Abstract
In this Chapter we describe the experimental procedures and main features of solid organised films produced with three techniques: Langmuir-Blodgett (LB), electrostatic layer-by-layer (LbL) and self-assembled monolayers (SAMs). Emphasis is placed on possible applications in which molecular control of the film architectures is exploited. In particular, the use of organised films in sensing units for electronic tongues (e-tongues) and biosensors is highlighted not only in terms of the nanotech-based methods but also in connection with computational methods. The latter are employed in sensing and biosensing data analysis, and becoming increasingly important for generating fully-fledged clinical diagnosis systems. With regard to basic science involved in organised films, we discuss the use of Langmuir monolayers in cell membrane models, which is important for drug design and drug delivery systems.
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References
Whitesides GM, Mathias JP, Seto CT (1991) Molecular self-assembly and nanochemistry: a chemical strategy for the synthesis of nanostructures. Science 254:1312–1319. doi:10.1126/science.1962191
Decher G (1997) Fuzzy nanoassemblies: toward layered polymeric multicomposites. Science 277:1232–1237. doi:10.1126/science.277.5330.1232
Hoeppener S, Maoz R, Cohen S, Chi L, Fuchs H, Sagiv J (2002) Metal nanoparticles, nanowires, and contact electrodes self-assembled on patterned monolayer templates: a bottom-up chemical approach. Adv Mater 14:1036–1041. doi:10.1002/1521-4095(20020805)14:15<1036::AID-ADMA1036>3.0.CO;2-J
Decher G, Hong JD, Schmitt J (1992) Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces. Thin Solid Films 210–211:831–835. doi:10.1016/0040-6090(92)90417-A
Blodgett KB (1935) Films built by depositing successive monomolecular layers on a solid surface. J Am Chem Soc 57:1007–1022
Langmuir I (1920) The mechanism of the surface phenomena of flotation. Trans Faraday Soc 15:62. doi:10.1039/tf9201500062
Langmuir I (1917) The constitution and fundamental properties of solids and liquids. II Liquids. 1. J Am Chem Soc 39:1848–1906. doi:10.1021/ja02254a006
Blodgett KB (1934) Monomolecular films of fatty acids on glass. J Am Chem Soc 56:495. doi:10.1021/ja01317a513
Petty MC (1996) Langmuir-Blodgett films. Cambridge University Press, Cambridge, UK
Roberts G (1990) Langmuir-Blodgett films. Plenum Press, New York
Tredgold RH (1994) Order in thin organic films. Cambridge University Press, Cambridge, UK
Ulman A (1991) An Introduction to organic ultrathin films from Langmuir-Blodgett to self-assembly. Academic, Boston
Oliveira Jr ON, He J-A, Zucolotto V, Balasubramanian S, Li L, Nalwa HS, Kumar J, Tripathy SK (2002) Layer-by-layer polyelectrolyte-based thin films for electronic and photonic applications. In: Kumar J, Tripathy SK, Nalwa HS (eds) Handbook of polyelectrolytes and their applications. American Scientific Publishers, Los Angeles, pp 1–33
Park JY, Advincula RC (2011) Nanostructuring polymers, colloids, and nanomaterials at the air–water interface through Langmuir and Langmuir–Blodgett techniques. Soft Matter 7:9829. doi:10.1039/c1sm05750b
Miyashita T (1993) Recent studies on functional ultrathin polymer films prepared by the Langmuir-Blodgett technique. Prog Polym Sci 18:263–294
Tredgold RH, Winter CS (1982) Langmuir–Blodgett monolayers of preformed polymers. J Phys D Appl Phys 15:L55–L58. doi:10.1088/0022-3727/15/6/003
Moon GD, Lee T II, Kim B, Chae G, Kim J, Kim S, Myoung J-M, Jeong U (2011) Assembled monolayers of hydrophilic particles on water surfaces. ACS Nano 5:8600–8612. doi:10.1021/nn202733f
Mitzi DB (2001) Thin-film deposition of organic − inorganic hybrid materials. Chem Mater 13:3283–3298. doi:10.1021/cm0101677
Girard-Egrot AP, Godoy S, Blum LJ (2005) Enzyme association with lipidic Langmuir-Blodgett films: interests and applications in nanobioscience. Adv Colloid Interface Sci 116:205–225. doi:10.1016/j.cis.2005.04.006
Sassolas A, Blum LJ, Leca-Bouvier BD (2012) Immobilization strategies to develop enzymatic biosensors. Biotechnol Adv 30:489–511. doi:10.1016/j.biotechadv.2011.09.003
Siqueira JR, Caseli L, Crespilho FN, Zucolotto V, Oliveira Jr ON (2010) Immobilization of biomolecules on nanostructured films for biosensing. Biosens Bioelectron 25:1254–1263. doi:10.1016/j.bios.2009.09.043
Brezesinski G, Möhwald H (2003) Langmuir monolayers to study interactions at model membrane surfaces. Adv Colloid Interface Sci 100–102:563–584. doi:10.1016/S0001-8686(02)00071-4
Netzer L, Sagiv J (1983) A new approach to construction of artificial monolayer assemblies. J Am Chem Soc 105:674–676. doi:10.1021/ja00341a087
Evans SD, Urankar E, Ulman A, Ferris N (1991) Self-assembled monolayers of alkanethiols containing a polar aromatic group: effects of the dipole position on molecular packing, orientation, and surface wetting properties. J Am Chem Soc 113:4121–4131. doi:10.1021/ja00011a010
Maoz R, Sagiv J (1987) Penetration-controlled reactions in organized monolayer assemblies. 2. Aqueous permanganate interaction with self-assembling monolayers of long-chain surfactants. Langmuir 3:1045–1051. doi:10.1021/la00078a028
Richer J, Stolberg L, Lipkowski J (1986) Quantitative investigations of adsorption of tert-amyl alcohol at the gold(110)-aqueous solution interface. Langmuir 2:630–638. doi:10.1021/la00071a019
Tillman N, Ulman A, Penner TL (1989) Formation of multilayers by self-assembly. Langmuir 5:101–111. doi:10.1021/la00085a019
Zhao X-M, Wilbur JL, Whitesides GM (1996) Using two-stage chemical amplification to determine the density of defects in self-assembled monolayers of alkanethiolates on gold. Langmuir 12:3257–3264. doi:10.1021/la960044e
Arya SK, Solanki PR, Datta M, Malhotra BD (2009) Recent advances in self-assembled monolayers based biomolecular electronic devices. Biosens Bioelectron 24:2810–7. doi:10.1016/j.bios.2009.02.008
Gooding JJ, Darwish N (2012) The rise of self-assembled monolayers for fabricating electrochemical biosensors–an interfacial perspective. Chem Rec 12:92–105. doi:10.1002/tcr.201100013
Booth MA, Vogel R, Curran JM, Harbison S, Travas-Sejdic J (2013) Detection of target-probe oligonucleotide hybridization using synthetic nanopore resistive pulse sensing. Biosens Bioelectron 45:136–40. doi:10.1016/j.bios.2013.01.044
Iler RK (1966) Multilayers of colloidal particles. J Colloid Interface Sci 21:569–594. doi:10.1016/0095-8522(66)90018-3
Lvov Y, Haas H, Decher G, Moehwald H, Kalachev A (1993) Assembly of polyelectrolyte molecular films onto plasma-treated glass. J Phys Chem 97:12835–12841. doi:10.1021/j100151a033
Lvov Y, Decher G, Moehwald H (1993) Assembly, structural characterization, and thermal behavior of layer-by-layer deposited ultrathin films of poly(vinyl sulfate) and poly(allylamine). Langmuir 9:481–486. doi:10.1021/la00026a020
Cassagneau T, Fendler JH (1999) Preparation and layer-by-layer self-assembly of silver nanoparticles capped by graphite oxide nanosheets. J Phys Chem B 103:1789–1793. doi:10.1021/jp984690t
Fendler JH (1996) Self-assembled nanostructured materials. Chem Mater 8:1616–1624. doi:10.1021/cm960116n
He J-A, Valluzzi R, Yang K, Dolukhanyan T, Sung C, Kumar J, Tripathy SK, Samuelson L, Balogh L, Tomalia DA (1999) Electrostatic multilayer deposition of a gold − dendrimer nanocomposite. Chem Mater 11:3268–3274. doi:10.1021/cm990311c
Balasubramanian S, Wang X, Wang HC, Yang K, Kumar J, Tripathy SK, Li L (1998) Azo chromophore-functionalized polyelectrolytes. 2. Acentric self-assembly through a layer-by-layer deposition process. Chem Mater 10:1554–1560. doi:10.1021/cm9707418
Tripathy SK, Katagi H, Kasai H, Balasubramanian S, Oshikiri H, Kumar J, Oikawa H, Okada S, Nakanishi H (1998) Self assembly of organic microcrystals 1: electrostatic attachment of polydiacetylene microcrystals on a polyelectrolyte surface. Jpn J Appl Phys 37:L343–L345. doi:10.1143/JJAP.37.L343
Fou AC, Onitsuka O, Ferreira M, Rubner MF, Hsieh BR (1996) Fabrication and properties of light-emitting diodes based on self-assembled multilayers of poly(phenylene vinylene). J Appl Phys 79:7501. doi:10.1063/1.362421
Wu A, Yoo D, Lee J-K, Rubner MF (1999) Solid-state light-emitting devices based on the tris-chelated ruthenium(II) complex: 3. High efficiency devices via a layer-by-layer molecular-level blending approach. J Am Chem Soc 121:4883–4891. doi:10.1021/ja9833624
Linford MR, Auch M, Möhwald H (1998) Nonmonotonic effect of ionic strength on surface dye extraction during dye − polyelectrolyte multilayer formation. J Am Chem Soc 120:178–182. doi:10.1021/ja972133z
Tedeschi C, Caruso F, Möhwald H, Kirstein S (2000) Adsorption and desorption behavior of an anionic pyrene chromophore in sequentially deposited polyelectrolyte-dye thin films. J Am Chem Soc 122:5841–5848. doi:10.1021/ja994029i
Caruso F, Möhwald H (1999) Protein multilayer formation on colloids through a stepwise self-assembly technique. J Am Chem Soc 121:6039–6046. doi:10.1021/ja990441m
He J-A, Samuelson L, Li L, Kumar J, Tripathy SK (1998) Oriented bacteriorhodopsin/polycation multilayers by electrostatic layer-by-layer assembly. Langmuir 14:1674–1679. doi:10.1021/la971336y
Lvov Y, Ariga K, Ichinose I, Kunitake T (1995) Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption. J Am Chem Soc 117:6117–6123. doi:10.1021/ja00127a026
Lvov Y, Ariga K, Kunitake T (1994) Layer-by-layer assembly of alternate protein/polyion ultrathin films. Chem Lett 23:2323–2326. doi:10.1246/cl.1994.2323
Oliveira Jr ON, Raposo M, Dhanabalan A (2011) Polymeric, Langmuir-Blodgett and self-assembled films. In: Nalwa HS (ed) Handbook of surfaces and interfaces of materials. Academic, San Diego, pp 1–63
Pavinatto FJ, Caseli L, Oliveira Jr ON (2010) Chitosan in nanostructured thin films. Biomacromolecules 11:1897–908. doi:10.1021/bm1004838
Izquierdo A, Ono SS, Voegel J-C, Schaaf P, Decher G (2005) Dipping versus spraying: exploring the deposition conditions for speeding up layer-by-layer assembly. Langmuir 21:7558–67. doi:10.1021/la047407s
Caruso F (2000) Hollow capsule processing through colloidal templating and self-assembly. Chem Eur J 6:413–419. doi:10.1002/(SICI)1521-3765(20000204)6:3<413::AID-CHEM413>3.0.CO;2-9
Wang Y, Angelatos AS, Caruso F (2008) Template synthesis of nanostructured materials via layer-by-layer assembly †. Chem Mater 20:848–858. doi:10.1021/cm7024813
Estephan ZG, Qian Z, Lee D, Crocker JC, Park S-J (2013) Responsive multidomain free-standing films of gold nanoparticles assembled by DNA-directed layer-by-layer approach. Nano Lett 13:4449–55. doi:10.1021/nl4023308
Raoufi M, Schönherr H (2014) Fabrication of complex free-standing nanostructures with concave and convex curvature via the layer-by-layer approach. Langmuir 30:1723–8. doi:10.1021/la500007x
Boudou T, Crouzier T, Ren K, Blin G, Picart C (2010) Multiple functionalities of polyelectrolyte multilayer films: new biomedical applications. Adv Mater 22:441–67. doi:10.1002/adma.200901327
Granicka LH (2014) Nanoencapsulation of cells within multilayer shells for biomedical applications. J Nanosci Nanotechnol 14:705–716. doi:10.1166/jnn.2014.9106
Skorb EV, Andreeva DV (2013) Layer-by-layer approaches for formation of smart self-healing materials. Polym Chem 4:4834. doi:10.1039/c3py00088e
Kerdjoudj H, Berthelemy N, Boulmedais F, Stoltz J-FJ-F, Menu P, Voegel JC (2010) Multilayered polyelectrolyte films: a tool for arteries and vessel repair. Soft Matter 6:3722. doi:10.1039/b920729e
De Temmerman M-L, Demeester J, De Smedt SC, Rejman J (2012) Tailoring layer-by-layer capsules for biomedical applications. Nanomedicine (Lond) 7:771–788. doi:10.2217/nnm.12.48
Wohl BM, Engbersen JFJ (2012) Responsive layer-by-layer materials for drug delivery. J Control Release 158:2–14. doi:10.1016/j.jconrel.2011.08.035
Yeagle PL (1993) The membranes of cells. Academic, San Diego
Krägel J, Derkatch SR (2010) Interfacial shear rheology. Curr Opin Colloid Interface Sci 15:246–255. doi:10.1016/j.cocis.2010.02.001
Hansen FK, Rødsrud G (1991) Surface tension by pendant drop. J Colloid Interface Sci 141:1–9. doi:10.1016/0021-9797(91)90296-K
Langevin D (2014) Rheology of adsorbed surfactant monolayers at fluid surfaces. Annu Rev Fluid Mech 46:47–65. doi:10.1146/annurev-fluid-010313-141403
Dynarowicz-Latka P, Dhanabalan A, Oliveira Jr ON (2001) Modern physicochemical research on Langmuir monolayers. Adv Colloid Interface Sci 91:221–293
Sadewasser S, Glatzel T (2012) Kelvin probe force microscopy. Springer Ser Surf Sci. doi:10.1007/978-3-642-22566-6
Dhanabalan A, Mello SV, Oliveira Jr ON (1998) Preparation of Langmuir − Blodgett films of soluble polypyrrole. Macromolecules 31:1827–1832. doi:10.1021/ma970606g
Helmholtz H (1902) Abhandlungen zur thermodynamik. 51
Demchak RJ, Fort T (1974) Surface dipole moments of close-packed un-ionized monolayers at the air-water interface. J Colloid Interface Sci 46:191–202. doi:10.1016/0021-9797(74)90002-2
Oliveira Jr ON, Taylor DM, Lewis TJ, Salvagno S, Stirling CJM (1989) Estimation of group dipole moments from surface potential measurements on Langmuir monolayers. J Chem Soc Faraday Trans 1 Phys Chem Condens Phases 85:1009. doi:10.1039/f19898501009
Oliveira Jr ON, Taylor DM, Morgan H (1992) Modelling the surface potential-area dependence of a stearic acid monolayer. Thin Solid Films 210–211:76–78. doi:10.1016/0040-6090(92)90172-8
Adamson AW (1967) Physical chemistry of surfaces. Wiley, New York
Taylor DM, Oliveira Jr ON, Morgan H (1989) The surface potential of monolayers formed on weak acidic electrolytes: implications for lateral conduction. Chem Phys Lett 161:147–150. doi:10.1016/0009-2614(89)85047-X
Brown JQ, McShane MJ (2005) Core-referenced ratiometric fluorescent potassium ion sensors using self-assembled ultrathin films on europium nanoparticles. IEEE Sens J 5:1197–1205. doi:10.1109/JSEN.2005.859252
Shi W, Lin Y, Kong X, Zhang S, Jia Y, Wei M, Evans DG, Duan X (2011) Fabrication of pyrenetetrasulfonate/layered double hydroxide ultrathin films and their application in fluorescence chemosensors. J Mater Chem 21:6088. doi:10.1039/c1jm00073j
Stubbe BG, Gevaert K, Derveaux S, Braeckmans K, De Geest BG, Goethals M, Vandekerckhove J, Demeester J, De Smedt SC (2008) Evaluation of encoded layer-by-layer coated microparticles as protease sensors. Adv Funct Mater 18:1624–1631. doi:10.1002/adfm.200701356
Hénon S, Meunier J (1991) Microscope at the Brewster angle: direct observation of first-order phase transitions in monolayers. Rev Sci Instrum 62:936. doi:10.1063/1.1142032
Honig D, Mobius D (1991) Direct visualization of monolayers at the air-water interface by Brewster angle microscopy. J Phys Chem 95:4590–4592. doi:10.1021/j100165a003
Weidemann G, Brezesinski G, Vollhardt D, Möhwald H (1998) Disorder in Langmuir monolayers. 1. Disordered packing of alkyl chains. Langmuir 14:6485–6492. doi:10.1021/la980188o
Popovitz-Biro R, Edgar R, Weissbuch I, Lavie R, Cohen S, Kjaer K, Als-Nielsen J, Wassermann E, Leiserowitz L, Lahav M (1998) Structural studies on Langmuir films of C50H102, nylon-6,6 polymer and its oligomeric analogue. Acta Polym 49:626–635. doi:10.1002/(SICI)1521-4044(199810)49:10/11<626::AID-APOL626>3.0.CO;2-8
Zhou X-L, Chen S-H (1995) Theoretical foundation of X-ray and neutron reflectometry. Phys Rep 257:223–348. doi:10.1016/0370-1573(94)00110-O
Kago K, Fürst M, Matsuoka H, Yamaoka H, Seki T (1999) Direct observation of photoisomerization of a polymer monolayer on a water surface by X-ray reflectometry. Langmuir 15:2237–2240. doi:10.1021/la981084g
Li ZX, Bain CD, Thomas RK, Duffy DC, Penfold J (1998) Monolayers of hexadecyltrimethylammonium p -tosylate at the air − water interface. 2. Neutron reflection. J Phys Chem B 102:9473–9480. doi:10.1021/jp9821432
Blaudez D, Buffeteau T, Cornut JC, Desbat B, Escafre N, Pezolet M, Turlet JM (1993) Polarization-modulated FT-IR spectroscopy of a spread monolayer at the air/water interface. Appl Spectrosc 47:869–874
Shultz MJ, Baldelli S, Schnitzer C, Simonelli D (2002) Aqueous solution/air interfaces probed with sum frequency generation spectroscopy. J Phys Chem B 106:5313–5324. doi:10.1021/jp014466v
Greenler RG (1966) Infrared study of adsorbed molecules on metal surfaces by reflection techniques. J Chem Phys 44:310. doi:10.1063/1.1726462
Golden W (1981) A method for measuring infrared reflection? Absorption spectra of molecules adsorbed on low-area surfaces at monolayer and submonolayer concentrations. J Catal 71:395–404. doi:10.1016/0021-9517(81)90243-8
Lambert AG, Davies PB, Neivandt DJ (2005) Implementing the theory of sum frequency generation vibrational spectroscopy: a tutorial review. Appl Spectrosc Rev 40:103–145. doi:10.1081/ASR-200038326
Williams CT, Beattie DA (2002) Probing buried interfaces with non-linear optical spectroscopy. Surf Sci 500:545–576. doi:10.1016/S0039-6028(01)01536-9
Volpati D, Aoki PHB, Alessio P, Pavinatto FJ, Miranda PB, Constantino CJL, Oliveira Jr ON (2014) Vibrational spectroscopy for probing molecular-level interactions in organic films mimicking biointerfaces. Adv Colloid Interface Sci 207C:199–215. doi:10.1016/j.cis.2014.01.014
Miranda PB, Du Q, Shen YR (1998) Interaction of water with a fatty acid Langmuir film. Chem Phys Lett 286:1–8. doi:10.1016/S0009-2614(97)01476-0
Nicholson GL (2014) The fluid-mosaic model of membrane structure: still relevant to understanding the structure, function and dynamics of biological membranes after more than 40 years. Biochim Biophys Acta 1838:1451–1466. doi:10.1016/j.bbamem.2013.10.019
Jones MN, Chapman D (1994) Micelles, monolayers and biomembranes. Wiley-Liss, New York
Berkowitz ML, Vácha R (2012) Aqueous solutions at the interface with phospholipid bilayers. Acc Chem Res 45:74–82. doi:10.1021/ar200079x
Blume A, Kerth A (2013) Peptide and protein binding to lipid monolayers studied by FT-IRRA spectroscopy. Biochim Biophys Acta 1828:2294–305. doi:10.1016/j.bbamem.2013.04.014
Chattoraj DK, Birdi KS (1984) Adsorption and the Gibbs surface excess. Springer, New York, pp 219–223
Galvez Ruiz MJ, Cabrerizo Vilchez MA (1991) A study of the miscibility of bile components in mixed monolayers at the air-liquid interface I. Cholesterol, lecithin, and lithocholic acid. Colloid Polym Sci 269:77–84. doi:10.1007/BF00654662
Caetano W, Ferreira M, Tabak M, Mosquera Sanchez MI, Oliveira Jr ON, Krüger P, Schalke M, Lösche M (2001) Cooperativity of phospholipid reorganization upon interaction of dipyridamole with surface monolayers on water. Biophys Chem 91:21–35. doi:10.1016/S0301-4622(01)00145-4
Hidalgo AA, Caetano W, Tabak M, Oliveira Jr ON (2004) Interaction of two phenothiazine derivatives with phospholipid monolayers. Biophys Chem 109:85–104. doi:10.1016/j.bpc.2003.10.020
Moraes ML, Bonardi C, Mendonça CR, Campana PT, Lottersberger J, Tonarelli G, Oliveira Jr ON, Beltramini LM (2005) Cooperative effects in phospholipid monolayers induced by a peptide from HIV-1 capsid protein. Colloids Surf B Biointerfaces 41:15–20. doi:10.1016/j.colsurfb.2004.10.026
Pickholz M, Oliveira Jr ON, Skaf MS (2006) Molecular dynamics simulations of neutral chlorpromazine in zwitterionic phospholipid monolayers. J Phys Chem B 110:8804–14. doi:10.1021/jp056678o
Torrano AA, Pereira ÂS, Oliveira Jr ON, Barros-Timmons A (2013) Probing the interaction of oppositely charged gold nanoparticles with DPPG and DPPC Langmuir monolayers as cell membrane models. Colloids Surf B Biointerfaces 108:120–6. doi:10.1016/j.colsurfb.2013.02.014
Caseli L, Pavinatto FJ, Nobre TM, Zaniquelli MED, Viitala T, Oliveira Jr ON (2008) Chitosan as a removing agent of beta-lactoglobulin from membrane models. Langmuir 24:4150–6. doi:10.1021/la7038762
Casal E, Montilla A, Moreno FJ, Olano A, Corzo N (2006) Use of chitosan for selective removal of β-lactoglobulin from whey. J Dairy Sci 89:1384–1389
Damalio JCP, Nobre TM, Lopes JL, Oliveira Jr ON, Araújo APU (2013) Lipid interaction triggering Septin2 to assembly into β-sheet structures investigated by Langmuir monolayers and PM-IRRAS. Biochim Biophys Acta 1828:1441–8. doi:10.1016/j.bbamem.2013.02.003
vanden Akker CC, Engel MFM, Velikov KP, Bonn M, Koenderink GH (2011) Morphology and persistence length of amyloid fibrils are correlated to peptide molecular structure. J Am Chem Soc 133:18030–3. doi:10.1021/ja206513r
Riul A, Dantas CAR, Miyazaki CM, Oliveira Jr ON (2010) Recent advances in electronic tongues. Analyst 135:2481–95. doi:10.1039/c0an00292e
Toko K (1996) Taste sensor with global selectivity. Mater Sci Eng C 4:69–82. doi:10.1016/0928-4931(96)00134-8
Dulac C (2000) The physiology of taste, vintage 2000. Cell 100:607–610. doi:10.1016/S0092-8674(00)80697-2
Riul A, dos Santos DS, Wohnrath K, Di Tommazo R, Carvalho ACPLF, Fonseca FJ, Oliveira Jr ON, Taylor DM, Mattoso LHC (2002) Artificial taste sensor: efficient combination of sensors made from Langmuir − Blodgett films of conducting polymers and a ruthenium complex and self-assembled films of an azobenzene-containing polymer. Langmuir 18:239–245. doi:10.1021/la011017d
Taylor DM, Macdonald AG (1987) AC admittance of the metal/insulator/electrolyte interface. J Phys D Appl Phys 20:1277
Gorban AN, Kégl B, Wunsch DC, Zinovyev A (2007) Principal manifolds for data visualisation and dimension reduction. Springer, Berlin
Ferreira M, Riul A, Wohnrath K, Fonseca FJ, Oliveira Jr ON, Mattoso LHC (2003) High-performance taste sensor made from Langmuir − Blodgett films of conducting polymers and a ruthenium complex. Anal Chem 75:953–955. doi:10.1021/ac026031p
Dos Santos DS, Riul A, Malmegrim RR, Fonseca FJ, Oliveira Jr ON, Mattoso LHC (2003) A layer-by-layer film of chitosan in a taste sensor application. Macromol Biosci 3:591–595. doi:10.1002/mabi.200350027
Liu M, Wang J, Li D, Wang M (2012) Electronic tongue coupled with physicochemical analysis for the recognition of orange beverages. J Food Qual 35:429–441. doi:10.1111/jfq.12004
Winquist F, Bjorklund R, Krantz-Rülcker C, Lundström I, Östergren K, Skoglund T (2005) An electronic tongue in the dairy industry. Sens Actuators B Chem 111–112:299–304. doi:http://dx.doi.org/10.1016/j.snb.2005.05.003
Riul A, Gallardo Soto AM, Mello SVV, Bone S, Taylor DMM, Mattoso LHC (2003) An electronic tongue using polypyrrole and polyaniline. Synth Met 132:109–116. doi:10.1016/S0379-6779(02)00107-8
Wiziack NKL, Paterno LG, Fonseca FJ, Mattoso LHC (2007) Effect of film thickness and different electrode geometries on the performance of chemical sensors made of nanostructured conducting polymer films. Sens Actuators B 122:484–492. doi:10.1016/j.snb.2006.06.016
Borato CE, Leite FL, Mattoso LHC, Goy RC, Filho SPC, de Vasconcelos CL, da Trindade Neto CG, Pereira MP, Fonseca JLC, Oliveira Jr ON (2006) Layer-by-layer films of poly(o-ethoxyaniline), chitosan and chitosan-poly(methacrylic acid) nanoparticles and their application in an electronic tongue. IEEE Trans Dielectr Electr Insul 13:1101–1109. doi:10.1109/TDEI.2006.247838
Brugnollo ED, Paterno LG, Leite FL, Fonseca FJ, Constantino CJL, Antunes PA, Mattoso LHC (2008) Fabrication and characterization of chemical sensors made from nanostructured films of poly(o-ethoxyaniline) prepared with different doping acids. Thin Solid Films 516:3274–3281. doi:10.1016/j.tsf.2007.08.118
Volpati D, Alessio P, Zanfolim AA, Storti FC, Job AE, Ferreira M, Riul A, Oliveira Jr ON, Constantino CJL (2008) Exploiting distinct molecular architectures of ultrathin films made with iron phthalocyanine for sensing. J Phys Chem B 112:15275–82. doi:10.1021/jp804159h
Ferreira EJ, Pereira RCT, Delbem ACB, Oliveira Jr ON, Mattoso LHC (2007) Random subspace method for analysing coffee with electronic tongue. Electron Lett 43:1138. doi:10.1049/el:20071182
Zucolotto V, Daghastanli KRP, Hayasaka CO, Riul A, Ciancaglini P, Oliveira Jr ON (2007) Using capacitance measurements as the detection method in antigen-containing layer-by-layer films for biosensing. Anal Chem 79:2163–7. doi:10.1021/ac0616153
Such GK, Johnston APR, Caruso F (2011) Engineered hydrogen-bonded polymer multilayers: from assembly to biomedical applications. Chem Soc Rev 40:19–29. doi:10.1039/c0cs00001a
Takahashi S, Sato K, Anzai J (2012) Layer-by-layer construction of protein architectures through avidin-biotin and lectin-sugar interactions for biosensor applications. Anal Bioanal Chem 402:1749–58. doi:10.1007/s00216-011-5317-4
Vannoy CH, Tavares AJ, Noor MO, Uddayasankar U, Krull UJ (2011) Biosensing with quantum dots: a microfluidic approach. Sensors (Basel) 11:9732–63. doi:10.3390/s111009732
Yan Y, Björnmalm M, Caruso F (2014) Assembly of layer-by-layer particles and their interactions with biological systems. Chem Mater 26:452–460. doi:10.1021/cm402126n
Caseli L, Crespilho FN, Nobre TM, Zaniquelli MED, Zucolotto V Jr, Oliveira Jr ON (2008) Using phospholipid Langmuir and Langmuir–Blodgett films as matrix for urease immobilization. J Colloid Interface Sci 319:100–108, doi:http://dx.doi.org/10.1016/j.jcis.2007.12.007
Caseli L, Moraes ML, Zucolotto V, Ferreira M, Nobre TM, Zaniquelli MED, Rodrigues Filho UP, Oliveira Jr ON (2006) Fabrication of phytic acid sensor based on mixed phytase − lipid Langmuir − Blodgett films. Langmuir 22:8501–8508. doi:10.1021/la061799g
Pavinatto FJ, Fernandes EGR, Alessio P, Constantino CJL, de Saja JA, Zucolotto V, Apetrei C, Oliveira Jr ON, Rodriguez-Mendez ML (2011) Optimized architecture for tyrosinase-containing Langmuir–Blodgett films to detect pyrogallol. J Mater Chem 21:4995. doi:10.1039/c0jm03864d
Lu F, Tian Y, Liu M, Su D, Zhang H, Govorov AO, Gang O (2013) Discrete nanocubes as plasmonic reporters of molecular chirality. Nano Lett 13:3145–51. doi:10.1021/nl401107g
Srivastava S, Kotov NA (2008) Composite layer-by-layer (LBL) assembly with inorganic nanoparticles and nanowires. Acc Chem Res 41:1831–41. doi:10.1021/ar8001377
Manickam A, Johnson CA, Kavusi S, Hassibi A (2012) Interface design for CMOS-integrated Electrochemical Impedance Spectroscopy (EIS) biosensors. Sensors (Basel) 12:14467–14488. doi:10.3390/s121114467
Marzo FF, Pierna AR, Barranco J, Lorenzo A, Barroso J, García JA, Pérez A (2008) Determination of trace metal release during corrosion characterization of FeCo-based amorphous metallic materials by stripping voltammetry. New materials for GMI biosensors. J Non Cryst Solids 354:5169–5171. doi:10.1016/j.jnoncrysol.2008.08.014
Caseli L, dos Santos DS, Foschini M, Gonçalves D, Oliveira Jr ON (2006) The effect of the layer structure on the activity of immobilized enzymes in ultrathin films. J Colloid Interface Sci 303:326–31. doi:10.1016/j.jcis.2006.07.013
Ferreira M, Fiorito PA, Oliveira Jr ON, Córdoba de Torresi SI (2004) Enzyme-mediated amperometric biosensors prepared with the Layer-by-Layer (LbL) adsorption technique. Biosens Bioelectron 19:1611–5. doi:10.1016/j.bios.2003.12.025
Crespilho FN, Emilia Ghica M, Florescu M, Nart FC, Oliveira Jr ON, Brett CMA (2006) A strategy for enzyme immobilization on layer-by-layer dendrimer–gold nanoparticle electrocatalytic membrane incorporating redox mediator. Electrochem Commun 8:1665–1670. doi:10.1016/j.elecom.2006.07.032
De Oliveira RF, de Moraes ML, Oliveira Jr ON, Ferreira M (2011) Exploiting cascade reactions in bienzyme layer-by-layer films. J Phys Chem C 115:19136–19140. doi:10.1021/jp207610w
Perinoto ÂC, Maki RM, Colhone MC, Santos FR, Migliaccio V, Daghastanli KR, Stabeli RG, Ciancaglini P, Paulovich FV, de Oliveira MCF, Oliveira Jr ON, Zucolotto V (2010) Biosensors for efficient diagnosis of leishmaniasis: innovations in bioanalytics for a neglected disease. Anal Chem 82:9763–8. doi:10.1021/ac101920t
Siqueira JR, Abouzar MH, Poghossian A, Zucolotto V, Oliveira Jr ON, Schöning MJ (2009) Penicillin biosensor based on a capacitive field-effect structure functionalized with a dendrimer/carbon nanotube multilayer. Biosens Bioelectron 25:497–501. doi:10.1016/j.bios.2009.07.007
Siqueira JR, Werner CF, Bäcker M, Poghossian A, Zucolotto V, Oliveira Jr ON, Schöning MJ (2009) Layer-by-layer assembly of carbon nanotubes incorporated in light-addressable potentiometric sensors. J Phys Chem C 113:14765–14770. doi:10.1021/jp904777t
Oliveira Jr ON, Iost RM, Siqueira JR, Crespilho FN, Caseli L (2014) Nanomaterials for diagnosis: challenges and application in smart devices based on molecular recognition. ACS Appl Mater Interfaces. doi:10.1021/am5015056
Siqueira JR, Maki RM, Paulovich FV, Werner CF, Poghossian A, de Oliveira MCF, Zucolotto V, Oliveira Jr ON, Schöning MJ (2010) Use of information visualization methods eliminating cross talk in multiple sensing units investigated for a light-addressable potentiometric sensor. Anal Chem 82:61–5. doi:10.1021/ac9024076
De Oliveira MCF, Levkowitz H (2003) From visual data exploration to visual data mining: a survey. IEEE Trans Vis Comput Graph 9:378–394. doi:10.1109/TVCG.2003.1207445
Paulovich FV, Maki RM, de Oliveira MCF, Colhone MC, Santos FR, Migliaccio V, Ciancaglini P, Perez KR, Stabeli RG, Perinoto AC, Oliveira Jr ON, Zucolotto V (2011) Using multidimensional projection techniques for reaching a high distinguishing ability in biosensing. Anal Bioanal Chem 400:1153–9. doi:10.1007/s00216-011-4853-2
Sammon JW (1969) A nonlinear mapping for data structure analysis. IEEE Trans Comput C-18:401–409. doi:10.1109/T-C.1969.222678
Paulovich FV, Moraes ML, Maki RM, Ferreira M, Oliveira Jr ON, de Oliveira MCF (2011) Information visualization techniques for sensing and biosensing. Analyst 136:1344–50. doi:10.1039/c0an00822b
Aoki PHB, Carreon EGE, Volpati D, Shimabukuro MH, Constantino CJL, Aroca RF, Oliveira Jr ON, Paulovich FV (2013) SERS mapping in Langmuir-Blodgett films and single-molecule detection. Appl Spectrosc 67:563–9. doi:10.1366/12-06909
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The authors acknowledge the financial support from FAPESP, CNPq, CAPES and nBioNet network (Brazil).
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Oliveira, O.N., Pavinatto, F.J., Balogh, D.T. (2015). Fundamentals and Applications of Organised Molecular Films. In: Bardosova, M., Wagner, T. (eds) Nanomaterials and Nanoarchitectures. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9921-8_10
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