Skip to main content

Cationic Dyes Sequestration from Aqueous Phase Using Biosurfactant Based Reverse Micelles

  • Conference paper
  • First Online:
Recent Advances in Chemical Engineering

Abstract

Several conventional methods are employed to remove cationic dyes from waste water. A novel technique based on liquid/liquid extraction using reverse micelles is proposed whereby recovery of solvent and reuse of dye is possible. Single component batch experimental studies were carried out using two dyes, namely Basic red 9 (BR9) and basic violet 3 (BV3). Glycolipids produced naturally using Pseudozyma antarctica from soybean oil medium were used as surfactant. Extraction efficiency of single component system of each dye was investigated by using amyl alcohol as solvent and sulphuric acid as carrier. The process parameters such as dye concentration, sulphuric acid concentration and surfactant concentration on the extraction efficiency were optimized using Box-Behnken design. The optimum conditions were calculated by using Derringer’s desirably.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Adamczak, M., Bednarski, W.: Influence of medium composition and aeration on the synthesis of biosurfactants produced by Candida Antarctica. Biotechnol. Lett. 22, 313–316 (2000)

    Article  CAS  Google Scholar 

  • Desai, J.D., Banat, I.M.: Microbial production of surfactants and their commercial potential. Microbiol. Mol. Biol. Rev. 61, 47–64 (1997)

    Google Scholar 

  • Hasmann, F.A., Gurpilhares, D.B., Roberto, I.C., Pessoa Jr., A.: Response surface methodology for the evaluation of glucose-6-phosphate dehydrogenase enrichment process by soybean lecithin reversed micelles. J. Chromatogr. B 847, 262–266 (2007)

    Article  CAS  Google Scholar 

  • Jarudilokkul, S., Poppenborg, L.H., Valetti, F., Gilardi, G., Stuckey, D.C.: Separation and purification of periplasmic cytochrome c553 using reversed micelles. Biotechnol. Tech. 13, 159–163 (1999)

    Article  CAS  Google Scholar 

  • Maran, J.P.: Statistical optimization of aqueous extraction of pectin from waste durian rinds. Int. J. Biol. Macromol. 73, 92–98 (2015)

    Article  CAS  Google Scholar 

  • Montgomery, D.C.: Design and analysis of experiments, 5th edn. Wiley, New York (2001)

    Google Scholar 

  • Sivarajasekar, N., Baskar, R.: Adsorption of basic magenta II onto H2SO4 activated immature Gossypium hirsutum seeds: kinetics, isotherms, mass transfer, thermodynamics and process design. Arab. J. Chem. accepted manuscript, (2014a). doi:10.1016/j.arabjc.2014.10.040

  • Sivarajasekar, N., Baskar, R.: Adsorption of basic red 9 on activated waste Gossypium hirsutum seeds: process modeling, analysis and optimization using statistical design. J. Ind. Eng. Chem. 20, 2699–2709 (2014b)

    Google Scholar 

  • Sivarajasekar, N., Baskar, R.: Adsorption of basic red 9 onto activated carbon derived from immature cotton seeds: isotherm studies and error analysis. Desalin Water Treat 52, 7743–7765 (2014c)

    Google Scholar 

  • Sivarajasekar, N., Baskar, R.: Biosorption of basic violet 10 onto activated Gossypium hirsutum seeds: Batch and fixed-bed column studies. Chinese J. Chem. Eng. 23, 1610–1619 (2015a)

    Article  CAS  Google Scholar 

  • Sivarajasekar, N., Baskar, R.: Agriculture waste biomass valorisation for cationic dyes sequestration: a concise review. J. Chem. Pharm. Res. 7(9), 737–748 (2015b)

    CAS  Google Scholar 

  • Sivarajasekar, N., Baskar, R., Ragu, T., Sarika.K., Preethi. N., Rathika. T.: Appl. Water Sci. accepted manuscript, (2016). doi:10.1007/s13201-016-0379-2

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. Sivarajasekar .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer Science+Business Media Singapore

About this paper

Cite this paper

Sivarajasekar, N., Ramasubbu, S., Prakash Maran, J., Priya, B. (2016). Cationic Dyes Sequestration from Aqueous Phase Using Biosurfactant Based Reverse Micelles. In: Regupathi, I., Shetty K, V., Thanabalan, M. (eds) Recent Advances in Chemical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-10-1633-2_8

Download citation

Publish with us

Policies and ethics