Abstract
The selective hydrogenation of alkynes and dienes is an important reaction in chemical industry. They are widely applied in the purification of olefin streams to remove alkynes/dienes, the gasoline refinery process, and some of the fine chemical processes. The selective hydrogenation of acetylene also provides a new route for the production of ethylene from natural gas or coal.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Yan K (1999) Progress in catalyst development for the selective hydrogenation of C2–C4. Mod Chem Ind 03:13–15
Gao H (1990) Removal of alkynes and dienes from 1-butene stream by selective hydrogenation. Qilu Petrochem Tech 02:40–45
Gao H, Gao B, Zhang J et al (1999) Selective hydrogenation of C3 cracking stream by catalytic distillation. Qilu Petrochem Tech 04:241–244
Liao L, Cheng J, Wang Z et al (2003) Catalytic distillation application in the selective hydrogenation of C3 stream. Chem Ind Eng 02:18–20
Dai W, Zhu J, Wan W (2000) Progress in the selective hydrogenation of C2 stream. Petrochem Tech 07:535–540
Gao B, Zhang J, Wang Y et al (2001) Application and development of selective hydrogenation. Qilu Petrochem Tech 04:269–272
Wang J, Liu Z, Zhao D (2008) Progress in hysomer technology for the utilization of C4 species. Petrochem Tech 01:100–105
Li Y, Fan Y (2003) Study on the selective hydrogenation of dienes and alkynes. J Sanxia Univ (Nat Sci) 04:381–384
Mao X, Zou X (1986) The formation of copper acetylide and its explosive properties. Fire Sci Tech 04:21–23
Zhang Q, Liu X, Zhu Q (1998) Current development in the selective hydrogenation of alkynes and dienes. Petrochem Tech 01:55–60
Hong D (2014) Review and outlook in petrochemical industry (China 2013). Chem Ind Eng Prog 07:1633–1658
Yang C (2013) The development of coal chemical industry is beneficial to reduce the external dependence of oil in China. Sino-Glob Energ 11:1–6
Li J, Zheng M, Zhang G et al (2012) Outlook on conventional and unconventional natural gas resources in China. Acta Petrol Sin S1:89–98
Chen J, Cheng Y, Xiong X et al (2009) Progress in thermal plasma pyrolysis of coal to acetylene. Chem Ind Eng Prog 03:361–367
Zhu X (2010) Imbalance in the PVC supply and demand. China Petro Chem Ind 02:26
Liu Z (2008) Challenges and development of PVC in China. China Chlor-Alkali 03:1–6
Jiao Y (2013) Analysis and forecast of PE market. Guangzhou Chem Eng 10:58–59
Dong X (2014) Analysis of factors on the operation of C2 hydrogenation reactors in PetroChina Daqing. Jiangxi Petrochem Ind 02:85–88
Yang F, Zhang L, Xie C (2011) Optimization of C2 hydrogenation reactor. Contem Chem Ind 10:1007–1012
Ren Z, Yang Z, Zhang Q (2009) Progress in the Ni catalyst for the selective hydrogenation of gasoline. Petrchem Tech 01:98–102
Huang Y, Liu H (2008) Process study in the selective hydrogenation of 1-methyldicyclopentadiene. Tech Econ Petrochem 05:36–40
Wei H, Huang X, Lv H et al (2010) Operation parameters’ effect on the selective hydrogenation of isoprene in trickle bed reactor. Petrochem Tech 12:1349–1353
Tian B, Dai W, Yang Z et al (2009) Selective hydrogenation of C5 dienes. Chem Ind Eng Prog 11:1932–1935
Zhang G (2006) Selective hydrogenation of OCT-M gasoline: process application. Petrochem Ind Tech 02:17–20
Li Z (2001) Design of tricle bed reactor for the liquid phase hydrogenation of hydrocarbons. Chem Eng (China) (03):33–36+33
Zhao B, Liu X, Li H (1991) Catalyst and process for the liquid phase hydrogenation of C3 stream. Petrochem Tech 04:255–261
Zhang S, Dai W, Qi D et al (2008) Application of novel catalyst in the selective hydrogenation of C3 stream. Chem Ind Eng Prog 03:464–467
Zhao B, Liu X (1987) Catalyst study in the liquid phase hydrogenation of propyne and propadiene. Petrochem Tech 12:821–827
Borodzinski A, Bond GC (2006) Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts. Part 1. Effect of changes to the catalyst during reaction. Catal Rev 48(02):91–144
Huang L, Dai W, Tian B et al (2011) Progress in the selective hydrogenation of cracking stream. Petrochem Tech 04:450–456
Dai W, Zhu J, Wan W (2000) Process and catalyst progress in the selective hydrogenation of C2 stream. Petrochem Tech 07:535–540
Duca D, Frusteri F, Parmaliana A et al (1996) Selective hydrogenation of acetylene in ethylene feedstocks on Pd catalysts. Appl Catal A-Gen 146(2):269–284
Shell Int Res MIJ NV (1974) NL Patent 142934-B
Chemetron Corp. (1962) NL Patent 132820-B
Ventron Corp. (1976) CA Patent 1000306-A
Ventron Corp. (1974). US Patent 3804916-A
Frevel LK, Kressley LJ (1978) US Patent 4101451-A
Vadekar M, Robson H E (1983) US Patent 4387258-A
Molnar A, Sarkany A, Varga M (2001) Hydrogenation of carbon-carbon multiple bonds: chemo-, regio- and stereo-selectivity. J Mol Catal A-Chem 173(1–2):185–221
Molero H, Bartlett BF, Tysoe WT (1999) The hydrogenation of acetylene catalyzed by palladium: hydrogen pressure dependence. J Catal 181(1):49–56
Borodzinski A (1999) Hydrogenation of acetylene-ethylene mixtures on a commercial palladium catalyst. Catal Lett 63(1–2):35–42
Borodzinski A, Golebiowski A (1997) Surface heterogeneity of supported palladium catalyst for the hydrogenation of acetylene-ethylene mixtures. Langmuir 13(5):883–887
Vincent MJ, Gonzalez RD (2001) A Langmuir-Hinshelwood model for a hydrogen transfer mechanism in the selective hydrogenation of acetylene over a Pd/γ-Al2O3 catalyst prepared by the sol-gel method. Appl Catal A-Gen 217(1–2):143–156
Mei D, Sheth PA, Neurock M et al (2006) First-principles-based kinetic Monte Carlo simulation of the selective hydrogenation of acetylene over Pd(111). J Catal 242(1):1–15
Hevia MAG, Bridier B, Perez-Ramirez J (2012) Mechanistic study of the palladium-catalyzed ethyne hydrogenation by the temporal analysis of products technique. App Catal A-Gen 439:163–170
Sheth PA, Neurock M, Smith CM (2003) A first-principles analysis of acetylene hydrogenation over Pd(111). J Phys Chem B 107(9):2009–2017
Xie X, Song X, Dong W et al (2014) Adsorption mechanism of acetylene hydrogenation on the Pd (111) surface. Chin J Chem 32(7):631–636
Duca D, Barone G, Varga Z (2001) Hydrogenation of acetylene-ethylene mixtures on Pd catalysts: computational study on the surface mechanism and on the influence of the carbonaceous deposits. Catal Lett 72(1–2):17–23
Duca D, Varga Z, La Manna G et al (2000) Hydrogenation of acetylene-ethylene mixtures on Pd catalysts: study of the surface mechanism by computational approaches: metal dispersion and catalytic activity. Theor Chem Acc 104(3–4):302–311
Li JN, Pu M, He SH et al (2011) Reaction mechanism of acetylene hydrogenation catalyzed by Pd-8 cluster. Acta Phys Chim Sin 27(4):793–800
Li JN, Pu M, Ma CC et al (2012) The effect of palladium clusters (Pd-n, n = 2–8) on mechanisms of acetylene hydrogenation: a DFT study. J Mol Catal A-Chem 359:14–20
Scholten JJF, Konvalinka JA (1966) Hydrogen-deuterium equilibration and parahydrogen and orthodeuterium conversion over palladium: kinetics and mechanism. J Catal 5(1):1–17
Larsson M, Jansson J, Asplund S (1998) The role of coke in acetylene hydrogenation on Pd/α-Al2O3. J Catal 178(1):49–57
Ahn IY, Lee JH, Kum SS et al (2007) Formation of C4 species in the deactivation of a Pd/SiO2 catalyst during the selective hydrogenation of acetylene. Catal Today 123(1–4):151–157
Xu Q, Smith CM, Blackson J et al (2005) TEM study on catalyst deactivation during selective acetylene hydrogenation. Microsc Microanal 11(S02):1576–1577
Liu RJ, Crozier PA, Smith CM et al (2005) Metal sintering mechanisms and regeneration of palladium/alumina hydrogenation catalysts. App Catal A-Gen 282(1–2):111–121
Ahn IY, Lee JH, Kim SK et al (2009) Three-stage deactivation of Pd/SiO2 and Pd-Ag/SiO2 catalysts during the selective hydrogenation of acetylene. App Catal A-Gen 360(1):38–42
Sarkany A (2001) Formation of C4 oligomers in hydrogenation of acetylene over Pd/Al2O3 and Pd/TiO2 catalysts. React Kinet Catal Lett 74(2):299–307
Esmaeili E, Rashidi AM, Mortazavi Y et al (2013) SMFs-supported Pd nanocatalysts in selective acetylene hydrogenation: pore structure-dependent deactivation mechanism. J Energ Chem 22(5):717–725
Almanza LO, Martinez OI (2001) Regeneration of supported palladium catalyst for selective hydrogenation of acetylene. In: Studies in surface science and catalysis, vol 139. Elsevier, pp 311–318
Liu JY, Lu HM, Ling ZG et al (2008) Catalytic properties of supported Pd/SBA-15 catalyst for selective hydrogenation of alkadienes. Chin J Catal 29(3):206–208
Riyapan S, Boonyongmaneerat Y, Mekasuwandumrong O et al (2014) Improved catalytic performance of Pd/TiO2 in the selective hydrogenation of acetylene by using H2-treated sol-gel TiO2. J Mol Catal A-Chem 383:182–187
Leon MA, Nijhuis TA, van der Schaaf J et al (2012) Mass transfer modeling of a consecutive reaction in rotating foam stirrer reactors: selective hydrogenation of a functionalized alkyne. Chem Eng Sci 73:412–420
Panpranot J, Kontapakdee K, Praserthdam P (2006) Effect of TiO2 crystalline phase composition on the physicochemical and catalytic properties of Pd/TiO2 in selective acetylene hydrogenation. J Phys Chem B 110(15):8019–8024
Borodzinski A (2001) The effect of palladium particle size on the kinetics of hydrogenation of acetylene-ethylene mixtures over Pd/SiO2 catalysts. Catal Lett 71(3–4):169–175
Tessier D, Rakai A, BozonVerduraz F (1996) Palladium-alumina catalysts: precursor, support and dispersion effects in selective hydrogenation. Bull Soc Chim Fr 133(6):637–642
Komhom S, Mekasuwandumrong O, Panpranot J et al (2009) Influence of preparation method on the nanocrystalline porosity of α-Al2O3 and the catalytic properties of Pd/α-Al2O3 in selective acetylene hydrogenation. Ind Eng Chem Res 48(13):6273–6279
Zakumbayeva GD, Toktabayeva NF, Kubasheva AZ et al (1994) Influence of the degree of dispersion of palladium on the selective hydrogenation of acetylene in an ethane-ethylene fraction. Petro Chem 34(3):249–258
Duca D, Liotta LF, Deganello G (1995) Selective hydrogenation of phenylacetylene on pumice-supported palladium catalysts. J Catal 154(1):69–79
Feng JT, Ma XY, Evans DG et al (2011) Enhancement of metal dispersion and selective acetylene hydrogenation catalytic properties of a supported pd catalyst. Ind Eng Chem Res 50(4):1947–1954
Komhom S, Mekasuwandumrong O, Praserthdam P et al (2008) Improvement of Pd/Al2O3 catalyst performance in selective acetylene hydrogenation using mixed phases Al2O3 support. Catal Comm 10(1):86–91
McKenna FM, Mantarosie L, Wells RPK et al (2012) Selective hydrogenation of acetylene in ethylene rich feed streams at high pressure over ligand modified Pd/TiO2. Catal Sci Tech 2(3):632–638
Pattamakomsan K, Aires FJCS, Suriye K et al (2011) Effects of impregnation solvent and reduction temperature on the catalytic performance of Pd/Al2O3 in the selective hydrogenation of 1,3-butadiene. React Kinet Mech Catal 103(2):405–417
Goetz J, Volpe MA, Touroude R (1996) Low-loaded Pd/α-Al2O3 catalysts: influence of metal particle morphology on hydrogenation of buta-1,3-diene and hydrogenation and isomerization of but-1-ene. J Catal 164(2):369–377
Liotta LF, Venezia AM, Martorana A et al (1997) Model pumices supported metal catalysts. 2. Liquid phase selective hydrogenation of 1,3-cyclooctadiene. J Catal 171(1):177–183
Pattamakomsan K, Suriye K, Dokjampa S et al (2010) Effect of mixed Al2O3 structure between θ- and α-Al2O3 on the properties of Pd/Al2O3 in the selective hydrogenation of 1,3-butadiene. Catal Comm 11(5):311–316
Boitiaux JP, Cosyns J, Vasudevan S (1983) Hydrogenation of highly unsaturated hydrocarbons over highly dispersed palladium catalyst: part I: behaviour of small metal particles. Appl Catal 6(1):41–51
Wehrli JT, Thomas DJ, Wainwright MS et al (1991) Selective hydrogenation of propyne over supported copper-catalysts: influence of support. Appl Catal 70(2):253–262
Primet M, Elazhar M, Guenin M (1990) Influence of the support towards platinum catalyzed 1,3-butadiene hydrogenation. Appl Catal 58(2):241–253
Zhu S, Hou R, Wang T (2012) Effects of supports and promoter ag on pd catalysts for selective hydrogenation of acetylene. Chin J Process Eng 12(3):489–496
Asplund S (1996) Coke formation and its effect on internal mass transfer and selectivity in Pd-catalysed acetylene hydrogenation. J Catal 158(1):267–278
Chinayon S, Mekasuwandumrong O, Praserthdam P et al (2008) Selective hydrogenation of acetylene over Pd catalysts supported on nanocrystalline α-Al2O3 and Zn-modified α-Al2O3. Catal Comm 9(14):2297–2302
Houzvicka J, Pestman R, Ponec V (1995) The role of carbonaceous deposits and support impurities in the selective hydrogenation of ethyne. Catal Lett 30(1–4):289–296
Tauster S, Fung S, Garten R (1978) Strong metal-support interactions: group 8 noble metals supported on titanium dioxide. J Am Chem Soc 100(1):170–175
Kang JH, Shin EW, Kim WJ et al (2002) Selective hydrogenation of acetylene on TiO2-added Pd catalysts. J Catal 208(2):310–320
Lee DC, Kim JH, Kim WJ et al (2003) Selective hydrogenation of 1,3-butadiene on TiO2-modified Pd/SiO2 catalysts. App Catal A-Gen 244(1):83–91
Weerachawanasak P, Praserthdam P, Arai M et al (2008) A comparative study of strong metal-support interaction and catalytic behavior of Pd catalysts supported on micron- and nano-sized TiO2 in liquid-phase selective hydrogenation of phenylacetylene. J Mol Catal A-Chem 279(1):133–139
Monteiro RD, Noronha FB, Dieguez LC et al (1995) Characterization of Pd-CeO2 interaction on alumina support and hydrogenation of 1,3-butadiene. App Catal A-Gen 131(1):89–106
Binet C, Jadi A, Lavalley JC et al (1992) Metal support interaction in Pd/CeO2 catalysts—Fourier-transform infrared studies of the effects of the reduction temperature and metal loading.1. Catalysts prepared by the microemulsion technique. J Chem Soc-Faraday Trans 88 (14):2079–2084
Kepinski L, Wolcyrz M (1997) Microstructure of Pd/CeO2 catalyst: effect of high temperature reduction in hydrogen. App Catal A-Gen 150(2):197–220
Shao Y, Xu Z, Wan H et al (2010) Influence of ZrO2 properties on catalytic hydrodechlorination of chlorobenzene over Pd/ZrO2 catalysts. J Hazard Mater 179(1–3):135–140
Zhou J, Han Y, Wang W et al (2013) Reductive removal of chloroacetic acids by catalytic hydrodechlorination over Pd/ZrO2 catalysts. Appl Catal B-Environ 134:222–230
Kim E, Shin EW, Bark CW et al (2014) Pd catalyst promoted by two metal oxides with different reducibilities: properties and performance in the selective hydrogenation of acetylene. App Catal A-Gen 471:80–83
Pattamakomsan K, Ehret E, Morfin F et al (2011) Selective hydrogenation of 1,3-butadiene over Pd and Pd-Sn catalysts supported on different phases of alumina. Catal Today 164(1):28–33
Borodzinski A, Bond GC (2008) Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts, part 2: steady-state kinetics and effects of palladium particle size, carbon monoxide, and promoters. Catal Rev 50(3):379–469
Garcia-Mota M, Bridier B, Perez-Ramirez J et al (2010) Interplay between carbon monoxide, hydrides, and carbides in selective alkyne hydrogenation on palladium. J Catal 273(2):92–102
Lopez N, Bridier B, Perez-Ramirez J (2008) Discriminating reasons for selectivity enhancement of CO in alkyne hydrogenation on palladium. J Phys Chem C 112(25):9346–9350
Zea H, Lester K, Datye AK et al (2005) The influence of Pd-Ag catalyst for ethylene hydrogenation restructuring on the activation energy in ethylene-acetylene mixtures. App Catal A-Gen 282(1–2):237–245
Azizi Y, Petit C, Pitchon V (2008) Formation of polymer-grade ethylene by selective hydrogenation of acetylene over Au/CeO2 catalyst. J Catal 256(2):338–344
Bridier B, Hevia MAG, Lopez N et al (2011) Permanent alkene selectivity enhancement in copper-catalyzed propyne hydrogenation by temporary CO supply. J Catal 278(1):167–172
Praserthdam P, Phatanasri S, Meksikarin J (2000) Activation of acetylene selective hydrogenation catalysts using oxygen containing compounds. Catal Today 63(2–4):209–213
Ngamsom B, Bogdanchikova N, Borja MA et al (2004) Characterisations of Pd-Ag/Al2O3 catalysts for selective acetylene hydrogenation: effect of pretreatment with NO and N2O. Catal Comm 5(5):243–248
Panpranot J, Aungkapipattanachai S, Sangvanich T et al (2007) Effect of N2O pretreatment on fresh and regenerated Pd-Ag/α-Al2O3 catalysts during selective hydrogenation of acetylene. React Kinet Catal Lett 91(2):195–202
Tao J, Yu Z, Liu S (2001) CN Patent 1317367-A
Khrenov EG, Perminova EA, Falkov IG A (1997) RU Patent 2074027-C1
Chamberlain LR, Gibler CJ, Kemp RA et al (1993) US Patent 5177155-A
Park YH, Price GL (1992) Promotional effects of potassium on Pd/Al2O3 selective hydrogenation catalysts. Ind Eng Chem Res 31(2):469–474
Kim WJ, Kang JH, Ahn IY et al (2004) Effect of potassium addition on the properties of a TiO2-modified Pd catalyst for the selective hydrogenation of acetylene. Appl Catal A-Gen 268(1–2):77–82
Huang W, Pyrz W, Lobo RF et al (2007) Selective hydrogenation of acetylene in the presence of ethylene on K+-beta-zeolite supported Pd and PdAg catalysts. App Catal A-Gen 333(2):254–263
Wongwaranon N, Mekasuwandumrong O, Praserthdam P et al (2008) Performance of Pd catalysts supported on nanocrystalline α-Al2O3 and Ni-modified α-Al2O3 in selective hydrogenation of acetylene. Catal Today 131(1–4):553–558
Kim WJ, Kang JH, Ahn IY et al (2004) Deactivation behavior of a TiO2-added Pd catalyst in acetylene hydrogenation. J Catal 226(1):226–229
Ahn IY, Kim WJ, Moon SH (2006) Performance of La2O3 or Nb2O5 added Pd/SiO2 catalysts in acetylene hydrogenation. App Catal A-Gen 308:75–81
Kang JH, Shin EW, Kim WJ et al (2000) Selective hydrogenation of acetylene on Pd/SiO2 catalysts promoted with Ti, Nb and Ce oxides. Catal Today 63(2–4):183–188
Kim WJ, Ahn IY, Lee JH et al (2012) Properties of Pd/SiO2 catalyst doubly promoted with La oxide and Si for acetylene hydrogenation. Catal Comm 24:52–55
Kim SK, Lee JH, Ahn IY et al (2011) Performance of Cu-promoted Pd catalysts prepared by adding Cu using a surface redox method in acetylene hydrogenation. App Catal A-Gen 401(1–2):12–19
Song S, Dai W, Zhu J et al (2004) Characterization of ethylene fraction selective hydrogenation catalyst using la promoted Al2O3 as support. Petrochem Tech 33(3):197–201
Liu T, Jin Y, Wei M et al (2003) Selective hydrogenation of FCC light gasoline on the Ni-La/Al2O3 catalyst. J Petrochem Univ 16 (4):24–26, 34
Wang H, Liu ZY, Shi RJ et al (2005) Deactivation and regeneration of amorphous Ru-La-B/ZrO2 catalyst for selective hydrogenation of benzene to cyclohexene. Chin J Catal 26(5):407–411
Liu SC, Liu Z, Wang Z et al (2008) Characterization and study on performance of the Ru-La-B/ZrO2 amorphous alloy catalysts for benzene selective hydrogenation to cyclohexene under pilot conditions. Chem Eng J 139(1):157–164
Sun HJ, Pan YJ, Li SH et al (2013) Selective hydrogenation of benzene to cyclohexene over Ce-promoted Ru catalysts. J Energ Chem 22(5):710–716
Chen PR, Chew LM, Kostka A et al (2013) The structural and electronic promoting effect of nitrogen-doped carbon nanotubes on supported Pd nanoparticles for selective olefin hydrogenation. Catal Sci Tech 3(8):1964–1971
Tailleur RG, Nascar JR (2012) Effect of H2S on selective hydrogenation of diolefins using NiPdCex/Si-Al-coated structured packing catalyst. App Catal A-Gen 439:125–134
Crespo-Quesada M, Dykeman RR, Laurenczy G et al (2011) Supported nitrogen-modified Pd nanoparticles for the selective hydrogenation of 1-hexyne. J Catal 279(1):66–74
Wang KJ, Chen YY, Li XS et al (2009) Unusual catalytic performance for selective acetylene hydrogenation over Pd nanoparticles fabricated on N, O-containing organic groups modified silica. Catal Lett 127(3–4):392–399
Chan CWA, Mahadi AH, Li MMJ et al (2014) Interstitial modification of palladium nanoparticles with boron atoms as a green catalyst for selective hydrogenation. Nat Comm 5(5):5787
Yang B, Burch R, Hardacre C et al (2014) Selective hydrogenation of acetylene over Pd-boron catalysts: a density functional theory study. J Phys Chem C 118(7):3664–3671
Cooper A, Bachiller-Baeza B, Anderson JA et al (2014) Design of surface sites for the selective hydrogenation of 1,3-butadiene on Pd nanoparticles: Cu bimetallic formation and sulfur poisoning. Catal Sci Tech 4(5):1446–1455
Shin EW, Choi CH, Chang KS et al (1998) Properties of Si-modified Pd catalyst for selective hydrogenation of acetylene. Catal Today 44(1–4):137–143
Boitiaux JP, Cosyns J, Robert E (1989) Additive effects in the selective hydrogenation of unsaturated-hydrocarbons on platinum and rhodium catalysts: 1. Influence of nitrogen-containing compounds. Appl Catal 49(2):219–234
Zhang QW, Li J, Liu XX et al (2000) Synergetic effect of Pd and Ag dispersed on Al2O3 in the selective hydrogenation of acetylene. Appl Catal A-Gen 197(2):221–228
Khan NA, Uhl A, Shaikhutdinov S et al (2006) Alumina supported model Pd-Ag catalysts: a combined STM, XPS, TPD and IRAS study. Surf Sci 600(9):1849–1853
Khan NA, Shaikhutdinov S, Freund HJ (2006) Acetylene and ethylene hydrogenation on alumina supported Pd-Ag model catalysts. Catal Lett 108(3–4):159–164
Sheth PA, Neurock M, Smith CM (2005) First-principles analysis of the effects of alloying Pd with Ag for the catalytic hydrogenation of acetylene-ethylene mixtures. J Phys Chem B 109(25):12449–12466
Ma Y, Diemant T, Bansmann J et al (2011) The interaction of CO with PdAg/Pd(111) surface alloys-A case study of ensemble effects on a bimetallic surface. Phys Chem Chem Phys 13(22):10741–10754
Gonzalez S, Neyman KM, Shaikhutdinov S et al (2007) On the promoting role of Ag in selective hydrogenation reactions over Pd-Ag bimetallic catalysts: a theoretical study. J Phys Chem C 111(18):6852–6856
Jin YM, Datye AK, Rightor E et al (2001) The influence of catalyst restructuring on the selective hydrogenation of acetylene to ethylene. J Catal 203(2):292–306
Mei D, Neurock M, Smith CM (2009) Hydrogenation of acetylene-ethylene mixtures over Pd and Pd-Ag alloys: first-principles-based kinetic Monte Carlo simulations. J Catal 268(2):181–195
Pachulski A, Schodel R, Claus P (2011) Performance and regeneration studies of Pd-Ag/Al2O3 catalysts for the selective hydrogenation of acetylene. App Catal A-Gen 400(1–2):14–24
Lamberov AA, Egorova SR, Il’yasov IR et al (2007) Changes in the course of reaction and regeneration of a Pd-Ag/Al2O3 catalyst for the selective hydrogenation of acetylene. Kinet Catal 48(1):136–142
Lee JH, Kim SK, Ahn IY et al (2011) Performance of Pd-Ag/Al2O3 catalysts prepared by the selective deposition of Ag onto Pd in acetylene hydrogenation. Catal Comm 12(13):1251–1254
Han YX, Peng D, Xu ZY et al (2013) TiO2 supported Pd@Ag as highly selective catalysts for hydrogenation of acetylene in excess ethylene. Chem Comm 49(75):8350–8352
Kontapakdee K, Panpranot J, Praserthdam P (2007) Effect of Ag addition on the properties of Pd-Ag/TiO2 catalysts containing different TiO2 crystalline phases. Catal Comm 8(12):2166–2170
Panpranot J, Nakkararuang L, Ngamsom B et al (2005) Synthesis, characterization, and catalytic properties of Pd and Pd-Ag catalysts supported on nanocrystalline TiO2 prepared by the solvothermal method. Catal Lett 103(1–2):53–58
Osswald J, Giedigkeit R, Jentoft RE et al (2008) Palladium-gallium intermetallic compounds for the selective hydrogenation of acetylene—Part I: preparation and structural investigation under reaction conditions. J Catal 258(1):210–218
Osswald J, Kovnir K, Armbruester M et al (2008) Palladium-gallium intermetallic compounds for the selective hydrogenation of acetylene—Part II: surface characterization and catalytic performance. J Catal 258(1):219–227
Kovnir K, Osswald J, Armbruester M et al (2006) PdGa and Pd3Ga7: highly-selective catalysts for the acetylene partial hydrogenation. In: Studies in surface science and catalysis, vol 162. Elsevier, pp 481–488
Armbruester M, Wowsnick G, Friedrich M et al (2011) Synthesis and catalytic properties of nanoparticulate intermetallic Ga-Pd compounds. J Am Chem Soc 133(23):9112–9118
Kovnir K, Armbruester M, Teschner D et al (2009) In situ surface characterization of the intermetallic compound PdGa—A highly selective hydrogenation catalyst. Surf Sci 603(10–12):1784–1792
Ota A, Armbruester M, Behrens M et al (2011) Intermetallic compound Pd2Ga as a selective catalyst for the semi-hydrogenation of acetylene: from model to high performance systems. J Phys Chem C 115(4):1368–1374
He Y, Liang L, Liu Y et al (2014) Partial hydrogenation of acetylene using highly stable dispersed bimetallic Pd-Ga/MgO-Al2O3 catalyst. J Catal 309:166–173
Bechthold P, Jasen P, Gonzalez E et al (2012) Hydrogen adsorption on PdGa(110): a DFT study. J Phys Chem C 116(33):17518–17524
Klanjsek M, Gradisek A, Kocjan A et al (2012) PdGa intermetallic hydrogenation catalyst: an NMR and physical property study. J Phys-Cond Matter 24(8):9
Rosenthal D, Widmer R, Wagner R et al (2012) Surface investigation of intermetallic PdGa(111). Langmuir 28(17):6848–6856
Bechthold P, Ardenghi JS, Nagel O et al (2014) Hydrogen adsorption on PdGa(100), (111) and (111) surfaces: a DFT study. Int J Hydrogen Energ 39(5):2093–2103
Prinz J, Gaspari R, Stockl QS et al (2014) Ensemble effect evidenced by CO adsorption on the 3-fold PdGa surfaces. J Phys Chem C 118(23):12260–12265
Prinz J, Pignedoli CA, Stockl QS et al (2014) Adsorption of small hydrocarbons on the three-fold PdGa surfaces: the road to selective hydrogenation. J Am Chem Soc 136(33):11792–11798
Lu FF, Sun DH, Huang JL et al (2014) Plant-mediated synthesis of Ag-Pd alloy nanoparticles and their application as catalyst toward selective hydrogenation. ACS Sustain Chem Eng 2(5):1212–1218
Wei H-H, Yen CH, Lin H-W et al (2013) Synthesis of bimetallic Pd-Ag colloids in CO2-expanded hexane and their application in partial hydrogenation of phenylacetylene. J Supercrit Fluids 81:1–6
Redjala T, Remita H, Apostolescu G et al (2006) Bimetallic Au-Pd and Ag-Pd clusters synthesised by gamma or electron beam radiolysis and study of the reactivity/structure relationships in the selective hydrogenation of buta-1,3-diene. Oil Gas Sci Technol 61(6):789–797
Sarkany A (1997) Semi-hydrogenation of 1,3-butadiene over Pd-Ag/α-Al2O3 poisoned by hydrocarbonaceous deposits. Appl Catal A-Gen 165(1–2):87–101
Sarkany A (1997) Self-poisoning and aging of Pd-Ag/Al2O3 in semi-hydrogenation of 1,3-butadiene: Effects of surface inhomogeneity caused by hydrocarbonaceous deposits. In: Studies in surf sci and catalysis, vol 111. Elsevier, pp 111–118
Zhang YY, Diao WJ, Williams CT et al (2014) Selective hydrogenation of acetylene in excess ethylene using Ag- and Au-Pd/SiO2 bimetallic catalysts prepared by electroless deposition. App Catal A-Gen 469:419–426
Pei GX, Liu XY, Wang AQ et al (2014) Promotional effect of Pd single atoms on Au nanoparticles supported on silica for the selective hydrogenation of acetylene in excess ethylene. New J Chem 38(5):2043–2051
Sarkany A, Horvath A, Beck A (2002) Hydrogenation of acetylene over low loaded Pd and Pd-Au/SiO2 catalysts. Appl Catal A-Gen 229(1–2):117–125
Kittisakmontree P, Yoshida H, Fujita S et al (2015) The effect of TiO2 particle size on the characteristics of Au-Pd/TiO2 catalysts. Catal Comm 58:70–75
Wang Z, Zhang K, Yang K, Liu C (2014) Effect of alkali metal modification on selective hydrogenation of isoprene on Pd-Au/Al2O3 catalysts. China Pet Process Petrochem 45(12):38–42
Zhang K, Wang Z, Ze B et al (2014) Selective hydrogenation of isoprene on Pd-Au/Al2O3 catalysts modified with Bi. Petrochem Tech 43(2):132–137
El Kolli N, Delannoy L, Louis C (2013) Bimetallic Au-Pd catalysts for selective hydrogenation of butadiene: influence of the preparation method on catalytic properties. J Catal 297:79–92
Kittisakmontree P, Pongthawornsakun B, Yoshida H et al (2013) The liquid-phase hydrogenation of 1-heptyne over Pd-Au/TiO2 catalysts prepared by the combination of incipient wetness impregnation and deposition-precipitation. J Catal 297:155–164
Pongthawornsakun B, Fujita SI, Arai M et al (2013) Mono- and bi-metallic Au-Pd/TiO2 catalysts synthesized by one-step flame spray pyrolysis for liquid-phase hydrogenation of 1-heptyne. App Catal A-Gen 467:132–141
Piccolo L, Piednoir A, Bertolini JC (2005) Pd-Au single-crystal surfaces: segregation properties and catalytic activity in the selective hydrogenation of 1,3-butadiene. Surf Sci 592(1–3):169–181
Miura H, Terasaka M, Oki K et al (1993) Preparation of eggshell type Pd-Ag and Pd-Au catalysts by selective deposition and hydrogenation of 1,3-butadiene. In: Studies in surface science and catalysis, vol 75. Elsevier, pp 2379–2382
Wang ZQ, Zhou ZM, Zhang R et al (2014) Selective hydrogenation of phenylacetylene over Pd-Cu/γ-Al2O3 catalysts. Acta Phys-Chim Sin 30(12):2315–2322
McCue AJ, McRitchie CJ, Shepherd AM et al (2014) Cu/Al2O3 catalysts modified with Pd for selective acetylene hydrogenation. J Catal 319:127–135
Kang M, Song MW, Kim KL (2002) SMSI effect on ceria supported Cu-Pd catalysts in the hydrogenation of 1, 3-butadiene. React Kinet Catal Lett 75(1):177–183
Insorn P, Suriyaphaparkorn K, Kitiyanan B (2013) Selective hydrogenation of 1-hexyne using Pd-Cu and Pd-W supported on alumina catalysts. In: 11th international conference on chemical and process engineering, Pts 1–4 32:847–852
Guczi L, Schay Z, Stefler G et al (1999) Pumice-supported Cu-Pd catalysts: influence of copper on the activity and selectivity of palladium in the hydrogenation of phenylacetylene and but-1-ene. J Catal 182(2):456–462
Mashkovsky IS, Baeva GN, Stakheev AY et al (2014) Novel Pd-Zn/C catalyst for selective alkyne hydrogenation: evidence for the formation of Pd-Zn bimetallic alloy particles. Mendeleev Comm 24(6):355–357
Tew MW, Emerich H, van Bokhoven JA et al (2011) Formation and characterization of PdZn alloy: a very selective catalyst for alkyne semihydrogenation. J Phys Chem C 115(17):8457–8465
Esmaeili E, Mortazavi Y, Khodadadi AA et al (2012) The role of tin-promoted Pd/MWNTs via the management of carbonaceous species in selective hydrogenation of high concentration acetylene. Appl Surf Sci 263:513–522
Choi SH, Lee JS (2000) XAFS study of tin modification of supported palladium catalyst for 1,3-butadiene hydrogenation in the presence of 1-butene. J Catal 193(2):176–185
Verdier S, Didillon B, Morin S et al (2003) Pd-Sn/Al2O3 catalysts from colloidal oxide synthesis—II. Surface characterization and catalytic properties for buta-1,3-diene selective hydrogenation. J Catal 218(2):288–295
Breinlich C, Haubrich J, Becker C et al (2007) Hydrogenation of 1,3-butadiene on Pd(111) and PdSn/Pd(111) surface alloys under UHV conditions. J Catal 251(1):123–130
Esmaeili E, Rashidi AM, Khodadadi AA et al (2014) Palladium-Tin nanocatalysts in high concentration acetylene hydrogenation: a novel deactivation mechanism. Fuel Process Technol 120:113–122
Lederhos CR, Juliana Maccarrone M, Badano JM et al (2011) Hept-1-yne partial hydrogenation reaction over supported Pd and W catalysts. App Catal A-Gen 396(1–2):170–176
Menezes WG, Altmann L, Zielasek V et al (2013) Bimetallic Co-Pd catalysts: study of preparation methods and their influence on the selective hydrogenation of acetylene. J Catal 300:125–135
Sarkany A, Zsoldos Z, Stefler G et al (1995) Promoter effect of Pd in hydrogenation of 1,3-butadiene over Co-Pd catalysts. J Catal 157(1):179–189
Zina MS, Ghorbel A (2004) Pd-Mo bimetallic catalysts supported on Y-Zeolite: effect of molybdenum on structural and catalytic properties of palladium in partial hydrogenation of 1,3 butadiene. In: Recent advances in the science and technology of zeolites and related materials, Pts A–C, vol 154. Studies in surface science and catalysis, pp 2364–2370
Miegge P, Rousset JL, Tardy B et al (1994) Pd1Ni99 and Pd5Ni95—Pd surface segregation and reactivity for the hydrogenation of 1,3-butadiene. J Catal 149(2):404–413
Gomez G, Belelli PG, Cabeza GF et al (2010) The adsorption of 1,3-butadiene on Pd/Ni multilayers: the interplay between spin polarization and chemisorption strength. J Solid State Chem 183(12):3086–3092
Jia JF, Haraki K, Kondo JN et al (2000) Selective hydrogenation of acetylene over Au/Al2O3 catalyst. J Phys Chem B 104(47):11153–11156
Choudhary TV, Sivadinarayana C, Datye AK et al (2003) Acetylene hydrogenation on Au-based catalysts. Catal Lett 86(1–3):1–8
Murugadoss A, Sorek E, Asscher M (2014) Structure and composition of Au-Cu and Pd-Cu bimetallic catalysts affecting acetylene reactivity. Top Catal 57(10–13):1007–1014
Sarkany A, Schay Z, Frey K et al (2010) Some features of acetylene hydrogenation on Au-iron oxide catalyst. App Catal A-Gen 380(1–2):133–141
Liu XY, Li YN, Lee JW et al (2012) Selective hydrogenation of acetylene in excess ethylene over SiO2 supported Au-Ag bimetallic catalyst. App Catal A-Gen 439:8–14
Rodriguez JC, Marchi AJ, Borgna A et al (2001) Gas phase selective hydrogenation of acetylene: importance of the formation of Ni-Co and Ni-Cu bimetallic clusters on the selectivity and coke deposition. In: Studies in surface science and catalysis, vol 139. Elsevier, pp 37–44
Onda A, Komatsu T, Yashima T (2000) Characterization and catalytic properties of Ni-Sn intermetallic compounds in acetylene hydrogenation. Phys Chem Chem Phys 2(13):2999–3005
Studt F, Abild-Pedersen F, Bligaard T et al (2008) Identification of non-precious metal alloy catalysts for selective hydrogenation of acetylene. Science 320(5881):1320–1322
Xu JH, Huang YQ, Yang XF et al (2014) Enhancement of acetylene hydrogenation activity over Ni-Zn bimetallic catalyst by doping with Au. J Nanosci Nanotechno 14(9):6894–6899
Trimm DL, Cant NW, Liu IOY (2011) The selective hydrogenation of acetylene in the presence of carbon monoxide over Ni and Ni-Zn supported on MgAl2O4. Catal Today 178(1):181–186
Yuanzhi L, Yining F, Jie H et al (2004) Selective liquid hydrogenation of long chain linear alkadienes on molybdenum nitride and carbide modified by oxygen. Chem Eng J 99(3):213–218
Wu ZL, Hao ZX, Ying PL et al (2000) An IR study on selective hydrogenation of 1,3-butadiene on transition metal nitrides: 1,3-butadiene and 1-butene adsorption on Mo2N/γ-Al2O3 catalyst. J Phys Chem B 104(51):12275–12281
Hao ZX, Wei ZB, Wang LJ et al (2000) Selective hydrogenation of ethyne on gamma-Mo2N. App Catal A Gen 192(1):81–84
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2017 Springer Science+Business Media Singapore
About this chapter
Cite this chapter
Hou, R. (2017). Introduction. In: Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-10-0773-6_1
Download citation
DOI: https://doi.org/10.1007/978-981-10-0773-6_1
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-10-0772-9
Online ISBN: 978-981-10-0773-6
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)