alkaline activation: new analytical perspectives. Mater. Constr. 64(315), e022 (2014). doi:10.3989/mc.2014.00314
Malviya, R., Chaudhary, R.: Factors affecting hazardous waste solidification/stabilization: a review. J. Hazard. Mater. B137, 267–276 (2006). doi:10.1016/j.jhazmat.2006.01.065
EPA/600/R-10/170: Background information for the leaching environmental assessment framework (LEAF) test methods (2010)
Palacios, M., Palomo, A.: Alkali-activated fly ash matrices for lead immobilisation: a comparison of different leaching tests. Adv. Cem. Res. 16, 137–144 (2004). doi:10.1680/adcr.16.4.137.46661
Fernández Pereira, C., Luna, Y., Querol, X., Antenucci, D., Vale, J.: Waste stabilization/solidification of an electric arc furnace dust using fly ash-based geopolymers. Fuel 88, 1185–1193 (2009). doi:10.1016/j.fuel.2008.01.021
Donatello, S., Fernández-Jiménez, A., Palomo, A.: An assessment of Mercury immobilisation in alkali activated fly ash (AAFA) cements. J. Hazard. Mater. 213–214, 207–215 (2012). doi:10.1016/j.jhazmat.2012.01.081
Zheng, L., Wang, W., Shi, Y.: The effects of alkaline dosage and Si/Al ratio on the immobilization of heavy metals in municipal solid waste incineration fly ash-based geopolymer. Chemosphere 79, 665–671 (2010). doi:10.1016/j.chemosphere.2010.02.018
van Jaarsveld, J.G.J., van Deventer, J.S.J., Lorenzen, L.: The potential use of geopolymeric materials to immobilise toxic metals: part I. Theory and applications. Miner. Eng. 10, 659–669 (1997). doi:10.1016/S0892-6875(97)00046-0
van Jaarsveld, J.G.J., van Deventer, J.S.J., Lorenzen, L.: Factors affecting the immobilization of metals in geopolymerized fly ash. Metall. Mater. Trans. B 29, 283 (1998). doi:10.1007/s11663-998-0032-z
Qian, G., Sun, D.D., Tay, H.J.: Characterization of mercury- and zinc-doped alkali-activated slag matrix-part I. Mercury. Cem. Concr. Res. 33, 1251–1256 (2003a). doi:10.1016/S0008-8846(03)00045-0
Phair, J.W., van Deventer, J.S.J.: Effect of silicate activator pH on the leaching and material characteristics of waste-based inorganic polymers. Miner. Eng. 14(3), 289–304 (2001). doi:10.1016/S0892-6875(01)00002-4
Qian, G., Sun, D.D., Tay, H.J.: Characterization of mercury- and zinc-doped alkali-activated slag matrix-part II. Zinc. Cem. Concr. Res. 33, 1251–1256 (2003b). doi:10.1016/S0008-8846(03)00045-0
El-Eswed, B.I., Yousef, R.I., Alshaaer, M., Hamadneh, I., Al-Gharabli, S.I., Khalili, F.: Stabilization/solidification of heavy metals in kaolin/zeolite based geopolymers. Int. J. Miner. Process. 137, 34–42 (2015). doi:10.1016/j.minpro.2015.03.002
Conner, J.R.: Chemical fixation and solidification of hazardous wastes. Van Nostrand Reinhold (1990)
Davis, P.J., Deshpande, R., Smith, D.M., Brinker, C.J., Assink, R.A.: Pore structure evolution in silica gel during aging/drying- IV. Varying pore fluid pH. J. Non-Cryst. Solids 167, 295–306 (1994)
Cheng, T.W., Lee, M.L., Ko, M.S., Ueng, T.H., Yang, S.F.: The heavy metal adsorption characteristics on metakaolin-based geopolymer. Appl. Clay Sci. 56, 90–96 (2012). doi:10.1016/j.clay.2011.11.027
Nikolić, I., Đurović, D., Tadić, M., Blečić, D., Radmilović, V.: Immobilization of zinc from metallurgical waste and water solutions using geopolymerization technology. In: Proceedings of the 16th International Conference on Heavy Metals in the Environment, vol 1 (2013). doi:10.1051/e3sconf/20130141026
Deja, J.: Immobilization of Cr6+, Cd2+, Zn2+ and Pb2+ in alkali-activated slag binders. Cem. Concr. Res. 32, 1971–1979 (2002). doi:10.1016/S0008-8846(02)00904-3
Kriven, W.M., Bell, J.L., Gordon, M.: Microstructure and nanoporosity of as-set geopolymers. Ceram. Eng. Sci. Proc. 27(2), 491–503 (2008). doi:10.1002/9780470291313.ch47
Yunsheng, Z., Wei, S., Qianli, C., Lin, C.: Synthesis and heavy metal immobilization behaviors of slag based geopolymer. J. Hazard. Mater. 143, 206–213 (2007). doi:10.1016/j.jhazmat.2006.09.033
Xu, J.Z., Zhou, Y.L., Chang, Q., Qu, H.Q.: Study on the factors of affecting the immobilization of heavy metals in fly ash-based geopolymers. Mater. Lett. 60, 820–822 (2006). doi:10.1016/j.matlet.2005.10.019
Guo, B., Pan, D., Liu, B., Volinsky, A.A., Fincan, M., Du, J., Zhang, S.: Immobilization mechanism of Pb in fly ash-based geopolymer. Constr. Build. Mater. 134, 123–130 (2017). doi:10.1016/j.conbuildmat.2016.12.139
Zhang, J., Provis, J.L., Feng, D., van Deventer, J.S.J.: The role of sulfide in the immobilization of Cr(VI) in fly ash geopolymers. Cem. Concr. Res. 38, 681–688 (2008b). doi:10.1016/j.cemconres.2008.01.006
Chen, J., Wang, Y., Wang, H., Zhou, S., Wu, H., Lei, X.: Detoxification/immobilization of hexavalent chromium using metakaolin-based geopolymer coupled with ferrous chloride. J. Environ. Chem. Eng. 4, 2084–2089 (2016). doi:10.1016/j.jece.2016.03.038
Katz, S.A., Salem, H.: The Biological and Environmental Chemistry of Chromium. VCH Publications, New York (1994)
Palomo, A., Palacios, M.: Alkali-activated cementitious materials: alternative matrices for the immobilisation of hazardous wastes -part II. Stabilisation of chromium and lead. Cem. Concr. Res. 33, 289–295 (2003)
Zhang, J., Provis, J.L., Feng, D., van Deventer, J.S.J.: Geopolymers for immobilization of Cr6+, Cd2+, and Pb2+. J. Hazard. Mater. 157, 587–598 (2008a). doi:10.1016/j.jhazmat.2008.01.053
Eary, L.E., Ral, D.: Chromate removal from aqueous wastes by reduction with ferrous ion. Environ. Sci. Technol. 22(8), 972–977 (1988). doi:10.1021/es00173a018
Lan, Y., Deng, B., Kim, C., Thornton, E.C.: Influence of soil minerals on chromium (VI) reduction by sulfide under anoxic conditions. Geochem. Trans. 8, 4 (2007). doi:10.1186/1467-4866-1188-1184
Omotoso, O.E., Ivey, D.G., Mikula, R.: Quantitative X-ray diffraction analysis of chromium (III) doped tricalcium silicate pastes. Cem. Concr. Res. 26, 1369–1379 (1996). doi:10.1016/0008-8846(96)00118-4
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Vu, T.H., Tran, M.V. (2018). A Review on Immobilisation of Toxic Wastes Using Geopolymer Technique. In: Tran-Nguyen, HH., Wong, H., Ragueneau, F., Ha-Minh, C. (eds) Proceedings of the 4th Congrès International de Géotechnique - Ouvrages -Structures. CIGOS 2017. Lecture Notes in Civil Engineering , vol 8. Springer, Singapore. https://doi.org/10.1007/978-981-10-6713-6_29
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