Skip to main content

Part of the book series: Springer Theses ((Springer Theses))

  • 409 Accesses

Abstract

Chapters 3 through 5 examined the flow reactor pyrolysis and laminar premixed flames of cyclohexane, methylcyclohexane and ethylcyclohexane; pyrolysis and flame intermediates were identified and quantified.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Cool, T. A., Nakajima, K., Mostefaoui, T. A., Qi, F., McIlroy, A., Westmoreland, P. R., et al. (2003). Selective detection of isomers with photoionization mass spectrometry for studies of hydrocarbon flame chemistry. Journal of Chemical Physics, 119(16), 8356–8365.

    Article  Google Scholar 

  2. Cool, T. A., Wang, J., Nakajima, K., Taatjes, C. A., & McIlroy, A. (2005). Photoionization cross sections for reaction intermediates in hydrocarbon combustion. International Journal of Mass Spectrometry, 247(1–3), 18–27.

    Article  Google Scholar 

  3. Wang, J., Yang, B., Cool, T. A., Hansen, N., & Kasper, T. (2008). Near-threshold absolute photoionization cross-sections of some reaction intermediates in combustion. International Journal of Mass Spectrometry, 269(3), 210–220.

    Article  Google Scholar 

  4. Yang, B., Wang, J., Cool, T. A., Hansen, N., Skeen, S., & Osborn, D. L. (2012). Absolute photoionization cross-sections of some combustion intermediates. International Journal of Mass Spectrometry, 309, 118–128.

    Article  Google Scholar 

  5. Zhou, Z., Xie, M., Wang, Z., & Qi, F. (2009). Determination of absolute photoionization cross-sections of aromatics and aromatic derivatives. Rapid Communications in Mass Spectrometry, 23(24), 3994–4002.

    Article  Google Scholar 

  6. Zhou, Z., Zhang, L., Xie, M., Wang, Z., Chen, D., & Qi, F. (2010). Determination of absolute photoionization cross-sections of alkanes and cyclo-alkanes. Rapid Communications in Mass Spectrometry, 24(9), 1335–1342.

    Article  Google Scholar 

  7. Hansen, N., Klippenstein, S. J., Miller, J. A., Wang, J., Cool, T. A., Law, M. E., et al. (2006). Identification of C5Hx isomers in fuel-rich flames by photoionization mass spectrometry and electronic structure calculations. The Journal of Physical Chemistry A, 110(13), 4376–4388.

    Article  Google Scholar 

  8. Soorkia, S., Trevitt, A. J., Selby, T. M., Osborn, D. L., Taatjes, C. A., Wilson, K. R., et al. (2010). Reaction of the C2H radical with 1-butyne (C4H6): Low-temperature kinetics and isomer-specific product detection. The Journal of Physical Chemistry A, 114(9), 3340–3354.

    Article  Google Scholar 

  9. Zhang, F., Wang, Z., Wang, Z., Zhang, L., Li, Y., & Qi, F. (2013). Kinetics of decomposition and isomerization of methylcyclohexane: Starting point for kinetic modeling mono-alkylated cyclohexanes. Energy & Fuels, 27(3), 1679–1687.

    Article  Google Scholar 

  10. Linstrom, P. J., & Mallard, W. G. (2005). NIST chemistry webbook. Gaithersburg, MD: National Institute of Standard and Technology, number 69. http://webbook.nist.gov/.

  11. Kiefer, J. H., Gupte, K. S., Harding, L. B., & Klippenstein, S. J. (2009). Shock tube and theory investigation of cyclohexane and 1-hexene decomposition. Journal of Physical Chemistry A, 113(48), 13570–13583.

    Article  Google Scholar 

  12. Luo, Y. R. (2007). Comprehensive handbook of chemical bond energies. Boca Raton, FL: CRC Press.

    Google Scholar 

  13. Wang, Z., Cheng, Z., Yuan, W., Cai, J., Zhang, L., Zhang, F., et al. (2012). An experimental and kinetic modeling study of cyclohexane pyrolysis at low pressure. Combustion and Flame, 159(7), 2243–2253.

    Article  Google Scholar 

  14. Crossley, S. P., Alvarez, W. E., & Resasco, D. E. (2008). Novel micropyrolyis index (MPI) to estimate the sooting tendency of fuels. Energy & Fuels, 22(4), 2455–2464.

    Article  Google Scholar 

  15. Li, W., Law, M. E., Westmoreland, P. R., Kasper, T., Hansen, N., & Kohse-Höinghaus, K. (2011). Multiple benzene-formation paths in a fuel-rich cyclohexane flame. Combustion and Flame, 158(11), 2077–2089.

    Article  Google Scholar 

  16. Wu, F., Kelley, A. P., & Law, C. K. (2012). Laminar flame speeds of cyclohexane and mono-alkylated cyclohexanes at elevated pressures. Combustion and Flame, 159(4), 1417–1425.

    Article  Google Scholar 

  17. Sirjean, B., Dames, E., Sheen, D. A., You, X.-Q., Sung, C., Holley, A. T., et al. (2009). A high-temperature chemical kinetic model of n-alkane oxidation. JetSurF Version 1.0 (Sept 15).

    Google Scholar 

  18. Kelley, A. P., Smallbone, A. J., Zhu, D. L., & Law, C. K. (2011). Laminar flame speeds of C5 to C8 n-alkanes at elevated pressures: Experimental determination, fuel similarity, and stretch sensitivity. Proceedings of the Combustion Institute, 33(1), 963–970.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhandong Wang .

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer Nature Singapore Pte Ltd.

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Wang, Z. (2018). Combustion Kinetics of Cyclohexane and C1–C2 Mono-alkyl Cyclohexanes. In: Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono-alkylated Derivatives Combustion. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-5693-2_6

Download citation

  • DOI: https://doi.org/10.1007/978-981-10-5693-2_6

  • Published:

  • Publisher Name: Springer, Singapore

  • Print ISBN: 978-981-10-5692-5

  • Online ISBN: 978-981-10-5693-2

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics