To elucidate the structures and reactivity of NO molecules on Cu surfaces, the valence states, i.e., \(2\pi ^*\) orbitals, were measured at the single-molecule level. At low coverage, NO molecules are adsorbed on Cu(110), (001), and (111) surfaces at about 15 K, forming isolated monomers in upright configurations.
Fermi Level Valence State Point Group Hollow Site Strong Intermolecular Interaction
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