Abstract
A non-thermal plasma fluidized bed (PFB) was developed for remediating phenanthrene (PHE)-contaminated soil. After a 25-min treatment, 95% of the PHE was removed with an energy density of 5960 J/g soil, air flow rate of 20 L/min, and soil moisture of 10%. The effects of the solid bed location, energy density, the flow rate, and the carrier gas were explored. It was found that decreasing the distance between the solid bed and electrodes properly and increasing the input energy density were favorable for PHE degradation. There existed appropriate flow rate and soil moisture for a higher efficiency. By means of various methods, the roles of the active species on the degradation efficiency and the products formed during discharge were analyzed. Possible mechanism of the PHE degradation by the PFB was proposed. Furthermore, a brief comparison with other competitive processes was performed, indicating that the proposed PFB was a promising alternative process for remediating PHE-contaminated soil [1].
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References
Ma DY. Low temperature plasma fluidized bed for Polycyclic aromatic hydrocarbons (PAHs) contaminated soil treatment. Yat-sen University; 2014.
Alcantara MT, Gomez J, Pazos M, Sanroman MA. Electrokinetic remediation of PAH mixtures from kaolin. J Hazard Mater. 2010;179:1156–60.
Lorraine MM, Russell JG, Nicholas JWC, Evelyn M. Doyle Bacterial community dynamics during bioremediation of phenanthrene—and fluoranthene-amended soil. Int Biodeter Biodegr. 2009;63:52–6.
Ferrarese E, Andreottola G, Oprea IA. Remediation of PAH-contaminated sediments by chemical oxidation. J Hazard Mater. 2008;152:128–39.
Lau EV, Gan SY, Ng HK, Poh PE. Extraction agents for the removal of polycyclic aromatic hydrocarbons (PAHs) from soil in soil washing technologies. Environ Pollut. 2014;184:640–9.
Pope CJ, Peters WA, Howard JB. Thermodynamic driving forces for PAH isomerization and growth during thermal treatment of polluted soils. J Hazard Mater. 2000;79:189–208.
Jia HZ, Li L, Fan XY, Liu MD, Deng WY, Wang CY. Visible light photodegradation of phenanthrene catalyzed by Fe(III)–smectite: role of soil organic matter. J Hazard Mater. 2013;256:16–23.
Kim SS, Kim JH, Han SJ. Application of the electrokinetic-Fenton process for the remediation of kaolinite contaminated with phenanthrene. J Hazard Mater. 2005;118:121–31.
Wang TC, Lu N, Li J, Wu Y. Evaluation of the potential of pentachlorophenol degradation in soil by pulsed corona discharge plasma from soil characteristics. Environ Sci Technol. 2000;44:3105–10.
Wang TC, Lu N, Li J, Wu Y. Plasma–TiO2 catalytic method for high-efficiency remediation of p-Nitrophenol contaminated soil in pulsed discharge. Environ Sci Technol. 2001;45:9301–7.
Wang TC, Qu GZ, Li J, Liang DL. Evaluation and optimization of multi-channel pulsed discharge plasma system for soil remediation. Vacuum. 2014;103:72–7.
Wang TC, Qu GZ, Li J, Liang DL. Remediation of p-nitrophenol and pentachlorophenol mixtures contaminated soil using pulsed corona discharge plasma. Sep Purif Technol. 2014;122:17–23.
Urashima K, Chang JS. Removal of volatile organic compounds from air streams and industrial flue gases by non-thermal plasma technology. IEEE Trans Dielectr Electr Insul. 2000;7:602–14.
Du CM, Yan JH, Li XD, Cheron BG, You XF, Chi Y, Ni MJ, Cen KF. Simultaneous removal of polycyclic aromatic hydrocarbons and soot particles from flue gas by gliding arc discharge treatment. Plasma Chem Plasma P. 2006;26:517–525.
Burlica R, Kirkpatrick MJ, Locke BR. Formation of reactive species in gliding arc discharges with liquid water. J Electrostat. 2006;64:35–43.
Kim SC, Chun YN. Experimental study on partial oxidation of methane to produce hydrogen using low-temperature plasma in AC glidarc discharge. Int J Energy Res. 2008;32:1185–93.
Ren Y, Li XD, Yu L, Cheng K, Yan JH, Du CM. Degradation of PCDD/Fs in fly ash by vortex-shaped gliding arc plasma. Plasma Chem Plasma P. 2013;33:293–305.
Chen GL, Chen SH, Zhou MY, Feng WR, Gu WC, Yang SZ. Application of a novel atmospheric pressure plasma fluidized bed in the powder surface modification. J Phys D Appl Phys. 2006;39:5211–5.
Schmidt–Sza owski K, Krawczyk K, Młotek M. Catalytic effects of metals on the conversion of methane in gliding discharges. Plasma Process Polym. 2007;4:728–736.
Lee H, Sekiguchi H. Plasma-catalytic hybrid system using spouted bed with a gliding arc discharge: CH4 reforming as a model reaction. J Phys D Appl Phys. 2011;44:274008–8012.
Soil environmental quality standards of China. GB 15618-2008.
Du CM, Shi TH, Sun YW, Zhuang XF. Decolorization of acid orange 7 solution by gas-liquid gliding arc discharge plasma. J Hazard Mater. 2008;154:1192–7.
Burlica R, Kirkpatrick MJ, Locke BR. Formation of reactive species in gliding arc discharges with liquid water. J Electrostat. 2006;64:35–43.
Ke Z, Huang Q, Zhang H, Yu ZL. Reduction and removal of aqueous Cr(VI) by glow discharge plasma at the gas-solution interface. Environ Sci Technol. 2011;45:7841–7.
Yu L, Tu X, Li XD, Wang Y, Chi Y, Yan JH. Destruction of acenaphthene, fluorene, anthracene and pyrene by a dc gliding arc plasma reactor. J Hazard Mater. 2010;180:449–55.
Zhang YL, Wong JWC, Liu PH, Yuan M. Heterogeneous photocatalytic degradation of phenanthrene in surfactant solution containing TiO2 particles. J Hazard Mater. 2011;191:136–43.
Kou JH, Li ZS, Guo Y, Gao J, Yang M, Zou ZG. Photocatalytic degradation of polycyclic aromatic hydrocarbons in GaN:ZnO solid solution-assisted process: Direct hole oxidation mechanism. J Mol Catal a-Chem. 2010;325:48–54.
Yin MC, Li ZS, Kou JH, Zou ZG. Mechanism investigation of visible light-Induced degradation in a heterogeneous TiO2/Eosin Y/Rhodamine B system. Environ Sci Technol. 2009;43:8361–6.
Song WK, Li JB, Zhang W, Hu X, Ling W. An experimental study on the remediation od phenanthraene in soil uing ultrasound and soil washing. Environ Earth Sci. 2012;66:1487–96.
O’Mahonya MM, Barnesb JD, Singleton I. The use of ozone in the remediation of polycyclic aromatic hydrocarbon contaminated soil. Chemosphere. 2005;63:307–14.
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© 2017 Zhejiang University Press, Hangzhou and Springer Natue Singapore Pte Ltd.
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Du, C., Yan, J. (2017). Remediation of Phenanthrene-Contaminated Soil Using Non-thermal Plasma Fluidized Bed. In: Plasma Remediation Technology for Environmental Protection. Advanced Topics in Science and Technology in China. Springer, Singapore. https://doi.org/10.1007/978-981-10-3656-9_2
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DOI: https://doi.org/10.1007/978-981-10-3656-9_2
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