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Enzymes for Chemicals and Polymers

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Abstract

Isolated enzymes have been used as highly specific catalyst in organic chemicals synthesis. However, industrial significance of enzyme reactions was especially emphasized in the 1970s with the production of high fructose corn syrup (HFCS) . Recombinant DNA technology also enables the efficient production of enzymes, making them cheaply available for use.

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References

  • Akkara JA, Seneccal KJ and Kapaln DL. Synthesis and characterization of polymers produced by horseradish peroxidase in dioxane. J. Polym. Sci. A Polym. Chem., 1991, 29:1561–1574.

    Google Scholar 

  • Alva KS, Lee TS, Kumar J and Tripathy SK. Enzymatically synthesized photodynamic polyaniline containing azobenzene groups. Chem. Mater., 1998, 10:1270–1275.

    Google Scholar 

  • Chandel AK, Rao LV, Narasu ML and Singh OV. The realm of penicillin G acylase in β-lactam antibiotics. Enzyme Microb Technol, 2008, 42:199–207.

    Google Scholar 

  • Dordick JS, Marletta MA and Klibanov AM. Polymerization of phenols catalyzed by peroxidase in nonaqueous media. Biotechnology and Bioengineering. 1987, 30:31–36.

    Google Scholar 

  • Drauz K and Waldmann H. ed, Enzyme Catalysis in organic synthesis; a comprehensive handbook. Volume I, II. VCH, 1995.

    Google Scholar 

  • Hanai T, Atsumi S. and Liao JC. Engineered synthetic pathway for isopropanol production in Escherichia coli. Appl. Environmental Microbiology, 2007, 73:7814–7818.

    Google Scholar 

  • Ikeda R, Sugihara J, Uyama H and Kobayashi S, Enzymatic oxidative polymerization of 4-hydroxybenzoic acid derivatives to poly(phenylene oxide)s. Polym Int., 1998, 47:295.

    Google Scholar 

  • Kim JW and Yoo YJ. A new detergentless micro-emulsion system using uroshiol as an enzyme reactor system. J. Microbio. Biotechnol. 2001, 11:369–375.

    Google Scholar 

  • Kim YH, Won KH, Kwon JM, Jeong HS, Park SY, An ES and Song BK. Synthesis of polycardanol from renewable source using a fungal peroxidase Coprinus cinereus, J. Molecular Catalyst B. Enzymatic, 2005, 34:33–38.

    Google Scholar 

  • Kim YH, An ES, Song BK, Kim DS and Rahul Chelikani, Polymerization of cardanol using soybean peroxidase and its potential application as anti-biofilm coating material, Biotechnology Letters, 2003, 25:1521–1524.

    Google Scholar 

  • Kobayashi S, Ritter H and Kaplan D. Enzyme-catalyzed synthesis of polymers, Springer, 2006.

    Google Scholar 

  • Kobayashi S and Makino A. Enzymatic polymer synthesis: an opportunity for green polymer chemistry. Chem. Rev, 2009, 109:5288–5353.

    Google Scholar 

  • Liu H and Lu T. Autonomous production of 1,4-butandiol via a de novo biosynthesis pathway in engineered Escherichia coli. Metabolic Engineering. 2015, 29:135–141.

    Google Scholar 

  • Li Q, Li G, Yu S, Zhang Z, Ma F and Feng Y. Ring-opening polymerization of ε-caprolactone catalyzed by a novelthermophilic lipase from Fervidobacterium nodosum. Process Biochem., 2011a, 46:253–257.

    Google Scholar 

  • Li Q, Li G, Ma F, Zhang Z, Zheng B and Feng Y. Highly efficient ring-opening polymerization of ε-caprolactone catalyzed by are combinant Escherichia coli whole-cell biocatalyst. Process Biochem., 2011b, 46:477–481.

    Google Scholar 

  • Ma J, Li Q, Song B, Liu D, Zheng B, Zhang Z and Feng Y. Ring-opening polymerization of ε-caprolactone catalyzed by a novelthermophilic esterase from the archaeon Archaeoglobus fulgidus. J. Mol. Catal. B: Enzyme, 2009, 56:151–157.

    Google Scholar 

  • Parmar A, Kumar H, Marwaha S and Kennedy JF. Advances in enzymatic transformation of penicillins to 6-aminopenicillanic acid (6-APA). Biotechnol Adv, 2000, 18:289–301.

    Google Scholar 

  • Richter M, Schulenburg C, Jankowska D, Heck T and Faccio G. Novel materials through nature’s catalysts. Mater. Today, 2015, doi:10.1016/j.mattod.2015.04.002.

  • Schulze B and Wubbolts MG. Biocatalysis for industrial production of fine chemicals. Current Opinion in Biotechnology, 1999, 10:609–615.

    Google Scholar 

  • Thomas SM, Di Cosimo R and Nagarajan V. Biocatalysis: applications and potentials form the chemical industry, Trends Biotechnol. 2002, 20:238–242.

    Google Scholar 

  • Wu Q, Chen CX, Du LL and Lin XF. Enzymatic synthesis of amoxicillin via a one-pot enzymatic hydrolysis and condensation cascade process in the presence of organic co-solvents. Appl Biochem Biotechnol, 2010, 160:2026–35.

    Google Scholar 

  • Xiang S, Zhang Q, Zhang G, Jiang W, Wang Y, Zhou H, Li Q and Tang J. Facile synthesis of block copolymers by tandem ROMP and eROP from esters precursors. Biomacromolecules, 2014, 15:3112–3118.

    Google Scholar 

  • Yamada H. and Nagawawa T. Production of useful amides by enzymatic hydration of nitriles. Ann. N.Y. Acad. Sci., 1990, 613:142–154.

    Google Scholar 

  • Yang Y, Yu Y, Zhang Y, Liu C, Shi W and Li Q. Lipase/esterase-catalyzed ring-opening polymerization: a green polyester synthesis technique. Process Biochem., 2011, 46:1900–1908.

    Google Scholar 

  • Yang Y, Zhang J, Wu D, Xing Z, Zhou Y, Shi W and Li Q. Chemoenzymatic synthesis of polymeric materials using lipases as catalysts: A review. Biotechnol. Adv., 2014, 32: 642–651.

    Google Scholar 

  • Yu Y, Wu D, Liu C, Zhao Z, Yang Y and Li Q. Lipase/esterase-catalyzed synthesis of aliphatic polyesters via polycondensation: a review. Process Biochem., 2012, 47:1207–1236.

    Google Scholar 

  • Zhang J, Shi H, Wu D, Xing Z, Zhang A, Yang Y and Li Q. Recent developments in lipase-catalyzed synthesis of polymeric materials. Process Biochem., 2014, 49:797–806.

    Google Scholar 

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Correspondence to Young Je Yoo .

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Yoo, Y.J., Feng, Y., Kim, Y.H., Yagonia, C.F.J. (2017). Enzymes for Chemicals and Polymers. In: Fundamentals of Enzyme Engineering. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1026-6_12

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