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Transition Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplings

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New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation

Part of the book series: Springer Theses ((Springer Theses))

Abstract

Transition metal-catalyzed decarboxylative cross-coupling reactions have recently emerged as a new and important category of organic transformations that find versatile applications in the construction of carbon–carbon and carbon–heteroatom bonds. The use of relatively cheap and stable carboxylic acids to replace organometallic reagents enables the decarboxylative cross-coupling reactions to proceed with good selectivities and functional group tolerance. In the present review, we summarize the various types of decarboxylative cross-coupling reactions catalyzed by different transition metal complexes. The scope and applications of these reactions are described. The challenges and opportunities in the field are discussed.

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  1. Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, China

    Rui Shang

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Shang, R. (2017). Transition Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplings. In: New Carbon–Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C–H Activation. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-3193-9_1

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