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Removal of Lead by Nanoscale Zerovalent Iron in Surfacewater

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InCIEC 2015

Abstract

This study investigates removal of Lead (Pb2+) by nanoscale zerovalent iron (nZVI) in surface water under various environmental conditions. Particles size of synthesized nZVI was in the range of 35.57–49.62 nm (<100 nm) and congregated to each other. Remarkable removal of Pb2+ (k = 0.30 min−1) was observed in nZVI suspension (0.32 g/L) in 10 min, while no significant of Pb2+ removal was observed in suspension alone at neutral pH. The removal of Pb2+ was significantly dependent on the suspension pH and concentrations of Pb2+ and nZVI. Percent removal of Pb2+ significantly decreased as the concentrations of Pb2+ increased. Removal efficiency of Pb2+ decreased (49–25 %) as the pH increased from neutral to basic conditions (pH 7–9). As concentration of nZVI increased (0.06–0.10 g/L), the removal efficiency increased approximately 1.67 times (42–70 %). Experimental results from this study provide basic knowledge on the role of nZVI as a reductant to remove Pb2+ in surface water at different environment conditions.

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References

  1. H. M. Salem, E. A. Eweida, and A. Farag, “Heavy metals in drinking water and their environmental impact on human health” ICEHM2000, Cairo University, Egypt, 2000, pp. 542–556.

    Google Scholar 

  2. S. Khan, Q. Cao, Y. M. Zheng, Y. Z. Huang and Y. Z. Zhu, “Health risk of heavy metals in contaminated soils and food crops irrigated with wastewater in Beijing, China”, Environmental Pollution, 2008, vol 152, pp. 686–692.

    Google Scholar 

  3. S. M. Saeed and I. M. Shaker, “Assessment of heavy metal pollution in water and sediments and their effect on oreochromis niloticus in the Northen Delta Lakes, Egypt”. International Symposium on Tilapia in Aquaculture 2008, pp. 475–489.

    Google Scholar 

  4. U.S. Environmental Protection Agency, “Lead and Environment” Retrived from http://www.epa.gov/superfund/lead/health.htm

  5. S. Suratman and A. Sefie, “Groundwater contamination at landfill sites in Selangor”. XXXVIII IAH Congress, Krakow, Poland.

    Google Scholar 

  6. F. A. Caliman, B. M. Robu, C. Smaranda, V. L. Pavel, and M. Gavrilescu, “Soil and groundwater cleanup: benefits and limits of emerging technologies”. Clean Technology Environmental Policy, vol 13, pp. 241–268.

    Google Scholar 

  7. L. B. Hoch, E. J. Mack, B. W. Hydutsky, J. M. Hershman, J. M. Skluzacek, and T. E. Mallouk, 2008 “Carbothermal Synthesis of Carbon Supported Nanoscale Zero- Valent Iron Particles for the Remediation of Hexavalent Chromium”. Environmental Science & Technology, 2008, vol. 42, pp. 2600–2605.

    Google Scholar 

  8. N. C. Mueller, J. Braun, J. Bruns, M. Černík, D. Rickerby, and B. Nowack, “Application of nanoscale zero valent iron (NZVI) for groundwater remediation in Europe “. Springer-Verlag, 2011.

    Google Scholar 

  9. R. Singh, V. Misra and R.P. Singh, “Removal of hexavalent chromium from contaminated ground water using zero-valent iron nanoparticles”. Environmental Monitoring and Assessment, 2011, vol 184, pp. 643–3651.

    Google Scholar 

  10. Z. E. Kashitarash, S. M. Taghi, N. Kazem, A. Abbass, and R. Alireza, “Application of iron nanoparticles in landfill leachate treatment – case study: Hamadan landfill leachate”. Iranian Journal of Environmental Health Sciences & Engineering 2012, vol 9, pp. 36.

    Google Scholar 

  11. X. Li, J. Cao, and W. Zhang, “Stoichiometry of Cr(VI) immobilization using Nanoscale Zerovalent Iron (nZVI): A study with high-resolution X-ray Photoelectron Spectroscopy (HR-XPS)”. Ind. Eng, Chem. Res, 2008, vol. 47, pp. 2131–2139.

    Google Scholar 

  12. S. Comba, A. D. Molfetta, and R. Sethi, 2010. “A Comparison between Field Applications of Nano-, Micro-, and Millimetric Zero-Valent Iron for The Remediation of Contaminated Aquifers”. Water Air Soil Pollution, 2011, 215:595–607.

    Google Scholar 

  13. M. Arshadi, M. Soleymanzadeh, J. W. L. Salvacion and F. SalimiVahid, “Nanoscale Zero-Valent Iron (nZVI) supported on singuelas waste for Pb(II) removal from aqueous solution: Kinetics, thermodynamic and mechanism”, Journal of Colloid and Interface Science. 2014, vol 426, pp. 241–251.

    Google Scholar 

  14. N. A. Miranda, S. E. Baltazar, A. Garcia, A.H. Romero, M. A Rubio and D. Altbir, “Lead removal by nano-scale zero valent iron: Surface analysis and pH effect”, Materials Research Bulletin, 2014, vol 59, pp. 341–348.

    Google Scholar 

  15. N. Efecan. “Characterization of The Adsorption Behaviour of Aqueous Cd(Ii) and Ni(Ii) Ions on Nanoparticles of Zero-Valent Iron”, Izmir Institute of Technology, 2008.

    Google Scholar 

  16. M. L. Alowitz & M. M. Scherer, “Kinetics of nitrate, nitrite and Cr(VI) reduction by iron metal”, Environmental Science & Technology, 2002, vol 36, No. 3.

    Google Scholar 

  17. A. Saberi, 2012. “Comparison of Pb2+ removal efficiency by Zero Valent Iron Nanoparticles and Ni/Fe Bimetallic Nanoparticles”. Iranica Journal of Energy & Environment, 2012, vol 3(2), pp. 189–196.

    Google Scholar 

  18. N. N. I. Nik Redzauddin, J. Kassim and A. Amir, “Removal of Zinc by Nano-scale Zero Valent Iron in Groundwater” Applied Mechanics and Materials, 2015, vols 773–774, pp. 1231–1236.

    Google Scholar 

  19. N. Kržišnik, A. Mladenovič, A. A. Škapin, L. Škrlep, J. Ščančar & R. Milačič. “Nanoscale zero-valent iron for the removal of Zn2+, Zn(II)-EDTA and Zn(II)-citrate from aqueous solutions”, Journal of Science of the Total Environment,2014, vol 476–477, pp. 20–28.

    Google Scholar 

  20. U.S. Environmental Protection Agency, Nanotechnology White Paper, Science Policy Council, 2007.

    Google Scholar 

  21. M. L. Alowitz & M. M. Scherer, “ Kinetics of nitrate, nitrite and Cr(VI) reduction by iron metal”, Environmental Science & Technology, 2002, vol 36, no. 3.

    Google Scholar 

  22. F. Fu, J. Ma, L. Xie, B. Tang, W. Han & S. Lin. “Chromium removal using resin supported nanoscale zero-valent iron” Journal of Environmental Management, 2013, vol 128, pp. 822–827.

    Google Scholar 

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Acknowledgements

Heartfelt credits are addressed to UiTM, Research Intensive Faculty Grant (600-RMI/DANA 5/3/RIF (740/2012)) for the research funding.

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Correspondence to Amnorzahira Amir .

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Iskandar, R.H.R.A., Kassim, J., Ali, M.F., Amir, A. (2016). Removal of Lead by Nanoscale Zerovalent Iron in Surfacewater. In: Yusoff, M., Hamid, N., Arshad, M., Arshad, A., Ridzuan, A., Awang, H. (eds) InCIEC 2015. Springer, Singapore. https://doi.org/10.1007/978-981-10-0155-0_7

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  • DOI: https://doi.org/10.1007/978-981-10-0155-0_7

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  • Print ISBN: 978-981-10-0154-3

  • Online ISBN: 978-981-10-0155-0

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