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Abstract

The synthesis and isolation of stable molecular compounds bearing metal–metal bonds involving group 12 metals (Zn, Cd, Hg) has proven a significant synthetic challenge. For many years, the only bonding interactions between two group 12 metals existed in mercury salt-like compounds, which possess a [Hg2]2+ ion.

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Hicks, J. (2017). Preparation of Low Oxidation State Group 12 Metal Complexes Stabilised by Bulky Amide Ligands. In: Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-2905-9_4

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