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Nanostructured Materials for the Detection of CBRN pp 279–292Cite as

Carbon Nitride Oxide (g-C3N4)O and Heteroatomic N-Graphene (Azagraphene) as Perspective New Materials in CBRN Defense

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Abstract

In the twenty first century, there was an abrupt growth in the number of terrorist attacks and local military conflicts. Weapons of mass destruction, in particular, chemical weapons, are now being used again in the Syrian conflict. Therefore, the development of modern means of protection against weapons of mass destruction is becoming extremely relevant. The most important modern tool for the timely detection of substances that are deadly dangerous to humans in CBRN defense is a new generation of sensors – nanosensors based on nanomaterials. As a promising material for the creation of a new generation of nanosensors, graphite-like carbon nitride and its nanostructured and doped derivatives attract special attention. The water-soluble carbon nitride oxide (g-C3N4)O was synthesized by the gas phase method under special reaction conditions of pyrolysis of melamine and urea. Reduction by the hydroquinone of carbon nitride oxide (g-C3N4)O yields nanostructured reduced carbon nitride (or reduced multilayer azagraphene).

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References

  1. Liu J, Wang H, Antonietti M (2016) Graphitic carbon nitride “reloaded”: emerging applications beyond (photo) catalysis. Chem Soc Rev 45:2308–2326

    Article  Google Scholar 

  2. Zhang Y, Pan Q, Chai G et al (2013) Synthesis and luminescence mechanism of multicolor-emitting g-C3N4 nanopowders by low temperature thermal condensation of melamine. Sci Rep 3:1943–1950

    Article  Google Scholar 

  3. Ma TY, Tang Y, Dai S et al (2014) Proton-functionalized two-dimensional graphitic carbon nitride nanosheet: an excellent metal-label-free biosensing platform. Small 10:2382–2389

    Article  Google Scholar 

  4. Kharlamov O, Bondarenko M, Kharlamova G (2015) O-Doped carbon nitride (O-g-C3N) with high oxygen content (11.1 mass%) synthesized by pyrolysis of pyridine, chapter 9. In: Camesano TA (ed) Nanotechnology to aid chemical and biological defense, NATO science for peace and security series A: chemistry and biology. Springer, Dordrecht, pp 129–145

    Google Scholar 

  5. Kharlamova G, Kharlamov O, Bondarenko M, Khyzhun O (2016) Hetero-Carbon nanostructures as the effective sensors in security systems, chapter 19. In: Bonca J, Kruchinin S (eds) Nanomaterials for security, NATO science for peace and security series A: chemistry and biology. Springer, Dordrecht, pp 239–258

    Google Scholar 

  6. Xiong M, Rong Q, Meng H et al (2017) Two-dimensional graphitic carbon nitride nanosheets for biosensing applications. Biosens Bioelectron 89:212–223

    Article  Google Scholar 

  7. Cooper AI, Bojdys MJ (2014) Carbon nitride vs. graphene – now in 2D. Mater Today 17:468–469

    Article  Google Scholar 

  8. Ong WJ (2017) 2D/2D graphitic carbon nitride (g-C3N4) heterojunction nanocomposites for photocatalysis: why does face-to-face interface matter? Front Mater 4:1–10

    Article  Google Scholar 

  9. Franklin EC (1922) The ammono carbonic acids. J Am Chem Soc 44(3):486–509

    Article  Google Scholar 

  10. Martha S, Nashima A, Parida KM (2013) Facile synthesis of highly active g-C3N4 for efficient hydrogen production under visible light. J Mater Chem A 1:7816–7824

    Article  Google Scholar 

  11. Xiangqian F, Zheng X, Zhu S (2015) Improved photocatalytic activity of g-C3N4 derived from cyanamide–urea solution. RSC Adv 5:8323–8328

    Article  Google Scholar 

  12. Zheng Y, Liu J, Liang J et al (2012) Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis. Energy Environ Sci 5:6717–6731

    Article  Google Scholar 

  13. Wu P, Shi J, Chen J, Wang B et al (2012) Graphitic carbon nitride modified by silicon for improved visible light driven photocatalytic hydrogen production, chap 33. In: Mathur S, Ray SS (eds) Nanostructured materials and nanotechnology VI: ceramic engineering and science proceedings. Wiley, pp 137–148

    Google Scholar 

  14. Fan X, Peng W, Li Y et al (2008) Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv Mater 20:4490–44932

    Article  Google Scholar 

  15. Han K, Wang C, Li Y et al (2013) Facile template-free synthesis of porous g-C3N4 with high photocatalytic performance under visible light. RSC Adv 3:9465–9469

    Article  Google Scholar 

  16. Zhang S, Li J, Zeng M et al (2013) In situ synthesis of magnetic graphitic carbon nitride photocatalyst and its synergistic catalytic performance. ACS Appl Mater Interfaces 5:12735–12743

    Article  Google Scholar 

  17. Yuan B, Chu Z, Li G et al (2014) Ribbon-like graphitic carbon nitride (g-C3N4): green synthesis, self-assembly and unique optical properties. J Mater Chem C 2:8212–8215

    Article  Google Scholar 

  18. Zhang X, Xie X, Wang H et al (2013) Enhanced photoresponsive ultrathin graphitic-phase C3N4 nanosheets for bioimaging. J Am Chem Soc 135:18–21

    Article  Google Scholar 

  19. Li J, Shen B, Hong Z et al (2012) A facile approach to synthesize novel oxygen-doped g-C3N4 with superior visible-light photoreactivity. Chem Commun 48:12017–12019

    Article  Google Scholar 

  20. Ming L, Yue H, Xua L et al (2014) Hydrothermal synthesis of oxidized g-C3N4 and its regulation of photocatalytic activity. J Mater Chem A 2:19145–19149

    Article  Google Scholar 

  21. Ma X, Lv Y, Xu J et al (2012) A strategy of enhancing the photoactivity of g-C3N4 via doping of nonmetal elements: a first-principles study. J Phys Chem C 116:23485–23493

    Article  Google Scholar 

  22. Tian J, Zhang L, Fan X et al (2016) A post-grafting strategy to modify g-C3N4 with aromatic heterocycles for enhanced photocatalytic activity. J Mater Chem A 4:13814–13821

    Article  Google Scholar 

  23. Sun Y, Ha W, Chen J et al (2016) Advances and applications of graphitic carbon nitride as sorbent in analytical chemistry for sample pretreatment: a review. TrAC Trends Anal Chem 84:12–21

    Article  Google Scholar 

  24. Nair AAS, Sundara R, Anitha N (2015) Hydrogen storage performance of palladium nanoparticles decorated graphitic carbon nitride. Int J Hydrogen Energy 40:3259–3267

    Article  Google Scholar 

  25. Nair AAS, Sundara R (2016) Palladium cobalt alloy catalyst nanoparticles facilitated enhanced hydrogen storage performance of graphitic carbon nitride. J Phys Chem C 120:9612–9618

    Article  Google Scholar 

  26. Kharlamov A, Bondarenko M, Kharlamova G (2016) Method for the synthesis of water-soluble oxide of graphite-like carbon nitride. Diamond Relat Mater 61:46–55

    Article  ADS  Google Scholar 

  27. Kharlamov AI, Bondarenko ME, Kharlamova GA (2014) New method for synthesis of oxygen-doped graphite-like carbon nitride from pyridine. Russ J Appl Chem 87:1284–1293

    Article  Google Scholar 

  28. Kharlamov A, Bondarenko M, Kharlamova G et al (2016) Features of the synthesis of carbon nitride oxide (g-C3N4)O at urea pyrolysis. Diam Relat Mater 66:16–22

    Article  ADS  Google Scholar 

  29. Kharlamov A, Bondarenko M, Kharlamova G et al (2016) Synthesis of reduced carbon nitride at the reduction by hydroquinone of water-soluble carbon nitride oxide (g-C3N4)O. J Solid State Chem 241:115–120

    Article  ADS  Google Scholar 

  30. Kharlamova G, Kharlamov O, Bondarenko M et al (2013) Hetero-carbon: heteroatomic molecules and nano-structures of carbon, Part VII. In: Vaseashta A, Khudaverdyan S (eds) Advanced sensors for safety and security. NATO science for peace and security series B: physics and biophysics. Springer, Netherlands, pp 339–357

    Google Scholar 

  31. Rodionov VE, Shmidko IN, Zolotovsky AA, Kruchinin SP (2013) Electroluminescence of Y2O3:Eu and Y2O3:Sm films. Mater Sci 2:210–220

    Google Scholar 

  32. Repetsky SP, Vyshyvana IG, Molodkin VB, Lizunov VV (2017) Influence of the adsorbed atoms of potassium on an energy spectrum of grapheme. Metallofiz Noveishie Tekhnol 39:1017–1022

    Article  Google Scholar 

  33. Ermakov V, Kruchinin S, Hori H, Fujiwara A (2007) Phenomena of strong electron correlation in the resonant tunneling. Int J Mod Phys B 11:827–835

    Google Scholar 

  34. Ermakov V, Kruchinin S, Fujiwara A (2008) Electronic nanosensors based on nanotransistor with bistability behaviour. In: Bonca J, Kruchinin S (eds) Proceedings of the NATO ARW “Electron transport in nanosystems”. Springer, pp 341–349

    Google Scholar 

  35. Wang X, Maeda K, Thomas A et al (2009) A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat Mater 8:76–80

    Article  ADS  Google Scholar 

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Author information

Authors and Affiliations

  1. Frantsevich Institute for Problems of Materials Science of NASU, Kiev, Ukraine

    O. Kharlamov, M. Bondarenko, P. Silenko, O. Khyzhun & N. Gubareni

  2. Taras Shevchenko National University of Kyiv, Kiev, Ukraine

    O. Kharlamov

  3. Taras Shevchenko National University of Kyiv, Kyiv, Ukraine

    G. Kharlamova

Authors
  1. O. Kharlamov
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  2. M. Bondarenko
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  3. G. Kharlamova
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  4. P. Silenko
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  5. O. Khyzhun
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  6. N. Gubareni
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Corresponding author

Correspondence to O. Kharlamov .

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Editors and Affiliations

  1. J. Stefan Institute, Ljubljana, Slovenia

    Janez Bonča

  2. Bogolyubov Institute for Theoretical Physics, NASU, Kiev, Ukraine

    Sergei Kruchinin

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Kharlamov, O., Bondarenko, M., Kharlamova, G., Silenko, P., Khyzhun, O., Gubareni, N. (2018). Carbon Nitride Oxide (g-C3N4)O and Heteroatomic N-Graphene (Azagraphene) as Perspective New Materials in CBRN Defense. In: Bonča, J., Kruchinin, S. (eds) Nanostructured Materials for the Detection of CBRN. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1304-5_20

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