Abstract
Quantitative X-Ray Diffraction (XRD) analysis was performed on 82 samples spanning the Green River Formation in the Piceance Creek Basin of Colorado. Samples represented basin margin (outcrop sections in Douglas Pass), and basin center (Savage 24-1 and Shell 23X-2 core) depositional environments. Bulk mineralogy is integrated into a stratigraphic framework of lake stages, incorporating variations in organic richness. Twenty-eight Douglas Pass samples consist of argillaceous, siliceous, feldspathic and dolomitic mudstone and siltstone composed predominantly of clay minerals, quartz, carbonate minerals, feldspar, and analcime. Fifteen Shell 23X-2 well samples cover the lower third of the basin center section. Data for 35 additional Shell 23-X2 samples from the U. S. Geological Survey core database were added to the dataset. The lower 24 Shell 23-X2 samples consist of argillaceous and siliceous mudstone and siltstone composed of clay minerals, carbonate minerals, quartz, feldspar and dawsonite. The upper 26 samples overlap the lower John Savage well section. Thirty-nine Savage 24-1 well samples cover the upper 2/3 of the basin center section. With the upper part of the Shell 23-X2 well samples, they consist of feldspathic and dolomitic mudstone and siltstone composed of feldspar, carbonate minerals, quartz, nahcolite [NahCO3], dawsonite [NaAl(OH)2(CO3)], and clay minerals. Buddingtonite [(NH4)AlSi3O8•0.5H2O] comprises a significant fraction of the feldspar.
Overall, basin center samples are clay-poor (6 %), and organic matter-rich (12 %), whereas basin margin samples are clay-rich (22 %), with more diverse clay types, and less organic matter (7 %). Divalent carbonates are dominantly dolomite-ankerite, with calcite essentially absent in the middle basin center, but commonly present in the basin margin section. Buddingtonite, nahcolite, dawsonite, and halite (NaCl) are common in the basin center, but sparse to absent in the basin margin, whereas analcime (NaAlSi2O6•H2O) is abundant in the basin margin (max 37 %), and sparse in the basin center.
Changes in mineralogy are related to lake stages (as defined by Tanavsuu-Milkeviciene and Sarg 2012), including a sharp reduction in clay and increase in authigenic dawsonite and feldspar content during Stage 2 (transitional lake), and a fall in quartz and dawsonite near the end of Stage 3 (rapidly fluctuating lake) in the basin center. These changes are attributed to reactions controlled by variations in salinity, alkalinity, pH, and silica concentration. Halite and nahcolite reflect saturation in the deep lake center. Differences between basin margin and center likely reflect varying lake levels but persistent stratification of the lake throughout most of its history. Mineralogic variations in the Green River Formation have relevance to other organic-rich shale and mudstone formations in lacustrine and potentially even in marine environments where organic matter preservation is enhanced by water column stratification.
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References
Bader JW (2009) Structural and tectonic evolution of the Douglas Creek arch, the Douglas Creek fault zone, and environs, northwestern Colorado and northeastern Utah: implications for petroleum accumulation in the Piceance and Uinta basins. Rocky Mt Geol 44(2):121–145
Baughman G (1978) Synthetic fuels data handbook. Cameron Engineers, Denver, 438 pp
Bradley WH (1925) A contribution to the origin of the Green River Formation and its oil shale. Am Assoc Pet Geol Bull 9:247–262
Bradley WH (1929) The varves and climate of the Green River epoch, U.S. Geological survey professional paper 158-E. U.S. Government Printing Office, Washington, DC, pp 87–110
Bradley WH (1931) Origin and microfossils of the oil shale of the Green River Formation of Colorado and Utah. U.S. Geological survey professional paper 168. U.S. Government Printing Office, Washington, DC, 58 p
Bradley WH (1964) Geology of Green River Formation and associated Eocene rocks in southwestern Wyoming and adjacent parts of Colorado and Utah, U.S. Geological Survey professional paper 496-A. U.S. Government Printing Office, Washington, DC, pp 1–86
Brobst DA, Tucker JD (1973) X-ray mineralogy of the Parachute Creek Member, Green River Formation, in the Northern Piceance Creek Basin, Colorado. U. S. Geological Survey professional paper 803. U.S. Government Printing Office, Washington, DC, 53 pp
Cashion WB, Donnell JR (1972) Chart showing correlation of selected key units in the organic-rich sequence of the Green River Formation, Piceance Creek Basin, Colorado, and Uinta Basin, Utah. U.S. Geological Survey, oil and gas investigations, Chart OC-65, U.S. Geological Survey, Washington, DC
Cashion WB, Donnell JR (1974) Revision of nomenclature of the upper part of the Green River Formation, Piceance Creek Basin, Colorado, and Eastern Uinta Basin, Utah. U.S. Geological Survey Bulletin, 1394-G. U.S. Government Printing Office, Washington, DC, 9 p
Chalmers GRL, Bustin RM (2012) Geological evaluation of Halfway – Doig – Montney hybrid gas shale – tight gas reservoir, northeastern British Columbia. Mar Pet Geol 38:53–72
Cole RD, Picard MD (1978) Comparative mineralogy of nearshore and offshore lacustrine lithofacies, Parachute Creek Member of the Green River Formation, Piceance Creek Basin, Colorado, and eastern Uinta Basin, Utah. Geol Soc Am Bull 89:1441–1454
Desborough GA (1978) A biogenic-chemical stratified lake model for the origin of oil shale of the Green River Formation: an alternative to the playa-lake model. Geol Soc Am Bull 89:961–971
Desborough GA, Pitman JK (1974) Significance of applied mineralogy to oil shale in the upper part of Parachute Creek Member of the Green River Formation, Piceance Creek Basin, Colorado. In Murray DK (ed) Energy resources of the Piceance Creek Basin, Colorado: Rocky Mountain Association of Geologists, 35th annual field conference guidebook, pp 81–89
Dean WE, Pitman JK, Harrach GH (1981) Geochemical and mineralogical analyses of U.S. Geologic Survey Oil Shale Core CR-2, Piceance Creek Basin, Colorado. U.S. Geological Survey open file report 81–596. The Survey, Reston
Donnell JR, Blair RW Jr (1970) Resource appraisal of three rich oil-shale zones in the Green River Formation, Piceance Creek basin, Colorado. In Gary JH (ed) Synthetic liquid fuels from oil shale, tar sands, and coal, A symposium. Colo Sch Mines Q 65(4):73–87
Eugster HP, Hardie LA (1978) Saline lakes. In: Lerman A (ed) Lakes: chemistry, geology, and physics. Springer, New York, pp 237–293
Eugster HP, Jones BF (1979) Behavior of major solutes during closed-basin brine evolution. Am J Sci 279:609–631
Eugster HP, Surdam RC (1973) Depositional environment of the Green River Formation of Wyoming: a preliminary report. Geol Soc Am Bull 84:1115–1120
Feng J (2011) Source rock characterization of the Green River oil shale, Piceance Creek Basin, Colorado. MSc thesis, Colorado School of Mines, Golden CO, 84 pp
Garrels RM, Christ CL (1965) Solutions, minerals, and equilibria. Harper and Row, New York, 450 pp
Hillier S (2006) Appendix A. Mineralogical and chemical data. In: Reeves GM, Sims I, Cripps JC (eds) Clay materials used in construction, vol 21, Geological society, engineering geology special publications. Geological Society of London, London, pp 449–459
Hite RJ, Dyni JR (1967) Potential resources of dawsonite and nahcolite in the Piceance Creek Basin, northwest Colorado. In Symposium on oil shale, 4th, Colo Sch Mines Q 62(3):25–38
Holland HD (1978) The chemistry of the atmosphere and oceans. Wiley, New York, p 170
Jagniecki EA, Jenkins DM, Lowenstein TK, Carroll AR (2013) Experimental study of shortite (Na2Ca2(CO3)3) formation and application to the burial history of the Wilkins Peak Member, Green River Basin, Wyoming, USA. Geochim Cosmochim Acta 115:31–45
Jagniecki EA, Lowenstein TK (2015) Evaporites of the Green River Formation, Bridger and Piceance Creek Basins: deposition, diagenesis, paleobrine chemistry, and eocene atmospheric CO2. In: Stratigraphy and paleolimnology of the Green River Formation, Western U.S. Springer, Dordrecht, pp 277–312
Johnson RC, Mercier TJ, Brownfield ME, Pantea MP, Self JG (2010) An assessment of in-place oil shale resources in the Green River Formation, Piceance Basin, Colorado. U.S. Geological Survey, Digital data series, DDS-69-Y(Chp. 1). U.S. Geological Survey, Reston, 187
Katz B (1988) Clastic and carbonate lacustrine systems: an organic geochemical comparison (Green River Formation and East African lake sediments). In: Fleet AJ, Kelts K, Talbot MR (eds) Lacustrine petroleum source rocks, Geological society special publication 40. Blackwell, London, pp 81–90
Krause FF, Wiseman AC, Williscroft KR, Solano N, Morris NJ, Meyer R, Marr R (2011) The Montney Formation: mineralogy, what shall it be? Canadian Society of Petroleum Geologists Convention. http://www.cspg.org/documents/Conventions/Archives/Annual/2011/232-The_Montney_Formation.pdf. Downloaded 6 Nov 2012
LaClair D, Lowenstein TK (2009) Fluid inclusion microthermometry from halite in the Eocene Green River Formation, Piceance Creek Basin, Colorado, USA: evidence for a perennial stratified Saline Lake. Geological Society of America Annual Meeting, Portland, OR, 18–21 Oct 2009, Abstracts with Programs, Vol. 41 no. 7
LaClair D, Lowenstein TK (2010) Using microthermometry and laser Raman Spectroscopy and evaporites to reconstruct the paleoclimate of the Eocene Green River Formation, Colorado, USA. 10th biennial pan-American current research on fluid inclusions conference, Las Vegas, Nevada, 7–10 June 2010
Mason GM (2009) Eocene age fossilized filamentous bacteria: new evidence suggesting a bacterial genesis of siderite in the Green River Formation, Wyoming. In: Proceedings of the 28th oil shale symposium, Colorado Energy Research Institute Document CERI-2009-2, Colorado School of Mines, Golden, Colorado
Mason GM, Surdam RC (1992) Carbonate mineral distribution and isotope fractionation: an approach to depositional environment interpretation, Green River Formation, Wyoming, U.S.A. Chem Geol 101:311–321
Milton C, Fahey J (1960) Classification and association of the carbonate minerals of the Green River Formation. Am J Sci (Bradley Volume) 258-A:242–246
Milton C (1961) Section of geological sciences: mineralogy and petrology of the Green River Formation of Wyoming, Utah, and Colorado. Trans N Y Acad Sci 23:561–567. doi:10.1111/j.2164-0947.1961.tb01388.x
Murray DK, Haun JD (1974) Introduction to the geology of the Piceance Creek Basin and vicinity, northwestern Colorado. In: Murray DK (ed) Energy resources of the Piceance Creek Basin, Colorado: Rocky Mountain Association Geologists, 25th annual field conference guidebook, pp 29–39
Oh MS, Foster KG, Alcaraz A, Crawford RW, Taylor RW, Coburn TT (1993) Thermal decomposition of buddingtonite in oil shales. Fuel 72(4):517–523
Omotoso O, Mccarty DK, Hillier S, Kleeberg R (2006) Some successful approaches to quantitative mineral analysis as revealed by the 3rd Reynolds Cup Contest. Clay Clay Miner 54(6):748–760
Picard MD (1955) Subsurface stratigraphy and lithology of the Green River Formation in the Uinta Basin, Utah. Am Assoc Pet Geol Bull 39:75–102
Poole S (2014) Mineralogy of the Green River Formation, Piceance Creek Basin, Colorado. MSc thesis, Colorado School of Mines, Golden CO
Ramseyer K, Diamond L, Boles JR (1993) Authigenic K-NH4 feldspar in sandstones; a fingerprint of the diagenesis of organic matter. J Sediment Petrol 63:1092–1099
Remy RR, Ferrell RE (1989) Distribution and origin of analcime in marginal lacustrine mudstones of the Green River Formation, South-Central Uinta Basin, Utah. Clay Clay Miner 37(5):419–432
Robb WA, Smith JW (1974) Mineral profile of oil shales in Colorado Core Hole No. 1, Piceance Creek basin, Colorado. In Murray DK (ed) Energy Resources of the Piceance Creek Basin, Colorado; 25th Field Conference, Rocky Mountain Association of Geologists, Denver CO
Roehler HW (1974) Depositional environments of Eocene rocks in the Piceance Creek Basin, Colorado. In: Murray DK (ed) Energy resources of the Piceance Creek Basin, 25th annual field conference guidebook. Rocky Mountain Association of Geologists, Denver, pp 57–64
Smith JW (1974) Geochemistry of oil-shale genesis in Colorado’s Piceance Creek Basin. In: Murray DK (ed) Energy resources of the Piceance Creek Basin, 25th annual field conference guidebook. Rocky Mountain Association of Geologists, Denver, pp 71–79
Smith JW (1983) The chemistry that formed the Green River Formation oil shale. In: Miknis FP, McKay JF (eds) Geochemistry of oil shales, American chemical society symposium series 230. American Chemical Society, Washington, DC, pp 225–248
Smith JW, Milton C (1966) Dawsonite in the Green River Formation of Colorado. Econ Geol 61:1029–1042
Smith JW, Robb WA (1966) Ankerite in the Green River Formation’s Mahogany zone. J Sediment Petrol 36(2):486–490
Smith JW, Robb WA (1973) Aragonite and the genesis of carbonates in Mahogany zone oil shales of Colorado’s Green River Formation, U. S. Bureau of Mines Report of .Investigations 7727. U.S. Dept. of Interior, Bureau of Mines, Washington, DC, 21pp
Surdam RC, Stanley KO (1979) Lacustrine sedimentation during the culminating phase of Eocene Lake Gosiute, Wyoming (Green River Formation). Geol Soc Am Bull 90:93–110
Surdam RC, Stanley KO (1980) Effects of changes in drainage- basin boundaries on sedimentation in Eocene Lakes Gosiute and Uinta of Wyoming, Utah, and Colorado. Geology 8:135–139
Srodon J (1999) Nature of mixed-layer clays and mechanisms of their formation and alteration. Annu Rev Earth Planet Sci 27:19–53
Suriamin H (2010) Facies, diagenesis, and geochemistry of the Eocene Green River Formation carbonates in the Piceance Creek Basin, Colorado. MSc. Thesis, Colorado School of Mines, Golden, CO, 108 pp
Svensen H, Bebout G, Kronz A, Li L, Planke S, Chevallier L, Jamtveit B (2008) Nitrogen geochemistry as a tracer of fluid flow in a hydrothermal vent complex in the Karoo Basin, South Africa. Geochim Cosmochim Acta 72:4929–4947
Taft WH, Harbaugh JW (1964) Modern carbonate sediments of southern Florida, Bahamas, and Espiritu Santo Island: Baja, California, vol 8, Stanford university publications, geological sciences. School of Earth Sciences, Stanford University, Stanford, pp 1–133
Tanavsuu-Milkeviciene K, Sarg JF (2012) Evolution of an organic-rich lake basin – stratigraphy, climate and tectonics: Piceance Creek basin, Eocene Green River Formation. Sedimentology 59(6):1735–1768
Tanavsuu-Milkeviciene K, Sarg JF (2015) Sedimentology of the world class organic-rich lacustrine system, Piceance basin, Colorado. In: Stratigraphy and paleolimnology of the Green River Formation, Western U.S. Springer, Dordrecht, pp 153–181
Trudell LG, Beard TN, Smith JW (1970) Green River Formation lithology and oil shale correlations in the Piceance Creek Basin, Colorado, U.S. Bureau of Mines, RI 7357. U.S. Dept. of Interior, Bureau of Mines, Washington, DC, 226 pp
U.S. Geological Survey Core Research Center (2012) Core Library Number C042. http://my.usgs.gov/crcwc/core/report/10109. Viewed 30 Oct 2012
Williamson CR, Picard MD (1974) Petrology of carbonate rocks of the Green River Formation (Eocene). J Sediment Petrol 44:739–759
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Boak, J., Poole, S. (2015). Mineralogy of the Green River Formation in the Piceance Creek Basin, Colorado. In: Smith, M., Carroll, A. (eds) Stratigraphy and Paleolimnology of the Green River Formation, Western USA. Syntheses in Limnogeology, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9906-5_8
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