Abstract
Gas sensors are widely used, playing important role in different sectors of daily life ranging from safety and security, environmental monitoring, food safety & control to medical diagnosis. The development of physical, chemical and biological detection systems, triggered the search for more sensitive, reliable, simple and low-cost gas sensors. With this perspective, metal oxides as sensing materials have been widely used in gas sensors due to the high sensitivity, fast response and recovery times. However, their low selectivity, lack of stability, and the high operational temperatures have limited their use as sensing material for applications in gas sensors. Recently, as a promising alternative to metal oxide, metal sulfides have attracted attention as sensing materials because, the activation of intrinsic surface reactions might occur at lower working temperatures, what has the potential to lead to better selectivity and stability during operation. Besides the electronic properties of the gas sensing nanomaterials, their morphology plays an important role for improving their sensing properties. In this context, hollow nanostructures with unique physicochemical property, surface active sites and abundant inner spaces have the potential to improve the gas detection. Here, recent research progress in hollow metal sulfides nanostructures and applications in gas sensors are summarized. The effect of structural and compositional engineering in the sensing properties of hollow metal sulfides is discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Jin C, Kim H, Choi S-W, Kim SS, Lee C (2014) Synthesis, structure, and gas-sensing properties of Pt-functionalized TiO2 nanowire sensors. J Nanosci Nanotechnol 14:5833
Peeters D, Barreca D, Carraro G, Comini E, Gasparotto A, Maccato C, Sada C, Sberveglieri G (2014) Au/ε-Fe2O3 nanocomposites as selective NO2 gas sensors. J Phys Chem C 118:11813
Li L, Liu M, He S, Chen W (2014) Free standing 3D mesoporous Co3O4@carbon foam nanostructures for ethanol gas sensing. Anal Chem 86:7996
Chang SP, Wen CH, Chang SJ (2014) Two-dimensional ZnO nanowalls for gas sensor and photoelectrochemical applications. Electron Mater Lett 10:693
Kim HR, Haensch AH, Kim ID, Barsan N, Weimar U, Lee JH (2011) The role of NiO doping in reducing the impact of humidity on the performance of SnO2-based gas sensors: synthesis, strategies, and phenomenological and spectroscopy studies. Adv Funct Mater 21:4456
Yamazoe N (2005) Toward innovation of gas sensor technology. Sensors Actuators B Chem 108(2)
Cássia-Santos MR, Sousa VC, Oliveira MM, Sensato FR, Bacelar WK, Gomes JW, Longo E, Leite ER, Varela JA (2005) Recent research developments in SnO2-based varistors. Mat Chem Phys 90:1
Barsan N, Koziej D, Weimar U (2007) Metal oxide-based gas sensor research: how to? Sensors Actuators B Chem 121:18
Bochenkov VE, Sergeev GB (2010) Sensitivity, selectivity, and stability of gas-sensitive metal-oxide nanostructures. In: Metal oxide nanostructures and their applications. American Scientific Publishers, Valencia, p 31
Timoumi A, Bouguila N, Chaari M, Kraini M, Matoussi A, Bouzouita H (2016) Electrical and dielectric properties of In2S3 synthesized by solid state reaction. J Alloy Compd 679:59
Liu Y, Xu HY, Qian YT (2006) double-source approach to in2s3 single crystallites and their electrochemical properties. Cryst Growth Des 6:1304
Wu Y, Wadia C, Ma WL, Sadtler B, Alivisatos AP (2008) Synthesis and photovoltaic application of Copper(I) sulfide nanocrystals. Nano Lett 8:2551
Li TL, Lee YL, Teng H (2011) CuInS2 quantum dots coated with CdS as high-performance sensitizers for TiO2 electrodes in photoelectrochemical cells. J Mater Chem 21:5089
Bierman MJ, Jin S (2009) Potential applications of hierarchical branching nanowires in solar energy conversion. Energy Environ Sci (2):1050
Hornyak GL, Dutta J, Tibbals HF, Rao AK (2008) Introduction to nanoscience. CRC Press, Boca Raton
Boudiba A, Zhang C, Umek P, Bittencourt C, Snyders R, Olivier MG, Debliquy M (2013) Sensitive and rapid hydrogen sensors based on Pd–WO3 thick films with different morphologies. Int J Hydrog Energy 38:2565
Wang Y, Wang T, Da P, Wu XM, Zheng HG (2013) Silicon nanowires for biosensing, energy storage, and conversion. Adv Mater 25:5177–5195
Desai UV, Xu C, Wu J, Gao D (2012) Solid-state dye-sensitized solar cells based on ordered ZnO nanowire arrays. Nanotechnology 23:205401
Bârsan N, Weimar U (2003) Understanding the fundamental principles of metal oxide based gas sensors; the example of CO sensing with SnO2 sensors in the presence of humidity. J Phys Condens Matter 15:R813–R839
Liu Z, Misra M (2010) Dye-sensitized photovoltaic wires using highly ordered TiO2 nanotube arrays. ACS Nano 4:2196
Lee J-H (2009) Gas sensors using hierarchical and hollow oxide nanostructures: overview. Sens Actuators B: Chem 140:319
Wang F, Li H, Yuan Z, Sun Y, Chang F, Deng H, Xie L, Li H (2016) High sensitive gas sensor based on CuO nanoparticles synthetized by sol-gel method, vol 6. RSC Advances, Cambridge, p 79343
Yu XL, Wang Y, Chan HLW, Cao B (2009) Novel gas sensoring materials based on CuS hollow spheres. Microporous Mesoporous Mater 118:423
Zhang J, Liu X, Neri G, Pinna N (2016) Nanostructured materials for room-temperature gas sensors. Adv Mater 28:795
Zou Z, Qiu Y, Xie C, Xu J, Luo Y, Wang C, Yan H (2015) CdS/TiO2 nanocomposite film and its enhanced photoelectric responses to dry air and formaldehyde induced by visible light at room temperature. J Alloys Compd 645:17
Xu K, Li N, Zeng D, Tian S, Zhang S, Hu D, Xie C (2015) Interface bonds determined gas-sensing of SnO2-SnS2 hybrids to ammonia at room temperature. ACS Appl Mater Interfaces 7:11359
Shi W, Huo L, Wang H, Zhang H, Yang J, Wei P (2006) Hydrothermal growth and gas sensing property of flower-shaped SnS2 nanostructures. Nanotechnology 17:2918
Fu X, Liu J, Wan Y, Zhang X, Meng F, Liu J (2012) Preparation of a leaf-like CdS micro−/nanostructure and its enhanced gas-sensing properties for detecting volatile organic compounds. J Mater Chem 22:17782
Yin YD, Rioux RM, Erdonmez CK, Hughes S, Somorjai GA, Alivisatos AP (2004) Science 304:711
Yang YJ, Qi LM, Lu CH, Ma JM, Cheng HM (2005) Angew Chem Int Ed 44:598; (a) Wang YL, Cai L, Xia YN (2005) AdV Mater 17:473
Liu B, Zeng HC (2004) J Am Chem Soc 126:16744
Ostwald W (1900) On the assumed isomerism of red and yellow mercury oxide and the surfacetension of solid bodies. Z Phys Chem 34:495
Pala N, Rumyantsev SL, Sinius J, Talapatra S, Shur MS, Gaska R (2004) Electron Lett 40:273
Hara M, Kondo T, Komoda M, Ikeda S, Shinohara K, Tanaka A, Kondo J, Domen K (1998) Chem Common:357
Liu B, Zeng HC (2005) Symmetric and asymmetric Ostwald ripening in the fabrication of homogeneous core-shell semiconductors. Small 1:566–571
Shao HF, Qian XF, Zhu ZK (2005) The synthesis of ZnS hollow nanospheres with nanoporous shell. J Solid State Chem 178:3522
Smigelskas AD, Kirkendall EO (1947) Zinc diffusion in alpha brass. Trans AIME 171:130
Wang Q, Li J-X, Li G-D et al (2007) Formation of CuS nanotube arrays from CuCl nanorods through a gas-solid reaction route. J Cryst Growth 299:386
Cao H, Qian X, Wang C et al (2005) High symmetric 18-facet polyhedron nanocrystals of Cu7S4 with a hollow nanocage. J Am Chem Soc 127:16024
Ye L, Wu C, Guo W et al (2006) MoS2 hierarchical hollow cubic cages assembled by bilayers: one-step synthesis and their electrochemical hydrogen storage properties. Chem Commun:4738
Wang Y, Cai L, Xia Y (2005) Monodisperse spherical colloids of Pb and their use as chemical templates to produce hollow particles. Adv Mater 17:473
Yin Y, Rioux RM, Erdonmez CK et al (2004) Formation of hollow nanocrystals through the nanoscale Kirkendall effect. Science 304:711
Cao HL, Qian XF, Wang C, Ma XD, Yin J, Zhu ZK (2005) High symmetric 18-Facet polyhedron nanocrystals of Cu7S4 with a hollow nanocage. J Am Chem Soc 127:16025
Wang YL, Cai L, Xia Y (2005) Monodisperse spherical colloids of Pb and their use as chemical templates to produce hollow particles. Adv Mater 17:473
Ye L, Wu Cz, Guo W, Xie Y (2006) MoS2 hierarchical hollow cubic cages assembled by bilayers: one-step synthesis and their electrochemical hydrogen storage properties. Chem Commun:4738
Xu LL, Chen D, Liu H, Yang J (2018) Understanding the formation of nanocomposites consisting of silver sulfide and platinum hollow nanostructures. J Solid State Chem 265:387
Wang XF, Xie Z, Huang HT, Liu Z, Chen D, Shen GZ (2012) Gas sensors, thermistor and photodetector based on ZnS nanowires. J Mater Chem 22:6845
Gaiardo A, Fabbri B, Guidi V, Bellutti P, Giberti A, Gherardi S, Vanzetti L, Malagù C, Zonta G (2016) Metal sulfides as sensing materials for chemoresistive gas sensors. Sensors 16:296
Carotta MC, Benetti M, Ferrari E, Giberti A, Malagù C, Nagliati M, Vendemiati B, Martinelli G (2007) Basic interpretation of thick film gas sensors for atmospheric application. Sensors Actuators B Chem 126:672–677
Park M, Park YJ, Chen X (2016) MoS2-based tactile sensor for electronic skin applications. Adv Mater 28(13):2556
Zhang LP, Dong R, Zhu ZhY, Wang ShR (2017) Au nanoparticles decorated ZnS hollow spheres for highly improved gas sensor performances. Sens Actuators B 245:112
Kim JS, Yoo HW, Choi HO (2014) Tunable volatile organic compounds sensor by using thiolated ligand conjugation on MoS2. Nano Lett 14:5941
Wang H, Sun Z, Lu Q et al (2012) One-pot synthesis of (Au Nanorod)–(Metal Sulfide) core–shell nanostructures with enhanced gas-sensing property. Small 8(8):1167–1172
Yue Q, Shao ZZ, Chang SL, Li JB (2013) Adsorption of gas molecules on monolayer MoS2 and effect of applied electric field. Nanoscale Res Lett 8:425
Tan YH, Yu K, Yang T, Zhang QF, Cong WT, Yin HH, Zhang ZL, Chen YW, Zhu ZQ (2014) The combinations of hollow MoS2 micro@nano-spheres: one-step synthesis, excellent photocatalytic and humidity sensing properties. J Mater Chem C 2(27):5422
Yu XL, Wang Y, Chan HLW, Cao CB (2009) Novel gas sensoring materials based on CuS hollow spheres. Microporous Mesoporous Mater 118:423
Guidi V, Fabbri B, Gaiardo A, Gherardi S, Giberti A, Malagù C, Zonta G, Bellutti P (2015) Metal sulfides as a new class of sensing materials. Procedia Eng 120:138
Yu XL, Ji HM, Wang HL, Sun J, Du XW (2010) Synthesis and sensing properties of ZnO/ZnS nanocages. Nanoscale Res Lett 5:644
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature B.V.
About this paper
Cite this paper
Li, W., Bittencourt, C., Snyders, R. (2019). Progress of Sensors Based on Hollow Metal Sulfides Nanoparticles. In: Bittencourt, C., Ewels, C., Llobet, E. (eds) Nanoscale Materials for Warfare Agent Detection: Nanoscience for Security. NMWAD 2017. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1620-6_6
Download citation
DOI: https://doi.org/10.1007/978-94-024-1620-6_6
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-024-1619-0
Online ISBN: 978-94-024-1620-6
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)