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Functional Nanomaterials Prepared by Nanoarchitectonics-Based Supramolecular Assembly

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Nanomaterials and Nanoarchitectures

Abstract

Recently, we have introduced the new concept of nanoarchitectonics to traditional supramolecular self-assembly to promote the development of the bottom-up approaches. The concept of nanoarchitectonics can be developed using synergic contributions of technical innovations such as atomic/molecular-level control, chemical nanofabrication, and self- and field-controlled organization. This concept might be applied to inorganic, organic, biochemical, and other systems, beyond the levels of substance, material, and system regardless of their dimensions i.e., macro, micro, or nano scale. In this chapter, recent examples of research on functional nanomaterials prepared by nanoarchitectonics-based supramolecular assembly are explained. These examples are classified according to their scale, (i) molecular-level nanoarchitectonics, (ii) microscale assembly, (iii) macroscopic materials with internal nanostructures.

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References

  1. Ariga K, Hill JP, Lee MV, Vinu A, Charvet R, Acharya S (2008) Challenges and breakthroughs in recent research on self-assembly. Sci Technol Adv Mater 9:014109

    Article  Google Scholar 

  2. Li M, Ishihara S, Ji Q, Akada M, Hill JP, Ariga K (2012) Paradigm shift from self-assembly to commanded assembly of functional materials: recent examples in porphyrin/fullerene supramolecular systems. Sci Technol Adv Mater 13:053001

    Article  Google Scholar 

  3. Ariga K, Li M, Richards GJ, Hill JP (2011) Nanoarchitectonics: a conceptual paradigm for design and synthesis of dimension-controlled functional nanomaterials. J Nanosci Nanotechnol 11:1–13

    Article  CAS  Google Scholar 

  4. Ariga K, Ishihara S, Abe H, Li M, Hill JP (2012) Materials nanoarchitectonics for environmental remediation and sensing. J Mater Chem 22:2369–2377

    Article  CAS  Google Scholar 

  5. Ariga K, Ji Q, McShane MJ, Lvov YM, Vinu A, Hill JP (2014) Inorganic nanoarchitectonics for biological applications. Chem Mater 24:728–737

    Article  Google Scholar 

  6. Ramanathan M, Shrestha LK, Mori T, Ji Q, Hill JP, Ariga K (2013) Amphiphile nanoarchitectonics: from basic physical chemistry to advanced applications. Phys Chem Chem Phys 15:10580–10611

    Article  CAS  Google Scholar 

  7. Mori T, Sakakibara K, Endo H, Akada M, Okamoto K, Shundo A, Lee MV, Ji Q, Fujisawa T, Oka K, Matsumoto M, Sakai H, Abe M, Hill JP, Ariga K (2013) Langmuir nanoarchitectonics: one-touch fabrication of regular-size nanodisks at the air-water interface. Langmuir 29:7239–7248

    Article  CAS  Google Scholar 

  8. Ariga K, Ji Q, Mori T, Naito M, Yamauchi Y, Abe H, Hill JP (2013) Enzyme nanoarchitectonics: organization and device application. Chem Soc Rev 42:6322–6345

    Article  CAS  Google Scholar 

  9. Ariga K, Mori T, Hill JP (2013) Interfacial nanoarchitectonics: lateral and vertical, static and dynamic. Langmuir 29:8459–8471

    Article  CAS  Google Scholar 

  10. Shrestha LK, Ji Q, Mori T, Miyazawa K, Yamauchi Y, Hill JP, Ariga K (2013) Fullerene nanoarchitectonics: from zero to higher dimensions. Chem Asian J 8:1662–1679

    Article  CAS  Google Scholar 

  11. Hill JP, Wakayama Y, Schmitt W, Tsuruoka T, Nakanishi T, Zandler ML, McCarty AL, D’Souza F, Milgrom LR, Ariga K (2006) Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation. Chem Commun 2320–2322

    Google Scholar 

  12. Hill JP, Wakayama Y, Akada M, Ariga K (2007) Self-assembly structures of a phenol-substituted porphyrin in the solid state: hydrogen bonding, Kagomé lattice, and defect tolerance. J Phys Chem C 111:16174–16180

    Article  CAS  Google Scholar 

  13. Hill JP, Wakayama Y, Akada M, Ariga K (2009) Two-dimensional molecular array of porphyrin derivatives with bright and dark spots as a model of two-digit molecular-dot memory. Synth Met 159:765–768

    Article  CAS  Google Scholar 

  14. Ariga K, Lee MV, Mori T, Yu X-Y, Hill JP (2010) Two-dimensional nanoarchitectonics based on self-assembly. Adv Colloid Interface Sci 154:20–29

    Article  CAS  Google Scholar 

  15. Ariga K, Ito H, Hill JP, Tsukube H (2012) Molecular recognition: from solution science to nano/materials technology. Chem Soc Rev 41:5800–5835

    Article  CAS  Google Scholar 

  16. Oishi Y, Torii Y, Kato T, Kuramori M, Suehiro K, Ariga K, Taguchi K, Kamino A, Koyano H, Kunitake T (1997) Molecular patterning of a guanidinium/orotate mixed monolayer through molecular recognition with flavin adenine dinucleotide. Langmuir 13:519–524

    Article  CAS  Google Scholar 

  17. Oishi Y, Kato T, Narita T, Ariga K, Kunitake T (2008) Formation of nano-domains confined in two-dimensional molecular plane. Langmuir 24:1682–1685

    Article  CAS  Google Scholar 

  18. Sathish M, Miyazawa K, Hill JP, Ariga K (2009) Solvent-engineering for shape-shifter pure fullerene (C60). J Am Chem Soc 131:6372–6373

    Article  CAS  Google Scholar 

  19. Shrestha LK, Sathish M, Hill JP, Miyazawa K, Tsuruoka T, Sanchez-Ballester NM, Honma I, Ji Q, Ariga K (2013) Alcohol-induced decomposition of olmstead’s crystalline Ag(I)-fullerene heteronanostructure yields ‘Bucky Cubes’. J Mater Chem C 1:1174–1181

    Article  CAS  Google Scholar 

  20. Shrestha LK, Yamauchi Y, Hill JP, Miyazawa K, Ariga K (2013) Fullerene crystals with bimodal pore architectures consisting of macropores and mesopores. J Am Chem Soc 135:586–589

    Article  CAS  Google Scholar 

  21. Charvet R, Acharya S, Hill JP, Akada M, Liao M, Seki S, Honsho Y, Saeki A, Ariga K (2009) Block-copolymer-nanowires with nanosized domain segregation and high charge mobilities as stacked p/n heterojunction arrays for repeatable photocurrent switching. J Am Chem Soc 131:18030–18031

    Article  CAS  Google Scholar 

  22. Acharya S, Hill JP, Ariga K (2009) Soft Langmuir-Blodgett technique for hard nanomaterials. Adv Mater 21:2959–2981

    Article  CAS  Google Scholar 

  23. Ariga K, Yamauchi Y, Mori T, Hill JP (2013) What can be done with the Langmuir-Blodgett method? Recent developments and its critical role in materials science. Adv Mater 25:6477–6511

    Article  CAS  Google Scholar 

  24. Ariga K, Hill JP, Ji Q (2007) Layer-by-layer assembly as a versatile bottom-up nanofabrication technique for exploratory research and realistic application. Phys Chem Chem Phys 9:2319–2340

    Article  CAS  Google Scholar 

  25. Ariga K, Ji Q, Hill JP, Bando Y, Aono M (2012) Forming nanomaterials as layered functional structures towards materials nanoarchitectonics. NPG Asia Mater 4:e17

    Article  Google Scholar 

  26. Ariga K, Yamauchi Y, Rydzek G, Ji Q, Yonamine Y, Wu KC-W, Hill JP (2014) Layer-by-layer nanoarchitectonics: invention, innovation, and evolution. Chem Lett 43:36–68

    Article  CAS  Google Scholar 

  27. Ariga K, Vinu A, Ji Q, Ohmori O, Hill JP, Acharya S, Koike J, Shiratori S (2008) A layered mesoporous carbon sensor based on nanopore-filling cooperative adsorption in the liquid phase. Angew Chem Int Ed 47:7254–7257

    Article  CAS  Google Scholar 

  28. Ji Q, Yoon SB, Hill JP, Vinu A, Yu J-S, Ariga K (2009) Layer-by-layer films of dual-pore carbon capsules with designable selectivity of gas adsorption. J Am Chem Soc 131:4220–4221

    Article  CAS  Google Scholar 

  29. Ji Q, Honma I, Paek S-M, Akada M, Hill JP, Vinu A, Ariga K (2010) Layer-by-layer films of graphene and ionic liquid for highly selective gas sensing. Angew Chem Int Ed 49:9737–9739

    Article  CAS  Google Scholar 

  30. Ji Q, Miyahara M, Hill JP, Acharya S, Vinu A, Yoon SB, Yu J-S, Sakamoto K, Ariga K (2008) Stimuli-free auto-modulated material release from mesoporous nanocompartment films. J Am Chem Soc 130:2376–2377

    Article  CAS  Google Scholar 

  31. Ji Q, Acharya S, Hill JP, Vinu A, Yoon SB, Yu J-S, Sakamoto K, Ariga K (2009) Hierarchic nanostructure for auto-modulation of material release: mesoporous nanocompartment films. Adv Funct Mater 19:1792–1799

    Article  CAS  Google Scholar 

  32. Li M, Ishihara S, Akada M, Liao M, Sang L, Hill JP, Krishnan V, Ma Y, Ariga K (2011) Electrochemical coupling layer-by-layer (ECC-LbL) assembly. J Am Chem Soc 133:7348–7351

    Article  CAS  Google Scholar 

  33. Li M, Ishihara S, Ji Q, Ma Y, Hill JP, Ariga K (2012) Electrochemical coupling layer-by-layer (ECC-LbL) assembly in patterning mode. Chem Lett 41:383–385

    Article  CAS  Google Scholar 

  34. Ariga K, Vinu A, Yamauchi Y, Ji Q, Hill JP (2012) Nanoarchitectonics for mesoporous materials. Bull Chem Soc Jpn 85:1–32

    Article  CAS  Google Scholar 

  35. Vinu A, Ariga K, Mori T, Nakanishi T, Hishita S, Golberg D, Bando Y (2005) Preparation and characterization of well ordered hexagonal mesoporous carbon nitride. Adv Mater 17:1648–1652

    Article  CAS  Google Scholar 

  36. Vinu A, Terrones M, Golberg D, Hishita S, Ariga K, Mori T (2005) Synthesis of mesoporous BN and BCN exhibiting large surface areas via templating methods. Chem Mater 17:5887–5890

    Article  CAS  Google Scholar 

  37. Vinu A, Miyahara M, Ariga K (2005) Biomaterial immobilization in nanoporous carbon molecular sieves: influence of solution pH, pore volume and pore diameter. J Phys Chem B 109:6436–6441

    Article  CAS  Google Scholar 

  38. Vinu A, Hossain KZ, Satish Kumar G, Ariga K (2006) Adsorption of L-histidine over mesoporous carbon molecular sieves. Carbon 44:530–536

    Article  CAS  Google Scholar 

  39. Hartmann M, Vinu A, Chandrasekar G (2005) Adsorption of vitamin E on mesoporous carbon molecular sieves. Chem Mater 17:829–833

    Article  CAS  Google Scholar 

  40. Zhang Q, Ariga K, Okabe A, Aida T (2004) Condensable amphiphile with cleavable tail as ‘lizard’ template for sol-gel synthesis of functionalized mesoporous silica. J Am Chem Soc 126:988–989

    Article  CAS  Google Scholar 

  41. Otani W, Kinbara K, Zhang Q, Ariga K, Aida T (2007) Catalysis of a peptidic micellar assembly covalently immobilized within mesoporous silica channels: importance of amphiphilic spatial design. Chem Eur J 13:1731–1736

    Article  CAS  Google Scholar 

  42. Vinu A, Miyahara M, Sivamurugan V, Mori T, Ariga K (2005) Large pore cage type mesoporous carbon, carbon nanocage: a superior adsorbent for biomaterials. J Mater Chem 15:5122–5127

    Article  CAS  Google Scholar 

  43. Ariga K, Vinu A, Miyahara M, Hill JP, Mori T (2007) One-pot separation of tea components through selective adsorption on pore-engineered nanocarbon, carbon nanocage. J Am Chem Soc 129:11022–11023

    Article  CAS  Google Scholar 

  44. Mandal S, Sathish M, Saravanan G, Datta KKR, Ji Q, Hill JP, Abe H, Honma I, Ariga K (2010) Open-mouthed metallic microcapsules: exploring performance improvements at agglomeration-free interiors. J Am Chem Soc 132:14415–14417

    Article  CAS  Google Scholar 

  45. Ariga K, Mori T, Hill JP (2012) Mechanical control of nanomaterials and nanosystems. Adv Mater 24:158–176

    Article  CAS  Google Scholar 

  46. Ariga K, Terasaka Y, Sakai D, Tsuji H, Kikuchi J (2000) Piezoluminescence based on molecular recognition by dynamic cavity array of steroid cyclophanes at the air-water interface. J Am Chem Soc 122:7835–7836

    Article  CAS  Google Scholar 

  47. Ariga K, Nakanishi T, Terasaka Y, Tsuji H, Sakai D, Kikuchi J (2005) Piezoluminescence at the air-water interface through dynamic molecular recognition driven by lateral pressure application. Langmuir 21:976–981

    Article  CAS  Google Scholar 

  48. Michinobu T, Shinoda S, Nakanishi T, Hill JP, Fujii K, Player TN, Tsukube H, Ariga K (2006) Mechanical control of enantioselectivity of amino acid recognition by cholesterol-armed cyclen monolayer at the air-water interface. J Am Chem Soc 128:14478–14479

    Article  CAS  Google Scholar 

  49. Michinobu T, Shinoda S, Nakanishi T, Hill JP, Fujii K, Player TN, Tsukube H, Ariga K (2011) Langmuir monolayer of cholesterol-armed cyclen complex that can control enantioselectivity of amino acid recognition by surface pressure. Phys Chem Chem Phys 13:4895–4900

    Article  CAS  Google Scholar 

  50. Mori T, Okamoto K, Endo H, Hill JP, Shinoda S, Matsukura M, Tsukube H, Suzuki Y, Kanekiyo Y, Ariga K (2010) Mechanical tuning of molecular recognition to discriminate the single-methyl-group difference between thymine and uracil. J Am Chem Soc 132:12868–12870

    Article  CAS  Google Scholar 

  51. Sakakibara K, Joyce LA, Mori T, Fujisawa T, Shabbir SH, Hill JP, Anslyn EV, Ariga K (2012) A mechanically-controlled indicator displacement assay. Angew Chem Int Ed 51:9643–9646

    Article  CAS  Google Scholar 

  52. Izawa H, Kawakami K, Sumita M, Tateyama Y, Hill JP, Ariga K (2013) β-Cyclodextrin-crosslinked alginate gel for patient-controlled drug delivery systems: regulation of host-guest interactions with mechanical stimuli. J Mater Chem B 1:2155–2161

    Article  CAS  Google Scholar 

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Acknowledgement

This work was partly supported by World Premier International Research Center Initiative (WPI Initiative), MEXT, Japan and Core Research for Evolutional Science and Technology (CREST) program of Japan Science and Technology Agency (JST), Japan.

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Authors and Affiliations

  1. World Premier International (WPI), Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, 305-0044, Japan

    Katsuhiko Ariga, Yusuke Yonamine & Jonathan P. Hill

  2. Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency (JST), 1-1 Namiki, Tsukuba, 305-0044, Japan

    Katsuhiko Ariga, Yusuke Yonamine & Jonathan P. Hill

Authors
  1. Katsuhiko Ariga
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  2. Yusuke Yonamine
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  3. Jonathan P. Hill
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Corresponding author

Correspondence to Katsuhiko Ariga .

Editor information

Editors and Affiliations

  1. Tyndall National Institute, Cork, Ireland

    M. Bardosova

  2. Faculty of Chemical Technology, University of Pardubice, Pardubice, Czech Republic

    T. Wagner

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Ariga, K., Yonamine, Y., Hill, J.P. (2015). Functional Nanomaterials Prepared by Nanoarchitectonics-Based Supramolecular Assembly. In: Bardosova, M., Wagner, T. (eds) Nanomaterials and Nanoarchitectures. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9921-8_3

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