Abstract
Carbon, one of the most versatile elements around, manifests itself in a wide variety of allotropic forms that exhibit a diverse range of properties. Amorphous carbons form a big class of carbon allotropes. As the name suggests, amorphous carbons contain a certain degree of disorder (non-crystallinity) in contrast to the crystalline structures of diamond and graphite. The sp3 content of amorphous carbon films is very important in achieving excellent properties such as high hardness and high density.
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References
J. Robertson, Diamond-like amorphous carbon. Mater. Sci. Eng. R-Rep. 37, 129 (2002)
M. Scarselli, P. Castrucci, M.D. Crescenzi, Electronic and optoelectronic nano-devices based on carbon nanotubes. J. Phys. Condens. Matter 24, 313202 (2012)
J. Robertson, Amorphous carbon. Adv. Phys. 35, 317 (1986)
D.G. McCulloch, D.R. McKenzie, C.M. Goringe, Ab initio simulations of the structure of amorphous carbon. Phys. Rev. B 61, 2349 (2000)
A.C. Ferrari, J. Robertson, Raman spectroscopy of amorphous, nanostructured, diamond-like carbon, and nanodiamond. Philos. Trans. R. Soc. Lond. Ser. A 362, 2477 (2004)
Y. Lifshitz, Diamond-like carbon—present status. Diam. Relat. Mater. 8, 1659 (1999)
D.R. McKenzie, Tetrahedral bonding in amorphous carbon. Rep. Prog. Phys. 59, 1611 (1996)
L. Holland, S.M. Ojha, Deposition of hard and insulating carbonaceous films on an r.f. target in a butane plasma. Thin Solid Films 38, L17 (1976)
B. Marchon, P.N. Vo, M.R. Khan, J.W. Ager, Structure and mechanical properties of hydrogenated carbon films prepared by magnetron sputtering [for magnetic discs]. IEEE Trans. Magn. 27, 5160 (1991)
M. Weiler, S. Sattel, T. Giessen, K. Jung, H. Ehrhardt, V.S. Veerasamy, J. Robertson, Preparation and properties of highly tetrahedral hydrogenated amorphous carbon. Phys. Rev. B 53, 1594 (1996)
C. Casiraghi, J. Robertson, A.C. Ferrari, Diamond-like carbon for data and beer storage. Mater. Today 10, 44 (2007)
R. Kalish, Y. Lifshitz, K. Nugent, S. Prawer, Thermal stability and relaxation in diamond-like-carbon. A Raman study of films with different sp3 fractions (ta-C to a-C). Appl. Phys. Lett. 74, 2936 (1999)
C. Donnet, A. Erdemir, Tribology of Diamond-like Carbon Films, 1st edn. (Springer, New York, NY, USA, 2008)
Y. Lifshitz, S. Kasi, J. Rabalais, W. Eckstein, Subplantation model for film growth from hyperthermal species. Phys. Rev. B: Condens. Matter 41, 10468 (1990)
J. Robertson, Deposition mechanisms for promoting sp3 bonding in diamond-like carbon. Diam. Relat. Mater. 2, 984 (1993)
S. Aisenberg, R. Chabot, Ion-beam deposition of thin films of diamondlike carbon. J. Appl. Phys. 42, 2953 (1971)
A. Libassi, A.C. Ferrari, V. Stolojan, B.K. Tanner, J. Robertson, L.M. Brown, Density and sp3 content in diamond-like carbon films by X-ray reflectivity and electron energy loss spectroscopy, in MRS Online Proceedings Library, vol. 593 (1999)
M. Chhowalla, J. Robertson, C.W. Chen, S.R.P. Silva, C.A. Davis, G.A.J. Amaratunga, W.I. Milne, Influence of ion energy and substrate temperature on the optical and electronic properties of tetrahedral amorphous carbon (ta-C) films. J. Appl. Phys. 81, 139 (1997)
P.J. Fallon, V.S. Veerasamy, C.A. Davis, J. Robertson, G.A.J. Amaratunga, W.I. Milne, J. Koskinen, Properties of filtered-ion-beam-deposited diamondlike carbon as a function of ion energy. Phys. Rev. B 48, 4777 (1993)
J. Zhu, J. Han, X. Han, H.I. Schlaberg, J. Wang, sp3-rich deposition conditions and growth mechanism of tetrahedral amorphous carbon films deposited using filtered arc. J. Appl. Phys. 104, 013512 (2008)
F.-X. Liu, Z.-L. Wang, Thickness dependence of the structure of diamond-like carbon films by Raman spectroscopy. Surf. Coat. Technol. 203, 1829 (2009)
M.G. Beghi, A.C. Ferrari, K.B.K. Teo, J. Robertson, C.E. Bottani, A. Libassi, B.K. Tanner, Bonding and mechanical properties of ultrathin diamond-like carbon films. Appl. Phys. Lett. 81, 3804 (2002)
C.A. Davis, G.A.J. Amaratunga, K.M. Knowles, Growth mechanism and cross-sectional structure of tetrahedral amorphous carbon thin films. Phys. Rev. Lett. 80, 3280 (1998)
A.C. Ferrari, A. Libassi, B.K. Tanner, V. Stolojan, J. Yuan, L.M. Brown, S.E. Rodil, B. Kleinsorge, J. Robertson, Density, sp3 fraction, and cross-sectional structure of amorphous carbon films determined by X-ray reflectivity and electron energy-loss spectroscopy. Phys. Rev. B 62, 11089 (2000)
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Yeo, R.J. (2017). Overview of Amorphous Carbon Films. In: Ultrathin Carbon-Based Overcoats for Extremely High Density Magnetic Recording. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-4882-1_2
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