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Introduction

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Part of the book series: Springer Theses ((Springer Theses))

Abstract

In this chapter, we introduce basic knowledges for understanding this book. We start with general introduction to electro-osmosis of polymer solutions. Especially, experimental observations are thoroughly explained with referring previous works. We explain a physical aspect of aqueous electrolyte solutions, for example, why electrolyte is generally soluble to water. After that, we focus on the interfacial properties of electrolyte solutions. Electric double layer and electrokinetics are the most important concepts in this book. We explain surface capacitance, electro-osmosis, and surface conductivity in continuum description. In addition to these basic things, we introduce Stern layer which is still issue in the latest research. Finally we summarize the basis of polymer physics which is necessary for the following chapters.

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References

  1. S.S. Dukhin, B.V. Derjaguin, Surafce and Colloid Science, vol. 7, ed. by E. Matijrvic (Wiley, New York, 1974)

    Google Scholar 

  2. W.B. Russel, D.A. Saville, W.R. Schowalter, Colloidal Dispersions (Cambridge University Press, Cambridge, 1989)

    Book  MATH  Google Scholar 

  3. J. Lyklema, Fundamentals of Interface and Colloid Science, vol. 3 (Academic Press, London, 1995)

    Google Scholar 

  4. R.J. Hunter, Fundations of Colloid Science, 2nd edn. (Oxford University Press, New York, 2001)

    Google Scholar 

  5. T.M. Squires, S.R. Quake, Rev. Mod. Phys. 77, 977–1026 (2005)

    Article  ADS  Google Scholar 

  6. X. Wang, C. Cheng, S. Wang, S. Liu, Microfluid. Nanofluid. 6, 145–162 (2009)

    Article  Google Scholar 

  7. F.H.J. van der Heyden, D.J. Bonthuis, D. Stein, C. Meyer, C. Dekker, Nano Lett. 6, 2232–2237 (2006)

    Article  ADS  Google Scholar 

  8. A. Siria, P. Pomcharal, A.-L. Biance, R. Fulcrand, X. Blase, S. T. Purcell, L. Bocquet, Nature 494, 455–458 (2013). Supplementary information

    Google Scholar 

  9. Y. Uematsu, T. Araki, J. Chem. Phys. 139, 094901 (2013)

    Article  ADS  Google Scholar 

  10. D.J. Bonthuis, R.R. Netz, Langmuir 28, 16049–16059 (2012)

    Article  Google Scholar 

  11. C. Zhao, C. Yang, Electrophoresis 31, 973–979 (2010)

    Article  Google Scholar 

  12. C. Zhao, C. Yang, Biomicrofulids 5, 014110 (2010)

    Article  Google Scholar 

  13. C. Zhao, C. Yang, J. Non-Newton. Fluid Mech. 166, 1076–1079 (2011)

    Article  Google Scholar 

  14. C. Zhao, C. Yang, Adv. Colloid Interface Sci. 201–202, 94–108 (2013)

    Article  Google Scholar 

  15. J. Znaleziona, J. Peter, R. Knob, V. Maier, J. Ševčík, Chromatographia 67, 5–12 (2008)

    Article  Google Scholar 

  16. H. Ohshima, J. Colloid Interface Sci. 163, 474–483 (1994)

    Article  Google Scholar 

  17. H. Ohshima, Adv. Colloid Interface Sci. 62, 189–235 (1995)

    Article  Google Scholar 

  18. J.L. Harden, D. Long, A. Ajdari, Langmuir 17, 705–715 (2001)

    Article  Google Scholar 

  19. O.A. Hickey, C. Holm, J.L. Harden, G.W. Slater, Macromolecules 44, 9455–9463 (2011)

    Article  ADS  Google Scholar 

  20. S. Raafatnia, O.A. Hickey, C. Holm, Phys. Rev. Lett. 113, 238301 (2014)

    Article  ADS  Google Scholar 

  21. S. Raafatnia, O.A. Hickey, C. Holm, Macromolecules 48, 775–787 (2015)

    Article  ADS  Google Scholar 

  22. O.A. Hickey, J.L. Harden, G.W. Slater, Phys. Rev. Lett. 102, 108304 (2009)

    Article  ADS  Google Scholar 

  23. X. Liu, D. Erickson, D. Li, U.J. Krull, Anal. Chim. Acta 507, 55–62 (2004)

    Article  Google Scholar 

  24. G. Danger, M. Ramonda, H. Cottet, Electrophoresis 28, 925–931 (2007)

    Article  Google Scholar 

  25. L. Feng, Y. Adachi, A. Kobayashi, Colloids Surf. A 440, 155–160 (2014)

    Article  Google Scholar 

  26. U.M.B. Marconi, M. Monteferrante, S. Melchionna, Phys. Chem. Chem. Phys. 16, 25473–25482 (2014)

    Google Scholar 

  27. F.-M. Chang, H.-K. Tsao, App. Phys. Lett. 90, 194105 (2007)

    Article  ADS  Google Scholar 

  28. C.L.A. Berli, M.L. Olivares, J. Colloid Interface Sci. 320, 582–589 (2008)

    Article  Google Scholar 

  29. M.L. Olivares, L. Vera-Candioti, C.L.A. Berli, Electrophoresis 30, 921–928 (2009)

    Article  Google Scholar 

  30. C.L.A. Berli, Electrophoresis 34, 622–630 (2013)

    Article  Google Scholar 

  31. M.S. Bello, P. de Besi, R. Rezzonico, P.G. Righetti, E. Casiraghi, Electrophoresis 15, 623–626 (1994)

    Article  Google Scholar 

  32. R.M. Jendrejack, D.C. Schwartz, J.J. de Pablo, M.D. Graham, J. Chem. Phys. 120, 2513 (2004)

    Article  ADS  Google Scholar 

  33. H. Ma, M.D. Graham, Phys. Fluids 17, 083103 (2005)

    Article  ADS  Google Scholar 

  34. J.P. Hernández-Ortiz, H. Ma, J.J. de Pablo, M.D. Graham, Phys. Fluids 18, 123101 (2006)

    Article  ADS  Google Scholar 

  35. J.N. Israelachvili, Intermolecular and Surface Forces, 3rd edn. (Academic Press, Waltham, 2011)

    Google Scholar 

  36. Kaye and Laby Online, http://www.kayelaby.npl.co.uk/

  37. http://www.chemister.ru/Database/search-en.php

  38. H. Ohtaki, Solution Chemisty (Shokabo, Tokyo, 1985)

    Google Scholar 

  39. H.S. Frank, W.-Y. Wen, Disc. Faraday Soc. 24, 133–140 (1957)

    Article  Google Scholar 

  40. O.Y. Samoilov, Dsic. Faraday Soc. 24, 141–146 (1957)

    Article  Google Scholar 

  41. Y. Marcus, Chem. Rev. 88, 1475–1498 (1988)

    Article  Google Scholar 

  42. D.C. Grahame, Chem. Rev. 41, 441–501 (1947)

    Article  Google Scholar 

  43. M. Doi, Soft Matter Physics (Oxford University Press, Oxford, 2013)

    Book  MATH  Google Scholar 

  44. S. Kim, S.J. Karrila, Microhydrodynamics (Dover, Mineola, 2005)

    Google Scholar 

  45. D. Burgreen, F.R. Nakache, J. Phys. Chem. 68, 1084–1091 (1964)

    Article  Google Scholar 

  46. B.S. Levine, J.R. Marriott, K. Robinson, J. Chem. Soc. Faraday Trans. II(71), 1–11 (1974)

    Google Scholar 

  47. C.L. Rice, R. Whitehead, J. Phys. Chem. 69, 4017–4024 (1965)

    Article  Google Scholar 

  48. R.W. O’Brien, L.R. White, J. Chem. Soc. Faraday Trans. II(74), 1607–1626 (1978)

    Article  Google Scholar 

  49. M.S. Kilic, M.Z. Bazant, A. Ajdari, Phys. Rev. E 75, 021502 (2007)

    Article  ADS  Google Scholar 

  50. Y. Nakayama, D. Andelman, J. Chem. Phys. 142, 044706 (2015)

    Article  ADS  Google Scholar 

  51. J. Lyklema, Colloid Surf. A 92, 41–49 (1994)

    Article  Google Scholar 

  52. J. Lyklema, J. Colloid Int. Sci. 58, 242–250 (1977)

    Article  Google Scholar 

  53. D.J. Bonthuis, S. Gekle, R.R. Netz, Phys. Rev. Lett. 107, 166102 (2011)

    Article  ADS  Google Scholar 

  54. D.J. Bonthuis, R.R. Netz, J. Phys. Chem. B 117, 11397–11413 (2013)

    Article  Google Scholar 

  55. P.J. Flory, Principles of Polymer Chemistry (Cornell University Press, Ithaca, 1953)

    Google Scholar 

  56. M. Doi, S.F. Edwards, The Theory of Polymer Dynamics (Oxford University Press, New York, 1986)

    Google Scholar 

  57. K. Devanand, J.C. Selser, Macromolecules 24, 5943–5947 (1991)

    Article  ADS  Google Scholar 

  58. A.R. Shultz, P.J. Flory, J. Am. Chem. Soc. 74, 4760–4767 (1952)

    Article  Google Scholar 

  59. G.N. Malcolm, J.S. Rowlinson, Trans. Faraday Soc. 53, 921–931 (1957)

    Article  Google Scholar 

  60. P.G. de Gennes, Scaling Concepts in Polymer Physics (Cornell University Press, Ithaca, 1979)

    Google Scholar 

  61. R.R. Netz, D. Andelman, Phys. Rep. 380, 1–95 (2003)

    Article  ADS  Google Scholar 

  62. J.F. Joanny, L. Leibler, P.G. de Gennes, J. Polym. Sci. Poym. Phys. Ed. 17, 1073–1084 (1979)

    Article  ADS  Google Scholar 

  63. P.G. de Gennes, Macromolecules 14, 1637–1644 (1981)

    Article  ADS  Google Scholar 

  64. P.G. de Gennes, Macromolecules 15, 492–500 (1982)

    Article  ADS  Google Scholar 

  65. Masami Kawaguchi, Akira Takahashi, Adv. Colloid Interface Sci. 37, 219–317 (1992)

    Article  Google Scholar 

  66. F. Oosawa, Polyelectrolytes (Marcel Dekker, New York, 1971)

    Google Scholar 

  67. J.F. Joanny, L. Leibler, J. Phys. (France) 51, 545–557 (1990)

    Article  Google Scholar 

  68. J.L. Barrat, J.F. Joanny, Adv. Chem. Phys. XCIV, 1–66 (1996)

    Google Scholar 

  69. A.V. Dobrynin, M. Rubinstein, Prog. Polym. Sci. 30, 1049–1118 (2005)

    Article  Google Scholar 

  70. R.R. Netz, H. Orland, Eur. Phys. J. B 8, 81–98 (1999)

    Article  ADS  Google Scholar 

  71. T. Odijk, Polymer 19, 989–990 (1978)

    Article  Google Scholar 

  72. J. Skolnick, M. Fixman, Macromolecules 10, 944–948 (1977)

    Article  ADS  Google Scholar 

  73. A.R. Khokhlov, K.A. Khachaturian, Polymer 23, 1742–1750 (1982)

    Article  Google Scholar 

  74. A.V. Dobrynin, R.H. Colby, M. Rubinstein, Macromolecules 28, 1859–1871 (1995)

    Article  ADS  Google Scholar 

  75. I. Borukhov, D. Andelman, H. Orland, Eurphys. Lett. 32, 499–504 (1995)

    Article  ADS  Google Scholar 

  76. X. Châtellier, J.F. Joanny, J. Phys. II France 6, 1669–1686 (1996)

    Article  Google Scholar 

  77. I. Borukhov, D. Andelman, H. Orland, Macromolecules 31, 1665–1671 (1998)

    Article  ADS  Google Scholar 

  78. J.F. Joanny, Eur. Phys. J. B 9, 117–122 (1999)

    Article  ADS  Google Scholar 

  79. A. Shafir, D. Andelman, R.R. Netz, J. Chem. Phys. 119, 2355–2362 (2003)

    Article  ADS  Google Scholar 

  80. A. Shafir, D. Andelman, Phys. Rev. E 70, 061804 (2004)

    Article  ADS  Google Scholar 

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Correspondence to Yuki Uematsu .

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Uematsu, Y. (2017). Introduction. In: Electro-Osmosis of Polymer Solutions. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-3424-4_1

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