Abstract
This chapter deals with the synthesis and ab initio structure determination of a novel lithium containing Metal Organophosphate Open Framework (MOPOF) material, [Li2(VO)2(HPO4)2(C2O4)]·6H2O. It was synthesized by hydrothermal method at 120 °C and the crystal structure was solved and refined from its powder X-ray diffraction data. The anhydrous phase, [Li2(VO)2(HPO4)2(C2O4)] obtained by dehydration of the hydrated phase at 200 °C was studied as a novel cathode material for Lithium ion batteries. The presence of extractable Li+ ions in the inter-layer space together with the feasibility of V4+/V5+ redox couple and a good theoretical capacity of 125 mAh g−1 make this compound suitable as a cathode material. Electrochemical properties of the material was investigated using cyclic voltammetry, galvanostatic charge-discharge cycling, electrochemical impedance spectroscopy (EIS) and ex situ XRD studies. The material exhibits reversible lithium insertion at ~4 V with a reversible capacity of 80 mAh g−1 at 0.1 C current rate.
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Hameed, A.S. (2016). Synthesis and Electrochemical Studies of a Novel MOPOF Cathode Material, [Li2(VO)2(C2O4)(HPO4)2]. In: Phosphate Based Cathodes and Reduced Graphene Oxide Composite Anodes for Energy Storage Applications. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-2302-6_3
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DOI: https://doi.org/10.1007/978-981-10-2302-6_3
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